公开(公告)号：US07468341B2

公开(公告)日：2008-12-23

申请号：US11303300

申请日：2005-12-16

申请人： Esterino Conca ,  Carlo Rubini ,  Marcello Marchi

发明人： Esterino Conca ,  Carlo Rubini ,  Marcello Marchi

IPC分类号： B01J23/00 ,  B01J21/00

CPC分类号： C07C45/38 ,  B01J23/002 ,  B01J23/8871 ,  B01J35/0006 ,  B01J35/026 ,  B01J35/1009 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/04 ,  B01J2523/00 ,  C07C47/04 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/3712

摘要： Catalysts for oxidation of methanol to formaldehyde, comprising a catalytic mixtures of Fe2(MoO4)3/MoO3, wherein the Mo/Fe atomic ratio ranges from 1.5 to 5, and a compound of cerium molybdenum and oxygen in a quantity from 0.1 to 10% by weight expressed as cerium.

摘要翻译： 用于将甲醇氧化成甲醛的催化剂，其包含Fe 2（MoO 4）3 / MoO 3的催化混合物，其中Mo / Fe原子比为1.5至5，并且铈钼和氧的化合物的量为0.1至10％ 以铈表示。

公开(公告)号：US06627777B2

公开(公告)日：2003-09-30

申请号：US09973391

申请日：2001-10-09

申请人： Michele Rossi ,  Carlo Rubini ,  Antonio Pasquale ,  Luigi Cavalli

发明人： Michele Rossi ,  Carlo Rubini ,  Antonio Pasquale ,  Luigi Cavalli

IPC分类号： C07C1723

CPC分类号： B01J37/0201 ,  B01J23/42 ,  B01J23/56 ,  B01J35/006 ,  B01J35/0093 ,  B01J35/023 ,  C07C17/23 ,  C07C19/04

摘要： Catalysts for the fluid-bed hydrodechlorination of carbon tetrachloride to chloroform having high catalytic stability and comprising platinum supported on microspheroidal gamma alumina, characterized in that the platinum is in the form of particles dispersed throughout the mass of the support.

公开(公告)号：US5939351A

公开(公告)日：1999-08-17

申请号：US615959

申请日：1996-03-14

申请人： Carlo Rubini ,  Luigi Cavalli

发明人： Carlo Rubini ,  Luigi Cavalli

IPC分类号： B01J2/20 ,  B01J2/22 ,  B01J21/04 ,  B01J23/28 ,  B01J23/88 ,  B01J23/881 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  C07B61/00 ,  C07C17/156 ,  C07C45/00 ,  C07C45/38 ,  C07C47/052

CPC分类号： B01J37/0009 ,  B01J23/88 ,  B01J23/881 ,  B01J35/002 ,  B01J35/026 ,  B01J35/10 ,  B01J37/0063 ,  B01J37/08 ,  C07C17/156 ,  C07C45/00 ,  C07C45/38 ,  C07C5/3332 ,  B01J35/0006 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1066

摘要： Catalysts and catalyst carriers, in the form of granules having a definite geometric form, characterized by porosity values such that at least 70% of the volume of the pores have a radius corresponding to the peak values of the porosity distribution curve. The catalysts and catalyst carriers are obtained by compression shaping, wherein the lubricant employed is applied to the molding of the chamber (external lubrication).

摘要翻译： 具有确定几何形式的颗粒形式的催化剂和催化剂载体的特征在于孔隙率值，使得至少70％的孔的体积具有对应于孔隙率分布曲线的峰值的半径。 催化剂和催化剂载体通过压缩成型获得，其中所用的润滑剂被应用于室的模制（外部润滑）。

公开(公告)号：US20060135371A1

公开(公告)日：2006-06-22

申请号：US11303493

申请日：2005-12-16

申请人： Esterino Conca ,  Carlo Rubini ,  Guido Petrini

发明人： Esterino Conca ,  Carlo Rubini ,  Guido Petrini

IPC分类号： C04B35/45

CPC分类号： B01J20/28014 ,  B01D53/02 ,  B01D53/565 ,  B01D2253/10 ,  B01D2255/91 ,  B01J20/0237 ,  B01J20/041 ,  B01J20/06 ,  B01J20/28057 ,  B01J20/3236 ,  F01N3/0842

摘要： Method for removing nitrogen oxides NOx from gas mixtures that contain them, comprising contacting of the gas mixtures with an absorbent material comprising compounds having formula CaCuO2 and/or Ca0.83CuO2 providing X-ray diffraction powder spectra that correspond, for the CaCuO2 compound, to JCPDS card 48-197 and, for the Ca0.83 CuO2, to JCPDS card 48-212, or mixtures of said compounds or compositions containing them.

