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    Synthesis of unsaturated esters and lactone from butadiene and carbon dioxide
    1.
    发明授权
    Synthesis of unsaturated esters and lactone from butadiene and carbon dioxide 失效
    从丁二烯和二氧化碳合成不饱和酯和内酯

    公开(公告)号：US4167513A

    公开(公告)日：1979-09-11

    申请号：US939793

    申请日：1978-09-05

    申请人： Alfredo Musco ,  Roberto Santi ,  Gian P. Chiusoli

    发明人： Alfredo Musco ,  Roberto Santi ,  Gian P. Chiusoli

    IPC分类号： C07C69/587 ,  B01J31/00 ,  C07B61/00 ,  C07C29/09 ,  C07C29/149 ,  C07C51/00 ,  C07C51/09 ,  C07C51/15 ,  C07C57/03 ,  C07C67/00 ,  C07C69/527 ,  C07D309/32 ,  C07D315/00 ,  C07D309/30 ,  C07C69/61

    CPC分类号： C07D315/00 ,  C07C29/095 ,  C07C29/149 ,  C07C51/09

    摘要： Octadienyl esters of 2-ethylidene-hepta-3,5-dienoic and 2-vinyl-hepta-3,5-dienoic acids of formula C.sub.8 H.sub.11 COOC.sub.8 H.sub.13 and .delta.-lactone of formula ##STR1## or 2-ethylidene-hepta-6-ene-5-olide, are prepared by reaction of 1,3-butadiene with CO.sub.2 at a temperature comprised between about 20.degree. and 150.degree. C. and at a total pressure between about 10 and 500 atm in the presence of a phosphinic complex of palladium having the formula Pd[P(R).sub.3 ].sub.x, wherein x is an integer from 2 to 4, and (R).sub.3 is a homogeneous or heterogeneous group consisting of alkyls, cycloalkyls having up to 8 carbon atoms and of phenyls, also substituted, in an inert atmosphere.The obtained products are "per se" new and are valuable intermediates for synthesis of chemicals (fungicides, pesticides, etc.) and in particular as effective plasticizers.

    摘要翻译： 式C 8 H 11 COOC 8 H 13的2-亚乙基 - 庚-3,5-二烯酸和2-乙烯基 - 庚-3,5-二烯酸的辛二烯基酯和式（II）的δ-内酯或2-亚乙基 - 七 烯-5-醇通过1,3-二丁烯与CO 2在约20-150℃的温度下反应并在约10-500atm的总压下在次膦酸盐络合物 具有式Pd [P（R）3] x的钯，其中x是2至4的整数，（R）3是由烷基，具有至多8个碳原子的环烷基和苯基组成的均相或异质基团 也在惰性气氛中取代。

    Intermediates for the preparation of 17-substituted-.DELTA..sup.4 -gonenes
    3.
    发明授权
    Intermediates for the preparation of 17-substituted-.DELTA..sup.4 -gonenes 失效
    用于制备17-取代的{66 {hu 4 {b-蒎烯

    公开(公告)号：US3980687A

    公开(公告)日：1976-09-14

    申请号：US489616

    申请日：1974-07-18

    申请人： Julien Warnant ,  Jean Jolly ,  Robert Joly

    发明人： Julien Warnant ,  Jean Jolly ,  Robert Joly

    IPC分类号： A41B1/00 ,  A41B3/00 ,  C07J1/00 ,  C07J7/00 ,  C07J41/00 ,  C07J73/00 ,  C07J75/00 ,  C07C69/145 ,  C07C69/24 ,  C07C69/61 ,  C07C69/74

    CPC分类号： C07J73/00 ,  C07J1/00 ,  C07J41/00 ,  C07J7/00 ,  C07J75/00

    摘要： A process for the production of a .DELTA..sup.4 -gonenic steroid having the formula ##SPC1##Wherein R represents a member selected from the group consisting of hydrogen and the acyl of an organic carboxylic acid having from 1 to 18 carbon atoms, R' represents an alkyl having from 1 to 4 carbon atoms, R.sup.iv represents a member selected from the group consisting of lower alkyl, lower alkenyl or lower alkynyl, and B represents a member selected from the group consisting of two hydrogens in the 9.alpha. and 10.beta. position and a double bond which comprises the steps of reacting a 3-ketal-4,5-seco-gonane-5-one with a ketalizing agent, oxidizing the resultant 3,5-diketal-4,5-seco-gonane-17.beta.-ol, reacting the resultant 3,5-diketal-4,5-seco-gonane-17-one with an organometallic compound, hydrolyzing the resultant 3,5-diketal-17.alpha.-R.sup.iv -4,5-seco-gonane-17.beta.-ol, cyclizing the resultant 17.alpha.-R.sup.iv -4,5-seco-gonane-17.beta.-ol-3,5-dione and recovering said .DELTA..sup.4 -gonenic steroid. The novel intermediates are also part of the invention. The .DELTA..sup.4 -gonenic steroids are known compounds having steroidal properties.

