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    Process for making base metal titanate catalytic device
    3.
    发明授权
    Process for making base metal titanate catalytic device 失效
    制造钛酸铋催化装置的方法

    公开(公告)号：US3892897A

    公开(公告)日：1975-07-01

    申请号：US44883574

    申请日：1974-03-07

    申请人： CORNING GLASS WORKS

    发明人： RITTLER HERMANN L

    IPC分类号： B01D53/94 ,  B01J23/84 ,  B01J37/02 ,  B01J1/06

    CPC分类号： B01D53/944 ,  B01J23/84 ,  B01J37/0234

    摘要： Processes for the preparation of base metal titanate catalysts in situ on refractory ceramic support structures which provide devices of significantly improved catalytic efficiency particularly suited for automotive exhaust emissions control applications are described. The base metal titanate catalysts comprise titaniferous crystal phases of spinel, ilmenite and/or pseudobrookite structure which consist essentially, in weight percent on the oxide basis, of about 15-85% TiO2, 15-70% M''''o, wherein M'''' is Mn 2, Co 2, Fe 2 or Cu 2, and 0-60% M2''''''O3, wherein M'''''' is A1 3, Fe 3, Cr 3, Mn 3 or Co 3. The process comprises preparing a solution of compounds of the desired metals, coating a refractory ceramic support structure with the solution, precipitating the desired metals from the solution onto the support structure as a coating of hydroxides, and firing the structure to convert the hydroxide coating to an oxide coating of the desired composition and crystalline structure.

    摘要翻译： 描述了在耐火陶瓷支撑结构上原位制备贱金属钛酸盐催化剂的方法，其提供了特别适用于汽车废气排放控制应用的显着提高的催化效率的装置。 贱金属钛酸盐催化剂包括尖晶石，钛铁矿和/或拟铁矿结构的钛酸晶相，其基本上以氧化物为基准计，约15-85％TiO 2，15-70％M''o，其中M' '是Mn +2，Co +2，Fe +2或Cu +2，以及0-60％M2“'O3，其中M”'是A1 + 3，Fe 3+，3+，3+，3+，3+。 该方法包括制备所需金属的化合物溶液，用溶液涂覆耐火陶瓷载体结构，将所需金属从溶液中沉淀成作为氢氧化物涂层的载体结构，并焙烧该结构以将氢氧化物涂层转化为 具有所需组成和结晶结构的氧化物涂层。

    Apparatus for the treatment of water solutions by ion exchange
    4.
    发明授权
    Apparatus for the treatment of water solutions by ion exchange 失效
    用于通过离子交换处理水溶液的装置

    公开(公告)号：US3915861A

    公开(公告)日：1975-10-28

    申请号：US39585473

    申请日：1973-09-10

    申请人： HAGER & ELSAESSER

    发明人： MARQUARDT KURT PAUL

    IPC分类号： B01J47/04 ,  B01J47/10 ,  B01J1/06 ,  B01D15/04

    CPC分类号： B01J47/10 ,  B01J47/04

    摘要： Treatment of watery solutions by means of ion exchange; the exchange mass through which the liquid under treatment flows is conducted from a bottom funnel of the treatment container to a regenerating-and-wash-column and thence back to the liquid treatment container. After leaving the liquid treatment container and before entering the regenerating-and-wash-column the ion exchange masses are back-rinsed in a back-rinse container; the ion exchange mass is transported from the regenerating-and-washcolumn means of an immersion tube at the top of the regeneratingand-wash-column, the depth of immersion of the immersion tube being adjustable according to the volume in the bottom funnel of the treatment container; consequently the ion exchange mass in the head of the regenerating-and-wash-column which has been transported from the treatment container corresponds to the volume transported from the bottom funnel thereof.

    摘要翻译： 通过离子交换处理水溶液; 待处理液体通过其进行的交换质量从处理容器的底漏斗传导到再生洗涤塔，然后返回到液体处理容器。 在离开液体处理容器之后并且在进入再生洗涤塔之前，将离子交换质量在后冲洗容器中反冲洗; 离子交换质量从再生洗涤塔顶部的浸入管的再生洗涤塔装置输送，浸入管的浸入深度可根据底部的体积调节 处理容器的漏斗; 因此，从处理容器输送的再生洗涤塔的头部中的离子交换质量对应于从其底漏斗输送的体积。

    Method and apparatus for regenerating mixed beds of ion exchange resins
    5.
    发明授权
    Method and apparatus for regenerating mixed beds of ion exchange resins 失效
    用于再生离子交换树脂混合床的方法和装置

