摘要:
Provided herein are a porous film, a separator including the same, an electrochemical device including the separator, and a method of preparing the porous film. The porous film includes first cellulose nanofibers which is impregnated with a carbonate-based solvent-containing electrolyte solution and has a reaction heat of 150 J/g or less at a temperature ranging from about 30° C. to about 300° C., as measured by differential scanning calorimetry (DSC).
摘要:
The present invention relates to a porous membrane containing cellulose fibers, wherein the cellulose fibers contain 5% by weight or more of cellulose fibers with a diameter of 1 μm or more, relative to the total weight of the cellulose, and the porous membrane has a tensile strength of 50 N·m/g or more, and/or has a tear strength of 0.40 kN/m or more. The porous membrane according to the present invention can provide a separator for electrochemical devices with superior properties, at a reasonable cost.
摘要:
Acrylic and alkakacrylic acid can be graft copolymerized with cellulose fibers to form ion exchanging materials. The cellulose, acid monomer, and one component of an alkali persulfate-alkali thiosulfate redox catalyst coupled are mixed first. Then a strongly alkaline solution of the second catalyst component is added and the polymerization is permitted to continue to completion.
摘要:
ANION EXCHANGE MEMBRANES CAN BE PREPARED FROM CELLULOSE SHEET MATERIALS SUCH AS CELLOPHASE, PARCHMENT PAPER, OR KRAFT PAPER BY IMPREGNATING THE SHEET WITH POLYETHYLENEIMINE. THE MEMBRANE IS CROSS-LINKED AT A TEMPERATURE FROM 10 TO 50*C., WITH A RREAGENT SELECTED FROM THE GROUP OF MONALDEHYDES, DIALDEHYDES, REACTIVE METHOLYOL COMPOUNDS AND MIXTURES THEREOF. THE MEMBRANE IS THEN QUATERNIZED. IT IS PARTICULARLY SUITED FOR USE IN THE ELECTRODIALYTIC PURIFICATION OF SALINE WATER.
摘要:
A PROCESS FOR MAKING PERMSELECTIVE MEMBRANES COMPRISES REACTING A CELLULOSIC FILM OR PARCHMENTIZED CELLULOSIC SHEET OF ABOUT 0.1 MM. THICKNESS WITH AN AQUEOUS SOLUTION OF A SULFONATED COMPOUND OF THE GROUP CONSISTING OF A SULFONATED TRICHLOROPYRIMIDINE DYE, A SULFONATED 2,3-DICHLOROQUINOXALINE REACTIVE DYE, AND A SULFONATED DICHLORO-S-TRIAZINE, IN HIGH CONCENTRATION FOR A PERIOD OF TIME IN THE ORDER OF AT LEAST THREE HOURS UNTIL SAID CELLULOSIC FILM OR SHEET IS CONVERTED TO PERMSELECTIVE MEMBRANE EXHIBITING PERMSELECTIVITY EXCEEDING 14 MV. IN A CELL CONTAINING N/10 TO N/20 POTASSIUM CHLORIDE, AND EXHIBITING AN ELECTRICAL RESISTANCE OF LESS THAN 20 OHMS/ CM.2.
摘要:
Ion-exchange paper in which at least 10 per cent, based on the dry weight of pulp, of discrete, preferably pulverized, particles of one or more ion-exchange resins passing U.S. Standard sieve No. 50 are uniformly distributed (see Group VIII) can be used e.g. to remove acidic impurities from lubricating oils. Paper containing mixed particles of cation-and anion-exchange resins is particularly suitable for purifying water.ALSO:Ion-exchange paper in which at least 10 per cent, based on the dry weight of pulp, of discrete, preferably micropulverized, particles of one or more ion-exchange resins passing U.S. Standard Sieve No. 50 are uniformly distributed (see Group VIII), is used for wrapping and preserving foodstuffs, in filter tips and cartridges for cigarettes and tobacco pipes and in catamenial appliances. Anion-exchange and/or cation-exchange resins may be used. Suitable cation-exchange resins are the sulphonated copolymers of styrene and divinylbenzene and copolymers of methacrylic acid and divinylbenzene. The anion-exchange resin may be a copolymer of styrene and divinylbenzene having quaternary ammonium groups joined by means of methylene groups to the aromatic nuclei. Anion-exchange resins made by reacting diethylenetriamine with an insoluble copolymer of ethyl acrylate and divinylbenzene or by reacting trimethylamine with a chloromethylated copolymer of styrene and divinylbenzene may be used. Alum or sulphuric acid, fillers, dyes, pigments and wet-strength resins such as urea - formaldehyde and melamine - aldehyde resins may be incorporated in the paper pulp. The paper may be rendered greaseproof by parchmentizing.
摘要:
Disclosed is a method of manufacturing a porous polymer membrane, including forming pores by applying water pressure to a polymer membrane composed of a polymer and a metal salt, wherein the porous polymer membrane has properties suitable for use as a separator for a secondary battery.
摘要:
Hydrophilic films, fibers and spongy articles of a water-insoluble polymer selected from the group consisting of regenerated cellulose, cellulose ether, cellulose ester and polyalkylene, and capable of forming fibers and films, are produced by distributing in a mass of the polymer up to 50% of pulverulent or granular amorphous particles of an originally water-soluble cellulose ether prepared from natural cellulose and rendered by chemical modification at least partly water-insoluble while remaining water-absorbent. The resulting mixture is then processed by conventional methods into the desired article.
摘要:
A highly dispersed solid non-porous insoluble and infusible urea-formaldehyde condensation polymer in the form of a fluffy white powder, said product having a specific surface area of more than 10 square meters per gram and an average particle size smaller than 5 microns. The product preferably essentially consists of approximately spherical microparticles having substantially uniform size and shape and shows a tendency to form loosely agglomerated structures. These solids are useful as rubber reinforcing agents and as paper pigmentary fillers.
摘要:
FILMS AND FIBERS OR FILAMENTS HAVING ION-EXCHANGE PROPERTIES ARE MADE BY THE VISCOSE PROCESS FROM CELLULOSIC MATERIAL TO WHICH CERTAIN IONIC POLYMERS HAVE BEEN GRAFT POLYMERIZED PORTION TO THE REGENERATION OF THE CELLULOSIC MATERIAL.