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    Preparation of C10-C30-alkenes by partial hydrogenation of alkynes over fixed-bed supported palladium catalysts
    1.
    发明授权
    Preparation of C10-C30-alkenes by partial hydrogenation of alkynes over fixed-bed supported palladium catalysts 失效
    通过固定床负载的钯催化剂上的炔进行部分氢化制备C10-C30-烯烃

    公开(公告)号：US06365790B2

    公开(公告)日：2002-04-02

    申请号：US09734024

    申请日：2000-12-12

    申请人： Klaus Reimer ,  Gerd Kaibel ,  Ulrich Kammel ,  Franz Josef Bröcker ,  Andreas Ansmann ,  Heinz Etzrodt ,  Manfred Stroezel ,  Mathias Haake ,  Lothar Laupichler ,  Bernhard Bockstiegel

    发明人： Klaus Reimer ,  Gerd Kaibel ,  Ulrich Kammel ,  Franz Josef Bröcker ,  Andreas Ansmann ,  Heinz Etzrodt ,  Manfred Stroezel ,  Mathias Haake ,  Lothar Laupichler ,  Bernhard Bockstiegel

    IPC分类号： C07C2900

    CPC分类号： C07C29/17 ,  B01J23/44 ,  B01J23/50 ,  B01J35/04 ,  B01J35/06 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/08 ,  C07C5/09 ,  C07C2523/44 ,  C07C11/02 ,  C07C33/025 ,  C07C33/02

    摘要： Alkenes are prepared by partial hydrogenation of alkynes in the liquid phase at from 20 to 250° C. and hydrogen partial pressures of from 0.3 to 200 bar over fixed-bed supported palladium catalysts which are obtainable by heating the support material in the air, cooling, applying a palladium compound and, if required, additionally other metal ions for doping purposes, molding and processing to give monolithic catalyst elements, by a process in which A) alkynes of 10 to 30 carbon atoms are used as starting compounds, B) the palladium compound and, if required, the other metal ions are applied to the support material by impregnation of the heated and cooled support material with a solution containing palladium salts and, if required, other metal ions and subsequent drying, and C) from 10 to 2000 ppm of carbon monoxide (CO) are added to the hydrogenation gas or a corresponding amount of CO is allowed to form in the liquid phase by slight decomposition of a compound which is added to the reaction mixture and eliminates CO under the reaction conditions. The process is particularly advantageous if the partial hydrogenation is carried out in a tube reactor by the trickle-bed or liquid phase procedure with product recycling at cross-sectional loadings of from 20 to 500 m3/m2*h. The process is particularly suitable for the preparation of 3,7,11,15-tetramethyl-1-hexadecen-3-ol (isophytol), 3,7,11-trimethyl-l-dodecen-3-ol (tetrahydronerolidol), 3,7,11-trimethyl-1,4-dodecadien-3-ol, 3,7,11-trimethyl-1,6-dodecadien-3-ol (dihydronerolidol), 3,7-dimethyloct-1,6-dien-3-ol or 3,7-dimethyloct-1-en-3-ol from the corresponding alkynes.

    摘要翻译： 烯烃通过液相中炔烃在20至250℃的部分氢化和固定床负载的钯催化剂的0.3至200巴的氢分压来制备，其可通过加热空气中的载体材料，冷却 使用钯化合物，另外还需要另外的金属离子用于掺杂目的，通过使用10-30个碳原子的炔烃作为起始化合物的方法，模塑和加工以得到整体式催化剂元素，B）钯 如果需要，另外的金属离子通过用含有钯盐的溶液浸渍加热和冷却的载体材料以及如果需要的话其它金属离子并随后干燥而被施加到载体材料上，C）为10-2000ppm 的一氧化碳（CO）加入到氢化气体中，或者相应量的CO在液相中形成，通过轻微分解添加到真空中的化合物 并且在反应条件下消除CO。如果部分氢化在管式反应器中通过滴流床或液相方法进行，则该方法是特别有利的，其中产物回收的横截面负荷为20-500m 3 / m2 * h。 该方法特别适用于制备3,7,11,15-四甲基-1-十六碳烯-3-醇（异山梨糖醇），3,7,11-三甲基-1-十二碳烯-3-醇（四氢化吗啉醇），3 ，7,11-三甲基-1,4-十二碳二烯-3-醇，3,7,11-三甲基-1,6-十二碳二烯-3-醇（二氢吗啉醇），3,7-二甲基辛-1,6-二烯 - 3-醇或3,7-二甲基辛-1-烯-3-醇。

