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    Method of producing active amino acid esters
    1.
    发明授权
    Method of producing active amino acid esters 失效
    生产活性氨基酸酯的方法

    公开(公告)号：US3872099A

    公开(公告)日：1975-03-18

    申请号：US31792172

    申请日：1972-12-26

    申请人： AJINOMOTO KK

    发明人： YASUDA NAOHIKO ,  ARIYOSHI YASUO ,  TOI KOJI

    IPC分类号： A61K38/00 ,  C07D207/46 ,  C07K1/06 ,  C07K1/08 ,  C07K1/10 ,  C07K5/06 ,  C07K5/068 ,  C07K5/072 ,  C07K5/078 ,  C07K5/083 ,  C07D27/10

    CPC分类号： C07C251/00 ,  A61K38/00 ,  C07K1/064 ,  C07K1/084 ,  C07K1/10 ,  C07K5/06026 ,  C07K5/06086 ,  C07K5/06113 ,  C07K5/06139 ,  C07K5/06165 ,  C07K5/0804

    摘要： Amino acids having masked amino groups react with amino acids having masked carboxyl groups to form peptide derivatives in good yields if the reaction medium contains an isonitrile. Isonitriles also are effective in causing condensation of amino acids having masked amino groups with compounds having active hydroxyl groups to the corresponding amino acid esters. The yields of the firstmentioned reaction are enhanced if the reaction mixture additionally contains one of the compounds having active hydroxyl groups. Both the peptide derivatives and the amino acid esters of the compounds having active hydroxyl groups are useful for peptide synthesis. The term ''''amino acid'''' herein embraces also oligopeptides having free amino and carboxyl groups unless specifically stated otherwise.

    摘要翻译： 如果反应介质含有异腈，具有掩蔽的氨基的氨基酸与具有掩蔽的羧基的氨基酸反应以以良好的产率形成肽衍生物。 异腈还有效地使具有掩蔽氨基的氨基酸与具有活性羟基的化合物缩合成相应的氨基酸酯。 如果反应混合物另外含有具有活性羟基的化合物之一，则提高反应​​的产率。 肽衍生物和具有活性羟基的化合物的氨基酸酯都可用于肽合成。 术语“氨基酸”也包括具有游离氨基和羧基的寡肽，除非另有特别说明。

    Sulfur derivatives of alkylhydroxyphenyl maleimides and compositions thereof
    2.
    发明授权
    Sulfur derivatives of alkylhydroxyphenyl maleimides and compositions thereof 失效
    烷基羟基苯乙烯氧化物的硫化物衍生物及其组合物

    公开(公告)号：US3790597A

    公开(公告)日：1974-02-05

    申请号：US3790597D

    申请日：1971-04-12

    申请人： CIBA GEIGY CORP

    发明人： KNELL M ,  PETERLI H ,  DEXTER M ,  MANOR B

    IPC分类号： C07D207/40 ,  C07D27/10

    CPC分类号： C07D207/40

    摘要： NOVEL SULFUR DRIVATIVES OF ALKYLHYDROXYPHENYL MALEIMIDES WERE PREPARED. THE ALKYL-HYDROXYPHENYL MALEIMIDES WERE PREPARED BY FIRST REACTING AN ALKYLHYDROXYPHENYL AMINE WITH MALIEC ANHYDRIDE WITH SUBSEQUENT CYCLIZATION OF THE MALEAMIC ACID TO OBTAIN THE CORRESPONDING MALEIMIDE. THE SULFUR CONTAINING DERIVATIVES OF THE ALKYLHYDROXYPHENYL MALEIMIDE IS PREPARED BY REACTING THE CORRESPONDING MALEIMIDE WITH AN APPROPRIATE MERCAPTAN OR DIMERCAPTAN COMPOUND. THE COMPOUNDS OF THIS INVENTION ARE USEFUL AS STABILIZERS OF ORGANIC MATERIALS WHICH ARE SUBJECT TO OXIDATIVE AND THERMAL DETERIORATION.

    Succinimide-containing dyestuffs
    4.
    发明授权
    Succinimide-containing dyestuffs 失效
    含SUCCINIMIDE的DYESTUFFS

    公开(公告)号：US3714184A

    公开(公告)日：1973-01-30

    申请号：US3714184D

    申请日：1969-10-01

    申请人： UGINE KUHLMANN

    发明人： KREMER G

    IPC分类号： C07D207/40 ,  C07D207/404 ,  C09B11/12 ,  C07D27/10

    CPC分类号： C07D207/404 ,  C09B11/12

    摘要： Dyestuffs of the formula:

    WHEREIN R represents a hydrogen atom or an alkyl or alkyl-Oalkyl group, the alkyl groups containing one to four atoms of carbon, R1 represents a hydrogen atom or a methyl group, R2 represents a alkyl group containing one to four carbon atoms, or a cycloalkyl, aryl, aralkyl or succinimidoethyl group, Y represents a hydrogen or halogen atom or an alkoxy, nitro, cyano, or amino group, and X represents a monovalent anion and processes for their manufacture. These dyestuffs are particularly suitable for the coloration of fibers based on polymers or copolymers of acrylonitrile.