    摘要翻译： 一种制备具有式WHEREIN R的一种DELTA 4-型类固醇的方法，其选自氢和具有1至18个碳原子的有机羧酸的酰基，R'表示具有 1至4个碳原子，Riv表示选自低级烷基，低级烯基或低级炔基的成员，B表示选自9α和10β位中的两个氢和双键的成员 其包括使3-缩酮-4,5-二羟基喹啉-5-酮与缩酮剂反应的步骤，将所得3,5-二缩酮-4,5-二羟基-17β-醇氧化，使 所得的3,5-二缩酮-4,5-二缩酮-17-酮与有机金属化合物，水解所得的3,5-二缩酮-17α-1R-4,5-间苯二酚-17β-醇 ，使得到的17α-Riv-4,5-Seco-gonane-17β-羟基-3,5-二酮环化并回收所述DELTA4-型葡萄糖甾族化合物。 新颖的中间体也是本发明的一部分。 DELTA 4-Gonenic类固醇是具有甾体特性的已知化合物。

    Steffimycinone, 7-deoxysteffimycinone and derivatives
    4.
    发明授权
    Steffimycinone, 7-deoxysteffimycinone and derivatives 失效
    苯乙酰丙酮酮，7-脱氧硫嘧啶酮及其衍生物

    公开(公告)号：US3976667A

    公开(公告)日：1976-08-24

    申请号：US588298

    申请日：1975-06-19

    申请人： Robert C. Kelly

    发明人： Robert C. Kelly

    IPC分类号： C07C50/26 ,  C07C50/36 ,  C07C49/74 ,  C07C69/18 ,  C07C69/21 ,  C07C69/30 ,  C07C69/33 ,  C07C69/61 ,  C07C69/63 ,  C07C69/67 ,  C07C69/68 ,  C07C69/74 ,  C07C69/78 ,  C07C69/84 ,  C07C69/92 ,  C07C69/96 ,  C07C79/46 ,  C07C121/00

    CPC分类号： C07C50/26 ,  C07C50/36 ,  Y10S514/924

    摘要： Antibiotic steffimycinone (U-25,055), produced by acid hydrolysis or methanolysis of antibiotic steffimycin (U-20,661), or steffimycin B, and 7-deoxysteffimycinone (U-25,920) produced by hydrogenolysis of steffimycin or steffimycin B (U-40,615). Steffimycinone is active against various microorganisms, for example, Bacillus subtilis, Mycobacterium avium and Bacillus cereus; 7-deoxysteffimycinone is active against Sarcina lutea and Mycobacterium avium. Thus, these antibiotics can be used to inhibit the growth of the above microorganisms in various environments.

    摘要翻译： 通过苯乙呋霉素或苯乙呋霉素B（U-40,615）的氢解制备的抗生素苯乙炔霉素（U-20,661）的酸水解或甲醇分解产生的抗生素Steffimycinone（U-25,055）或者谷氨酰霉素B和7-脱氧硫羟孕酮酮（U-25,920）。 斯蒂夫霉酮对各种微生物有活性，例如枯草芽孢杆菌，鸟分枝杆菌和蜡状芽孢杆菌; 7-脱氧硫咪唑酮对刺鼻黄杆菌和鸟分枝杆菌有活性。 因此，这些抗生素可用于抑制各种环境中上述微生物的生长。

    Preparation of 2-ketogulonic acid
    5.
    发明授权
    Preparation of 2-ketogulonic acid 失效
    2-酮基古洛糖酸的制备

    公开(公告)号：US4212988A

    公开(公告)日：1980-07-15

    申请号：US24284

    申请日：1979-03-26

    申请人： Glenn C. Andrews

    发明人： Glenn C. Andrews

    IPC分类号： C07C51/377 ,  C07C59/33 ,  C07C67/30 ,  C07C69/61

    CPC分类号： C07C51/377

    摘要： 2,5-Diketogluconic acid, alkyl esters or salts thereof, are reduced by an amine-borane to 2-ketogulonic acid, an intermediate for the preparation of ascorbic acid.

    摘要翻译： 2,5-二酮葡萄糖酸，其烷基酯或其盐通过胺 - 硼烷还原成2-酮庚酸，其是制备抗坏血酸的中间体。