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    Alkylation process using a sulfur-containing alkylation catalyst
    1.
    发明申请
    Alkylation process using a sulfur-containing alkylation catalyst 审中-公开
    使用含硫烷基化催化剂的烷基化方法

    公开(公告)号：US20030092948A1

    公开(公告)日：2003-05-15

    申请号：US10278143

    申请日：2002-10-22

    发明人： Emanuel Hermanus van Broekhoven ,  Pieter Bogaard

    IPC分类号： C07C015/12 ,  C07C002/04 ,  C07C002/24

    CPC分类号： B01J29/068 ,  B01J27/045 ,  B01J29/126 ,  B01J37/20 ,  C07C2/58 ,  C07C2521/04 ,  C07C2527/045 ,  C07C2529/12

    摘要： The invention relates to a process for alkylating a hydrcarbon feed which comprises contacting the hydrocarbon feed to be alkylated with an alkylation agent in the presence of a catalyst comprising a solid acid, a hydrogenation component consisting essentially of one or more Group VIII noble metals, and at least about 0.05 wt % of sulfur, based on the total weight of the catalyst composition. The invention further pertains to a catalyst suitable for said process and to a process for the preparation of said catalyst. The use of said catalyst results in a high conversion of the alkylation agent, a high C5null alkylate yield, and a good stability, while the selectivity has improved over the use of a comparable catalyst without sulfur.

    摘要翻译： 本发明涉及一种用于烷基化烃基进料的方法，该方法包括使烷基化的烃进料与烷基化试剂在催化剂存在下接触，所述催化剂包含固体酸，基本上由一种或多种VIII族贵金属组成的氢化组分和 至少约0.05重量％的硫，基于催化剂组合物的总重量。 本发明还涉及适用于所述方法的催化剂和制备所述催化剂的方法。 所述催化剂的使用导致烷基化试剂的高转化率，高的C5 +烷基化产率和良好的稳定性，而选择性比使用无硫的可比催化剂有所改善。

    Soluble late transition metal catalysts for olefin oligomerizations II
    2.
    发明申请
    Soluble late transition metal catalysts for olefin oligomerizations II 失效
    用于烯烃低聚的可溶性后过渡金属催化剂II

    公开(公告)号：US20040039238A1

    公开(公告)日：2004-02-26

    申请号：US10449273

    申请日：2003-05-30

    发明人： Baiyi Zhao ,  Enock Berluche ,  Smita Kacker ,  Jo Ann Marie Canich

    IPC分类号： C07C002/24 ,  B01J031/00

    CPC分类号： C07F15/0066 ,  C07F15/045

    摘要： A series of soluble null-diimine late transition metal catalysts has been invented. The catalysts demonstrate high activity and selectivity for linear null-olefins. As such, these catalysts conveniently oligomerize ethylene. Typical activators as known to those of ordinary skill in the art are used to activate these transition metal catalyst. These catalysts can be used in a supported or unsupported form.

    摘要翻译： 已经发明了一系列可溶性α-二亚胺晚期过渡金属催化剂。 催化剂表现出对线性α-烯烃的高活性和选择性。 因此，这些催化剂方便地使乙烯低聚。 使用本领域普通技术人员已知的典型活化剂来活化这些过渡金属催化剂。 这些催化剂可以以负载或未负载的形式使用。

    Linear alpha-olefin dimers possessing substantial linearity
    3.
    发明申请
    Linear alpha-olefin dimers possessing substantial linearity 有权
    线性α-烯烃二聚体具有很大的线性

    公开(公告)号：US20020177744A1

    公开(公告)日：2002-11-28

    申请号：US10056137

    申请日：2002-01-24

    发明人： Brooke L. Small ,  Eduardo J. Baralt

    IPC分类号： C07C011/00 ,  C07C009/00 ,  C07C002/04 ,  C07C002/24

    CPC分类号： C07C2/32 ,  C07C11/02 ,  C07C2531/22 ,  C07C2531/26

    摘要： Linear 1-butene dimers and other linear alpha-olefin dimers are manufactured in high yield and with high selectivity by coupling of alpha-olefins. The coupling is accomplished by contacting alpha olefins with an iron-based catalyst activated with an aluminum-based co-catalyst. The catalyst is structured to preclude formation of multiple dimer products, and the byproducts of the olefin coupling consist almost exclusively of methyl branched olefin dimers. The dimers have potentially diverse use in areas stretching form pharmaceuticals to plastics. Linear 1-butene dimers may be particularly useful in the production of plasticizer alcohols which may in turn be used to manufacture high quality plastics with reduced leaching.