    摘要翻译： 染料的配方：

    Dithioamides
    5.
    发明授权
    Dithioamides 失效
    DITHIOAMIDES

    公开(公告)号：US3709907A

    公开(公告)日：1973-01-09

    申请号：US3709907D

    申请日：1970-01-12

    申请人： MONSANTO CO

    发明人： BEHFOROUZ M

    IPC分类号： C07D295/26 ,  C08K5/43 ,  C07D27/10 ,  C07D27/52

    CPC分类号： C07D295/26 ,  C08K5/43 ,  C08L21/00

    摘要： NEW COMPOUNDS WITH A NUCLEUS OF

    R-S-S-N(-)-CO-

    WHERE THE DANGLING VALENCE ON THE NITROGEN IS LINKED TO A SECOND CARBONYL, ALKYL, ARYL, CYCLOALKYL, HYDROGEN, ALKYLENE CARBON, OR ARYLENE CARBON AND R IS ALKYL, ARYL, OR CYCLOALKYL ARE INHIBITORS OF PREMATURE VULCANIZATION OF DIENE RUBBERS. COMPOUNDS OF THE FORMULA

    R"''-S-S-N(-X'')-X

    WHERE X IS CYCLOALKYL, ALKYL, ARYL, OR HYDROGEN AND X'' IS CYCLOALKYL, ALKYL, OR ARYL; OR X AND X'' TOGETHER WITH THE N ATOM FORM A HETEROCYCLIC AMINE; AND R"'' IS ARYL, ALKYL, OR CYCLOALKYL ARE ALSO INHIBITORS OF PREMATURE VULCANIZATION OF DIENE RUBBERS. A COMBINATION OF A VULCANIZATION ACCELERATOR AND AN INHIBITOR OF THIS INVENTION IS AN IMPROVED RUBBER ADDITIVE WHICH ALLOWS LONGER AND SAFER PROCESSING TIME FOR RUBBER.

    N-phenylsuccinimides
    8.
    发明授权
    N-phenylsuccinimides 失效
    N-PHENYLSUCCINIMIDES

    公开(公告)号：US3804856A

    公开(公告)日：1974-04-16

    申请号：US17671371

    申请日：1971-08-31

    申请人： SUMITOMO CHEMICAL CO

    发明人： OOBA S ,  OZAKI T ,  YAMAMOTO S ,  TANAKA K

    IPC分类号： C07D207/40 ,  C07D207/416 ,  C07D27/10

    CPC分类号： C07D207/416 ,  Y10S514/949

    摘要： A NOVEL N-PHENYLSUCCINIMIDE DERIVATIVE HAVING THE FORMULA,

    1-(2-R,6-R'',(X)N-PHENYL),3-(R"-S(=O)M-)PYRROLIDINE-2,5-

    DIONE

    WHEREIN R AND R'' ARE INDIVIDUALLY HALOGEN OR A LOWER ALKYL, X IS HALOGEN, A LOWER ALKYL, A LOWER ALKOXY OR NITRO, R" IS AN ALKYL HAVING 1 TO 10 CARBON ATOMS, AN ALKENYL, A GROUP OF THE FORMULA,

    (Q-PHENYL)-(CH2)L-

    WHEREIN Q IS HYDROGEN, HALOGEN, A LOWER ALKYL, A LOWER ALKOXY OR NITRO, AND L IS 1, 2, 3 OR 4, A GROUP OF THE FORMULA,

    Z-PHENYL

    WHEREIN Z IS HYDROGEN, HALOGEN, A LOWER ALKYL, A LOWER ALKOXY OR NITRO, A-FURFURYL OR A GROUP OF THE FORMULA, -CH2COOR'''''' WHEREIN R'''''' IS A LOWER ALKYL, N IS 0, 1, 2 OR 3, AND M IS 0, 1 OR 2, EXHIBITS AND EXTREMELY STRONG MICROBICIDAL ACTIVITY ON A MARKEDLY WIDE SCOPE OF MICROORGANISMS AND HAS A LOW TOXICITY. THE ABOVE-MENTIONED COMPOUND CAN BE PREPARED BY THE ADDITION REACTION OF AN N-PHENYLMALEIMIDE DERIVATIVE REPRESENTED BY THE FORMULA,