    Method for producing 2,3-dichloro-1-propanol and epichlorohyrin
    2.
    发明授权
    Method for producing 2,3-dichloro-1-propanol and epichlorohyrin 有权
    2,3-二氯-1-丙醇和表氯醇的制备方法

    公开(公告)号：US06743955B2

    公开(公告)日：2004-06-01

    申请号：US10311225

    申请日：2002-12-16

    申请人： Toshitaka Hiro ,  Kazuhiro Sakurai

    发明人： Toshitaka Hiro ,  Kazuhiro Sakurai

    IPC分类号： C07C2900

    CPC分类号： C07C29/62 ,  C07C31/36

    摘要： Methods for continuously producing 2,3-dichloro-1-propanol (2,3-DCH) and epichlorohydrin in high yields and in a stabel manner for a long time are disclosed. In a method where allyl alcohol is chorinated in a hyrochloric acid solution and the reaction solution is introduced into a degassing tower to release hydrogen chloride and 2,3-DCH is obtained from the remaining solution, the concentraton of chlorine in the reaction mixture to be introduced into the degassing tower is maintaining to 0.015 g/ml or less and/or the partial pressure of chlorine gas in the reactor immediately before the degassing tower to 0.08 MPa or less, by monitoring and/or the partial pressure of chlorine gas in the reactor immediately before the degassing tower to 0.08 MPa or less, by monitoring and/or controlling the chlorine concentration of a solution at the outlet of the reactor immediately before the degassing tower and/or the partial pressure of chlorine gas present in the gas phase section of the reactor and the flow rate of chlorine gas immediately before the degassing tower.

    摘要翻译： 公开了以高产率和长时间稳定生产2,3-二氯-1-丙醇（2,3-DCH）和表氯醇的方法。 在烯丙醇在氯酸酸溶液中合成并将反应溶液引入脱气塔中以释放氯化氢并从剩余溶液中获得2,3-DCH的方法中，反应混合物中氯的浓度为 引入脱气塔的排气通过监测和/或氯气的分压来维持在脱气塔内的0.015g / ml以下和/或反应器内的氯气分压至0.08MPa以下 通过监测和/或控制在脱气塔之前的反应器出口处的溶液的氯浓度和/或存在于气相部分中的氯气分压，立即在脱气塔之前的反应器至0.08MPa或更低 的反应器和氯气的流量在脱气塔之前。

    Method for the photocatalytic conversion of gas hydrates
    3.
    发明授权
    Method for the photocatalytic conversion of gas hydrates 失效
    气体水合物的光催化转化方法

    公开(公告)号：US06267849B1

    公开(公告)日：2001-07-31

    申请号：US09616689

    申请日：2000-07-14

    申请人： Charles E. Taylor ,  Richard P. Noceti ,  Bradley C. Bockrath

    发明人： Charles E. Taylor ,  Richard P. Noceti ,  Bradley C. Bockrath

    IPC分类号： C07C2900

    CPC分类号： C07C29/48 ,  C07C31/04

    摘要： A method for converting methane hydrates to methanol, as well as hydrogen, through exposure to light. The process includes conversion of methane hydrates by light where a radical initiator has been added, and may be modified to include the conversion of methane hydrates with light where a photocatalyst doped by a suitable metal and an electron transfer agent to produce methanol and hydrogen. The present invention operates at temperatures below 0° C., and allows for the direct conversion of methane contained within the hydrate in situ.

    摘要翻译： 通过曝光将甲烷水合物转化成甲醇以及氢气的方法。 该方法包括通过添加自由基引发剂的光转化甲烷水合物，并且可以被修饰以包括用光转化甲烷水合物，其中由合适的金属和电子转移剂掺杂的光催化剂产生甲醇和氢。 本发明在低于0℃的温度下操作，并允许原位在水合物中直接转化甲烷。

    Water soluble bactericide and producing method thereof
    4.
    发明授权
    Water soluble bactericide and producing method thereof 失效
    水溶性杀菌剂及其制备方法

    公开(公告)号：US06781020B2

    公开(公告)日：2004-08-24

    申请号：US10215999

    申请日：2002-08-08

    申请人： Akihiko Shiba ,  Kiyoko Shiba ,  Gotaro Shiota ,  Yoshiaki Maruyama

    发明人： Akihiko Shiba ,  Kiyoko Shiba ,  Gotaro Shiota ,  Yoshiaki Maruyama

    IPC分类号： C07C2900

    CPC分类号： A61K31/335

    摘要： A water soluble bactericide is obtained by ozone-oxidizing glycerin. Specifically, a 0.1 to 20% glycerin aqueous solution and gas phase ozone obtained by ozonizing oxygen through contact between oxygen and a silent discharge field, are brought into gas-liquid contact with each other, thereby to ozone-oxdize glycerin. Alternatively, a 0.1 to 20% glycerin aqueous solution is electrolyzed, thereby to produce ozone directly in the glycerin aqueous solution.