    摘要翻译： 线性1-丁烯二聚体和其它直链α-烯烃二聚体以高产率和高选择性通过α-烯烃的偶联制备。 通过使α-烯烃与用铝基助催化剂活化的铁基催化剂接触来实现偶合。 该催化剂被构造成排除多个二聚体产物的形成，并且烯烃偶联的副产物几乎完全由甲基支链烯烃二聚体组成。 二聚体在从药物到塑料中拉伸的领域中具有潜在的多种用途。 线性1-丁烯二聚体可以特别用于生产增塑剂醇，其可以用于制造具有减少浸出的高质量塑料。

    Fuel components and their selective manufacturing methods
    7.
    发明申请
    Fuel components and their selective manufacturing methods 有权
    燃料组分及其选择性制造方法

    公开(公告)号：US20030088134A1

    公开(公告)日：2003-05-08

    申请号：US10134475

    申请日：2002-04-30

    发明人： Veli-Matti Purola ,  Sami Toppinen ,  Antti Pyhalahti ,  Marina Lindblad ,  Johan Gronqvist ,  Pirjo Siira

    IPC分类号： C07C002/02 ,  C07C002/04 ,  C07C002/24

    CPC分类号： C07C2/28 ,  C07C2531/10 ,  Y02P20/127

    摘要： The invention relates to a method for dimerizing isobutene, wherein, in dimerizing conditions, the isobutene is brought into contact with a porous cation exchange resin comprising a styrene polymer, which is cross-linked with divinyl benzene, and any sulphonic acid groups adhering to the polymer. The harmful deactivation of this catalyst, which is caused by the accumulation of the oligomers and polymers of isobutene and other C4-olefins in the cation exchange resin catalyst, is essentially decreased by selecting the cation exchange resin from a group including cation exchange resins, the acid capacity of which is 4.7 equivalents/kg at a minimum, and the portion of divinyl benzene units of which is 5% by weight at a minimum and smaller than 20% by weight.

    摘要翻译： 本发明涉及异丁烯二聚的方法，其中在二聚条件下，使异丁烯与包含与二乙烯基苯交联的苯乙烯聚合物的多孔阳离子交换树脂和与二乙烯基苯交联的任何磺酸基团接触 聚合物。 通过从阳离子交换树脂中选择阳离子交换树脂，阳离子交换树脂催化剂中异丁烯和其它C4-烯烃的低聚物和聚合物的积聚引起的该催化剂的有害失活基本上降低， 其酸容量最小为4.7当量/ kg，二乙烯基苯单元的份数最小为5重量％且小于20重量％。

    Preparation of a basic catalyst avoiding high temperatures
    10.
    发明申请
    Preparation of a basic catalyst avoiding high temperatures 失效
    避免高温的碱性催化剂的制备

    公开(公告)号：US20010044563A1

    公开(公告)日：2001-11-22

    申请号：US09884655

    申请日：2001-06-20

    发明人： Ulrich Steinbrenner ,  Eugen Gehrer

    IPC分类号： C07C015/067 ,  C07C002/04 ,  C07C005/25 ,  C07C002/24

    CPC分类号： C07C2/72 ,  B01J23/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/18 ,  C07C2523/50 ,  C07C2523/52

    摘要： A catalyst comprising at least one alkali metal and at least one metallic or semimetallic promoter selected from the group consisting of Ca, Sr, Ba, Ag, Au, Zn, Cd, Hg, In, Tl, Sn, As, Sb and Bi, on a support which may be doped with one or more compounds of an alkali metal and/or alkaline earth metal, where the alkali metal/support ratio by weight is from 0.01 to 5, the promoter/alkali metal ratio by weight is from 0.0001 to 5 and, when a dopant is present, the dopant/support ratio by weight is from 0.01 to 5.

    摘要翻译： 一种包含至少一种碱金属和至少一种选自Ca，Sr，Ba，Ag，Au，Zn，Cd，Hg，In，Tl，Sn，As，Sb和Bi的金属或半金属助催化剂的催化剂， 在可以掺杂一种或多种碱金属和/或碱土金属的化合物的载体上，其中碱金属/载体比例为0.01至5，助催化剂/碱金属重量比为0.0001至 并且当存在掺杂剂时，掺杂剂/载体的重量比为0.01至5。