    1-(2-R,6-R'',(X)N-PHENYL)-3-PYRROLINE-2,5-DIONE

    WITH A COMPOUND REPRESENTED BY THE FORMULA

    R''''SH

    OR BY THE OXIDATION OF A COMPOUND OF THE FORMULA,

    1-(2-R,6-R'',(X)N-PHENYL),3-(R"-S-)PYRROLIDINE-2,5-DIONE

    WHICH IS OBTAINED BY THE ABOVE-MENTIONED REACTION. ALTERNATIVELY, THE SAID NOVEL N-PHENYLSUCCINIMIDE DERIVATIVE CAN BE PREPARED BY DEHYDRATING AND RING-CLOSING A COMPOUND OF THE FORMULA,

    (2-R,6-R'',(X)N-PHENYL)-NH-CO-CH(-S(=O)M-R")-CH2-COOH OR

    (2-R,6-R'',(X)N-PHENYL)-NH-CO-CH2-CH(-S(=O)M-R")-COOH

    Polymeric succinimides and their derivatives as fuel and motor oil additives
    9.
    发明授权
    Polymeric succinimides and their derivatives as fuel and motor oil additives 失效
    作为燃料和电机油添加剂的聚合物及其衍生物

    公开(公告)号：US3723460A

    公开(公告)日：1973-03-27

    申请号：US3723460D

    申请日：1969-10-10

    申请人： STANDARD OIL CO

    发明人： BRANNEN W ,  WATSON R

    IPC分类号： C10L1/14 ,  C10M159/12 ,  C07D27/10

    CPC分类号： C10L1/14 ,  C10M159/12 ,  C10M2215/086 ,  C10M2215/16 ,  C10M2215/28 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2223/12 ,  C10M2227/06 ,  C10N2210/01 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2210/04 ,  C10N2210/05

    摘要： The disclosure describes reaction products useful as multipurpose fuel and motor oil additives which are reaction products of about equal molar portions of (1) an intermediate product produced by the condensation reaction between about equal molar portions of a compound selected from the group consisting of an alkenyl substituted succinic acid, an alkenyl substituted succinic anhydride and an alkenyl substituted succinimide or metal salt thereof, said compound having an average molecular weight from about 350 to about 1,000, and a second compound selected from the group consisting of ammonia gas, ammonium hydroxide and hydrazine, and (2) a third compound selected from the group consisting of basic metal compounds, compounds with displaceable halogens, acid halides, alkylene oxides, acid anhydrides, thio anhydrides, triethyl phosphite, boric acid and acrylonitrile. The intermediate product was itself found to be useful as a fuel and motor oil additive.

    摘要翻译： 本公开描述了可用作多用途燃料和机油添加剂的反应产物，其为（1）通过缩合反应产生的中等产物的反应产物，所述缩合反应在约等摩尔数之间的选自以下的化合物 取代的琥珀酸，烯基取代的琥珀酸酐和烯基取代的琥珀酰亚胺或其金属盐，所述化合物的平均分子量为约350至约1,000，第二种化合物选自氨气，氢氧化铵和肼 ，和（2）选自碱金属化合物，具有可置换卤素的化合物，酰卤，环氧烷，酸酐，硫代酸酐，亚磷酸三乙酯，硼酸和丙烯腈的第三种化合物。 中间产物本身被发现可用作燃料和机油添加剂。

    Sulfonyl substituted terpolymer fuel detergents
    10.
    发明授权
    Sulfonyl substituted terpolymer fuel detergents 失效
    SULFONYL取代的TERPOLYMER燃料洗涤剂

    公开(公告)号：US3715368A

    公开(公告)日：1973-02-06

    申请号：US3715368D

    申请日：1970-02-16

    申请人： CHEVRON RES

    发明人： MEHMEDBASICH E

    IPC分类号： C08F8/00 ,  C10L1/24 ,  C07D27/10

    CPC分类号： C10L1/2468 ,  C08F8/00 ,  C08F20/02

    摘要： Terpolymer compositions of relatively low molecular weight having aliphatic 1-olefins of from about eight to 30 carbon atoms, N-substituted maleimides and olefins having a sulfone interrupted chain. The compositions find use as detergents in fuels.

    摘要翻译： 具有约8至30个碳原子的脂族1-烯烃的相对低分子量的三元共聚物组合物，N-取代的马来酰亚胺和具有砜中断链的烯烃。 该组合物用作燃料中的洗涤剂。