摘要翻译： 包括从含有它们的气体混合物中除去氮氧化物的方法，包括使气体混合物与包含具有式CaCO 2和/或Ca的化合物的吸收材料接触 提供对于CaCl 2 O 2化合物对应于JCPDS卡48-197的X射线衍射粉末光谱，并且对于Ca 3 O 3， NCPC卡48-212，或所述化合物或含有它们的组合物的混合物。

公开(公告)号：US06833125B2

公开(公告)日：2004-12-21

申请号：US10730448

申请日：2003-12-08

申请人： Alberto Cremona ,  Carlo Rubini ,  Edoardo Vogna

发明人： Alberto Cremona ,  Carlo Rubini ,  Edoardo Vogna

IPC分类号： B01J800

CPC分类号： B01J23/8892 ,  B01D53/8668 ,  B01D2255/206 ,  B01D2255/2073 ,  B01D2255/20761 ,  B01D2257/708 ,  B01J37/0205 ,  Y02A50/235

摘要： Oxidation catalysts for used in the full oxidation to CO2 and H2O of volatile organic compounds, such as hydrocarbons, comprising mixed oxides of copper, manganese and one or more rare-earth metals, wherein the metals can assume multiple valency states, having a percentage composition by weight, expressed as CuO, MnO and rare-earth oxides, in which the metal has the minimum value of 8-50%, 10-75% and 2-15%, respectively. The oxides are supported on inert porous inorganic oxides.

摘要翻译： 用于完全氧化成CO 2和H 2 O的氧化催化剂，其包括铜，锰和一种或多种稀土金属的混合氧化物的挥发性有机化合物（例如烃），其中金属可以具有多种价态，其组成百分比 ，表示为CuO，MnO和稀土氧化物，其中金属的最小值分别为8-50％，10-75％和2-15％。 氧化物负载在惰性多孔无机氧化物上。

公开(公告)号：US06790274B2

公开(公告)日：2004-09-14

申请号：US10386798

申请日：2003-03-12

申请人： Esterino Conca ,  Carlo Rubini ,  Guido Petrini

发明人： Esterino Conca ,  Carlo Rubini ,  Guido Petrini

IPC分类号： C09C122

CPC分类号： B41F1/08 ,  B01J23/745 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/086 ,  B01J37/12 ,  B41F1/50 ,  C01G49/02 ,  C01G49/06 ,  C01P2006/12 ,  C01P2006/13 ,  C09C1/24

摘要： Highly pure iron oxides are prepared by reaction of metallic iron, in the form of microspheroidal particles or of scraps or cuttings, with an agitated aqueous solution of a mono- or polycarboxylic acid with a pKa of 0.5 to 6 relative to the first carboxyl and capable of decomposing, by heating in air at 200 to 350° C., to carbon dioxide and water, using 0.03 to 1.5 moles of acid per g-atoms of iron, a water/iron weight ration of 1 to 20, and by oxidation of the ferrous carboxilate to ferric salt, with an agent selected from oxygen, mixtures containing oxygen, hydrogen peroxide, organic peroxides and hydroperoxides.

摘要翻译： 高纯度的氧化铁是通过以微球形颗粒或废料或切屑的形式的金属铁与搅拌的单羧酸或多元羧酸的水溶液相对于第一羧基和pKa为0.5至6的反应制备的 通过在200-350℃的空气中加热分解成二氧化碳和水，每克原子铁使用0.03至1.5摩尔酸，1至20的水/铁重量比，并通过氧化 碳酸亚铁酸盐与铁盐，与选自氧的试剂，含氧的混合物，过氧化氢，有机过氧化物和氢过氧化物。

公开(公告)号：US06669847B2

公开(公告)日：2003-12-30

申请号：US09910175

申请日：2001-07-20

申请人： Antonio Pasquale ,  Carlo Rubini ,  Michele Rossi ,  Luigi Cavalli

发明人： Antonio Pasquale ,  Carlo Rubini ,  Michele Rossi ,  Luigi Cavalli

IPC分类号： C02F300

CPC分类号： C02F3/2806 ,  C02F1/283 ,  C02F1/66 ,  C02F1/70 ,  C02F1/78 ,  C02F2101/163 ,  C02F2209/06

摘要： A method for denitrification of water, in which the water to be denitrified is made to flow over a porous carrier which comprises a transition metal, preferably palladium, used in an amount between 0.01 and 5% by weight on the carrier and on which denitrifying bacterial strains capable of surviving in the presence of hydrogen are made to adhere, and in which hydrogen is used as a reducing agent and the pH of the reaction is adjusted to values of 4.5 to 7.8 preferably by using carbon dioxide.

