摘要:
The present disclosure describes tunable methods of treating cellulosic materials with a composition that provides increased hydrophobicity and/or lipophobicity to such materials without sacrificing the biodegradability thereof. The methods as disclosed provide for binding of saccharide fatty acid esters on cellulosic materials, including that the disclosure provides products made by such methods. The materials thus treated display higher hydrophobicity, lipophobicity, barrier function, and mechanical properties, and may be used in any application where such features are desired.
摘要:
The purpose of the present invention is to provide a cellulose acetate which can be used to obtain an optical film having a very small amount of bright spot foreign matters, with excellent production efficiency, even when cellulose containing a small amount of hemicellulose components and having a high degree of crystallinity is used as a raw material. A cellulose acetate in which a content ratio by mole of mannose units to a sum of xylose units, mannose units and glucose units, which are sugar chain components, is 0.04 mol % or less, and a filtration index K measured by the following measurement method is 30 mL−1 or less. (Measurement method) The cellulose acetate is dissolved in a mixed solvent containing methylene chloride and methanol at a weight ratio of methylene chloride/methanol of 9/1 to obtain a solution with a solid concentration of 16% by weight. The temperature of the solution is adjusted to 25° C., and the solution is subjected to constant-pressure filtration under a pressure of 3 kg/cm2 using a cloth obtained by stacking three sheets of calico (s 618) (diameter: 15 mm, filtration area: 1.77 cm2). At this time, the filtration index k (mL−1) is calculated from the following expression, where P1 represents the amount of filtration (mL) up to 20 minutes after the start of filtration, and P2 represents the amount of filtration (mL) from 0 to 60 minutes. Filtration index K = 2 - P 2 / P 1 P 1 + P 2 × 10 4 [ Mathematical Formula 1 ]
摘要:
The purpose of the present invention is to provide a cellulose acetate which can be used to obtain an optical film having a very small amount of bright spot foreign matters, with excellent production efficiency, even when cellulose containing a small amount of hemicellulose components and having a high degree of crystallinity is used as a raw material. A cellulose acetate in which a content ratio by mole of mannose units to a sum of xylose units, mannose units and glucose units, which are sugar chain components, is 0.04 mol % or less, and a filtration index K measured by the following measurement method is 30 mL−1 or less. (Measurement method) The cellulose acetate is dissolved in a mixed solvent containing methylene chloride and methanol at a weight ratio of methylene chloride/methanol of 9/1 to obtain a solution with a solid concentration of 16% by weight. The temperature of the solution is adjusted to 25° C., and the solution is subjected to constant-pressure filtration under a pressure of 3 kg/cm2 using a cloth obtained by stacking three sheets of calico (s 618) (diameter: 15 mm, filtration area: 1.77 cm2). At this time, the filtration index k (mL−1) is calculated from the following expression, where P1 represents the amount of filtration (mL) up to 20 minutes after the start of filtration, and P2 represents the amount of filtration (mL) from 0 to 60 minutes. Filtration index K = 2 - P 2 / P 1 P 1 + P 2 × 10 4 [ Mathematical Formula 1 ]
摘要:
A plant for continuous production of cellulose triacetate in a heterogeneous phase, comprising consecutively arranged apparatus for activating, acetylation and benzene washings, benzene stripping, partial saponification, water washings and final product drying. The apparatus for activating, the apparatus for acetylation and benzene washings, the apparatus for benzene stripping and the partial saponification apparatus are interconnected by connecting adaptors for conveying the fibrous reaction mass from one apparatus to another and provided with means for creating therein a sealing plug from the conveyed reaction mass. Said means for the creation of the sealing plug is in the form of a screw conveyer with a valve arranged at its discharge orifice and spring-loaded in the direction opposite to the direction of the fibrous reaction mass conveying.
摘要:
An apparatus for continuously producing chemically-modified cellulose, the apparatus having a first mechanism for transporting a fine-powder cellulose fiber starting material and a hydrophobizing chemical substance, a specific extruder, a solvent tank connected to the extruder, and a dryer connected to the solvent tank, and a method for continuously producing chemically-modified cellulose, the method having a step of washing, in the solvent tank, chemically-modified cellulose having been produced out of the fine-powder cellulose fiber starting material and the hydrophobizing chemical substance in the extruder, and then drying the chemically-modified cellulose in the dryer, in order to remove any unreacted hydrophobizing chemical substance.