    公开(公告)号：US3660282A

    公开(公告)日：1972-05-02

    申请号：US3660282D

    申请日：1969-06-17

    申请人： ECODYNE CORP

    发明人： O'BRIEN DENNIS M

    IPC分类号： B01D15/04 ,  B01J47/04 ,  B01D15/06 ,  B01J1/06

    CPC分类号： B01J47/04

    摘要： THE INVENTION PROVIDES AN IMPROVED METHOD AND APPARATUS FOR DELIVERING A MIXTURE OF ANION AND CATION EXCHANGE RESINS TO A SEPARATION COLUMN,. IN CARRYING OUT THE METHOD, RESIN IS DELIVERED RAPIDLY FROM A METERING ZONE TO THE TRANSFER ZONE, AND THEN IS DELIVERED FROM THE TRANSFER ZONE TO THE SEPARATION COLUMN AT A RELATIVELY SLOW RATE OF SPEED. THIS TWO-STEP TRANSFER MINIMIZES UNDESIRABLE

    DISTURBANCES IN THE SEPARATION COLUMN. IN THE APPARATUS, THE METERING AND TRANSFER ZONES ARE PREFERABLY DEFINED BY SUITABLE HOPPERS LOCATED ABOVE THE SEPARATION COLUMN.

    Continuous ion exchange process and apparatus
    6.
    发明授权
    Continuous ion exchange process and apparatus 失效
    连续离子交换过程和设备

    公开(公告)号：US3879287A

    公开(公告)日：1975-04-22

    申请号：US30258972

    申请日：1972-10-31

    申请人： PORTER ROBERT R

    发明人： PORTER ROBERT R

    IPC分类号： B01J47/10 ,  B01D15/06 ,  B01J1/06

    CPC分类号： B01J47/11

    摘要： A solution to be treated by ion exchange is continuously introduced into the bottom of the first of a series of ion exchange vessels containing respective adsorption columns of an appropriate, particulate, ion exchange material, and is passed successively through the subsequent ion exchange vessels of the series, so that such solution flows continuously upwardly through each adsorption column, thence to the bottom of the next column, and is finally discharged from the last column of the series as fully treated solution. The loaded adsorption column is removed from the first vessel of the series, usually to eluting means for regeneration, and the other adsorption columns are transferred from vessel to vessel up the line, the adsorption column of the last vessel of the series being replaced by substantially unloaded ion exchange material, usually eluted material from the adsorption column of the first vessel of the series. The cycle is repeated continuously throughout any given period of operation of the method. The eluting means preferably comprises one or more conventional fixed bed ion exchange vessels, with or without a holding vessel in advance thereof, and there is preferably an excess of ion exchange material at this stage so that, in conjunction with such vessel or vessels, there is a metering of ion exchange material circulating batchwise through the system countercurrent to the solution.

    摘要翻译： 通过离子交换处理的溶液被连续地引入到包含合适的颗粒状离子交换材料的各个吸附塔的一系列离子交换容器的第一个的底部，并连续地通过随后的离子交换容器 使得这样的溶液连续向上流过每个吸附柱，然后从下一个塔的底部流出，最后作为完全处理的溶液从串联的最后一个塔排出。 将负载的吸附塔从该系列的第一容器中取出，通常用于洗脱用于再生的装置，并且其它吸附塔从容器中转移到容器上，该系列的最后一个容器的吸附塔被基本上 未加载的离子交换材料，通常是从该系列的第一容器的吸附塔洗脱的物质。 在该方法的任何给定的操作周期内连续重复循环。 洗脱装置优选地包括一个或多个常规的固定床离子交换容器，其中有或没有预先存放容器，并且在该阶段优选地存在过量的离子交换材料，使得与这样的容器或容器结合在一起 是通过与溶液逆流的系统分批循环的离子交换材料的计量。

    Method and apparatus for softening or desalting water by ion exchange
    7.
    发明授权
    Method and apparatus for softening or desalting water by ion exchange 失效
    通过离子交换进行水或脱水处理的方法和装置

    公开(公告)号：US3679581A

    公开(公告)日：1972-07-25

    申请号：US3679581D

    申请日：1970-04-15

    申请人： GHH M A N TECHNIK GES FUR ANLA

    发明人： KUNZ GERHARD K

    IPC分类号： B01D15/04 ,  B01J47/10 ,  B01D15/06 ,  B01J1/06

    CPC分类号： B01J47/10

    摘要： IN AN ION EXCHANGE APPARATUS AND METHOD FOR THE SOFTENING AND/OR DESALTING OF WATER BY COUNTERCURRENT FLOW, AN ION EXCHANGE COLUMN, CONTAINING ALTERNATELY CATION EXCHANGE MATERIAL AND ANION EXCHANGE MATERIAL, IS PROVIDED WITH A PAIR OF REGENERATING COLUMNS BEING CONNECTED TO SAID EXCHANGE COLUMN, WITH ONE RECEIVING SPENT CATION MATERIAL AND THE OTHER SPENT ANION MATERIAL, AND A WASHING COLUMN CONNECTED TO EACH REGENERATION COLUMN AND TO THE EXCHANGE COLUMN SO THAT UPON THE REGENERATION AND WASHING OF THE CATION AND ANION EXCHANGE MATERIALS, EACH WILL BE PASSED TO THEIR RESPECTIVE ZONE.