    摘要翻译： 通过臭氧氧化甘油获得水溶性杀菌剂。 具体地说，通过氧与无声放电场之间的接触使氧气臭氧化得到的0.1〜20％的甘油水溶液和气相臭氧彼此气液接触，从而臭氧氧化甘油。 或者，将0.1〜20％的甘油水溶液进行电解，直接在甘油水溶液中生成臭氧。

    Processes for producing unsaturated alcohols
    6.
    发明授权
    Processes for producing unsaturated alcohols 失效
    不饱和醇的制备方法

    公开(公告)号：US06369283B1

    公开(公告)日：2002-04-09

    申请号：US09704411

    申请日：2000-11-02

    申请人： Anil Sakharam Guram ,  John Robert Briggs ,  Kurt Damar Olson ,  Thomas Carl Eisenschmid ,  Daine Lee Packett ,  Erik Bruce Tjaden

    发明人： Anil Sakharam Guram ,  John Robert Briggs ,  Kurt Damar Olson ,  Thomas Carl Eisenschmid ,  Daine Lee Packett ,  Erik Bruce Tjaden

    IPC分类号： C07C2900

    CPC分类号： C07C29/16 ,  C07B2200/09 ,  Y02P20/582 ,  C07C33/025 ,  C07C33/03 ,  C07C31/125

    摘要： This invention relates in part to processes for producing one or more substituted or unsubstituted unsaturated alcohols which comprise reacting one or more substituted or unsubstituted alkadienes with carbon monoxide and hydrogen in the presence of a metal-ligand complex catalyst and a promoter and optionally free ligand to produce said one or more substituted or unsubstituted unsaturated alcohols. The substituted and unsubstituted unsaturated alcohols produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted unsaturated alcohols as principal product(s) of reaction.

    摘要翻译： 本发明部分涉及制备一种或多种取代或未取代的不饱和醇的方法，其包括在金属 - 配体配合物催化剂和助催化剂和任选的游离配位体的存在下使一种或多种取代或未取代的烷二烯与一氧化碳和氢反应 产生所述一种或多种取代或未取代的不饱和醇。 通过本发明方法制备的取代和未取代的不饱和醇可进一步反应以提供所需的衍生物。 本发明还部分涉及含有一种或多种取代或未取代的不饱和醇作为主要反应产物的反应混合物。

    Process for producing fluoroalcohol
    8.
    发明授权
    Process for producing fluoroalcohol 失效
    氟代醇的制备方法

    公开(公告)号：US06187969B1

    公开(公告)日：2001-02-13

    申请号：US09394679

    申请日：1999-09-13

    申请人： Fumihiko Yamaguchi ,  Shoji Takaki ,  Toru Yoshizawa ,  Eiji Ogura ,  Toshiyuki Katsube

    发明人： Fumihiko Yamaguchi ,  Shoji Takaki ,  Toru Yoshizawa ,  Eiji Ogura ,  Toshiyuki Katsube

    IPC分类号： C07C2900

    CPC分类号： C07C29/44 ,  C07C31/38

    摘要： A process for producing a fluoroalcohol of the following formula (1) H(CFR1CF2)nCH2OH  (1) (n=1 or 2, wherein R1 represents F or CF3 when n=1; R1 represents F when n=2) comprising reacting methanol with tetrafluoroethylene or hexafluoropropylene in the presence of an initiator wherein the fluoroalcohol of formula (1) is distilled after decomposing the remaining initiator contained in the reaction mixture.

    摘要翻译： 一种制备下式（1）的氟代醇的方法（n = 1或2，当n = 1时，R1表示F或CF3;当n = 2时，R1表示F），包括使甲醇与四氟乙烯或六氟丙烯反应， 其中在分解反应混合物中所含的剩余引发剂之后蒸馏出式（1）的氟代醇的引发剂。