公开(公告)号：US6066589A

公开(公告)日：2000-05-23

申请号：US81335

申请日：1998-05-19

申请人： Marinella Malentacchi ,  Luigi Cavalli ,  Carlo Rubini

发明人： Marinella Malentacchi ,  Luigi Cavalli ,  Carlo Rubini

IPC分类号： B01J23/44 ,  B01J21/00 ,  B01J21/18 ,  B01J23/00 ,  B01J23/46 ,  B01J23/89 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  B01J37/025 ,  C01B31/08 ,  C02F1/00 ,  C02F1/58 ,  C02F1/72 ,  C07B61/00 ,  C07C51/42 ,  C07C51/487 ,  C07C63/26

CPC分类号： C02F1/725 ,  B01J23/44 ,  B01J35/002 ,  B01J35/0053 ,  B01J35/006 ,  C07C51/487 ,  B01J21/18 ,  B01J35/023 ,  B01J35/1042 ,  B01J35/1076 ,  C02F2101/16

摘要： Hydrogenation catalysts comprising metallic palladium supported on activated carbon, wherein less than 50% by weight of the palladium is comprised within a surface layer with a depth of up to 50 microns, the remainder being comprised in a layer between 50 and 400 microns deep. The catalysts can be used in particular in purifying terephthalic acid obtained by oxidation of p-xylene.

摘要翻译： 包含负载在活性炭上的金属钯的氢化催化剂，其中小于50重量％的钯包含在深度达50微米的表面层内，其余部分包含在50至400微米深的层中。 催化剂特别可用于纯化通过对二甲苯的氧化获得的对苯二甲酸。

公开(公告)号：US08574450B2

公开(公告)日：2013-11-05

申请号：US13114201

申请日：2011-05-24

申请人： Esterino Conca ,  Carlo Rubini ,  Guido Petrini

发明人： Esterino Conca ,  Carlo Rubini ,  Guido Petrini

IPC分类号： C09C1/22

CPC分类号： B41F1/08 ,  B01J23/745 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/086 ,  B01J37/12 ,  B41F1/50 ,  C01G49/02 ,  C01G49/06 ,  C01P2006/12 ,  C01P2006/13 ,  C09C1/24

摘要： Highly pure iron oxides are prepared by reaction of metallic iron, in the form of microspheroidal particles or of scraps or cuttings, with an agitated aqueous solution of a mono- or polycarboxylic acid with a pKa of 0.5 to 6 relative to the first carboxyl and capable of decomposing, by heating in air at 200 to 350° C., to carbon dioxide and water, using 0.03 to 1.5 moles of acid per g-atoms of iron, a water/iron weight ration of 1 to 20, and by oxidation of the ferrous carboxilate to ferric salt, with an agent selected from oxygen, mixtures containing oxygen, hydrogen peroxide, organic peroxides and hydroperoxides.

公开(公告)号：US07572752B2

公开(公告)日：2009-08-11

申请号：US11303500

申请日：2005-12-16

申请人： Esterino Conca ,  Carlo Rubini ,  Marcello Marchi

发明人： Esterino Conca ,  Carlo Rubini ,  Marcello Marchi

IPC分类号： B01J23/00 ,  B01J23/40 ,  B01J23/42 ,  B01J23/70 ,  B01J23/74

CPC分类号： B01J23/881 ,  B01J23/002 ,  B01J23/8871 ,  B01J35/026 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/04 ,  B01J37/12 ,  B01J2523/00 ,  C07C45/38 ,  C07C47/04 ,  B01J2523/68 ,  B01J2523/842

摘要： Process for preparing a catalyst for the oxidation of methanol to formaldehyde, comprising reacting iron powder and molybdenum trioxide in a Mo/Fe ratio from 1.5 to 5 in an aqueous suspension at temperatures from 20 to 100° C., and subsequently, optionally simultaneously, oxidizing the mixture with an oxidizing agent in a quantity equal to, or greater than the quantity required for the oxidation of the ferrous ion to ferric ion and to oxidize the molybdenum to the valence state 6.

摘要翻译： 制备用于将甲醇氧化成甲醛的催化剂的方法，包括在20至100℃的温度下在水性悬浮液中使铁粉和Mo / Fe比为1.5至5的三氧化钼反应，随后任选地同时地， 以等于或大于将亚铁离子氧化成铁离子所需量并将钼氧化成化合价态的氧化剂氧化混合物6。