公开(公告)号：US20230047114A1

公开(公告)日：2023-02-16

申请号：US17779765

申请日：2020-11-11

Applicant: Dow Global Technologies LLC

Inventor： Arkady L. Krasovskiy ,  Ivan A. Konstantinov ,  Sarat Munjal ,  Sean W. Ewart

IPC: C08L23/08 ,  C08F236/06 ,  C08F236/22 ,  C08F2/38 ,  C08F2/01

Abstract: The present disclosure provides a composition. In an embodiment, the composition is an ethylene-based polymer composition formed by high pressure (greater or equal to 100 MPa) free radical polymerization. The composition includes ethylene monomer and a mixture of hydrocarbon-based molecules. Each hydrocarbon-based molecule includes three or more internal alkene groups.

公开(公告)号：US20220017666A1

公开(公告)日：2022-01-20

申请号：US17294538

申请日：2019-11-26

Applicant: Dow Global Technologies LLC

Inventor： Hayley A. Brown ,  Carmelo Declet Perez ,  John O. Osby ,  Sean W. Ewart ,  Sarat Munjal ,  Christopher R. Eddy ,  Mehmet Demirors ,  Jonathan D. Mendenhall ,  Ivan A. Konstantinov ,  Arkady L. Krasovskiy

IPC: C08F210/02 ,  C08F236/06 ,  C08F236/22 ,  C08F2/01 ,  C08L23/08

Abstract: The present disclosure provides a polymer composition. In an embodiment, an ethylene-based polymer composition is provided and is formed by high pressure (greater than or equal to 100 MPa), free-radical polymerization, by reacting: ethylene monomer and a mixture of hydrocarbon-based molecules, with each hydrocarbon-based molecule comprising three or more terminal alkene groups.

公开(公告)号：US20160237222A1

公开(公告)日：2016-08-18

申请号：US15023673

申请日：2014-09-18

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Mehmet Demirors ,  Sean W. Ewart ,  Teresa P. Karjala ,  Maria Pollard

IPC: C08J3/22 ,  C08L23/06

CPC classification number: C08J3/226 ,  C08J2323/06 ,  C08J2423/06 ,  C08K5/0025 ,  C08K5/14 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/025 ,  C08L2205/06 ,  C08L2310/00 ,  C08L23/04

Abstract: A process for increasing the melt strength of a polyethylene resin comprising a) selecting a polyethylene resin having i) a density, as determined according to ASTM D792, in the range of from 0.865 g/cm3 to 0.97 g/cm3, and ii) a melt index, I2, as determined according to ASTM D1238 (2.16 kg, 190° C.), in the range of from 0.01 g/10 min to 100 g/10 min; b) reacting from 10 ppm to 1000 ppm of at least one peroxide having a 1 hour half-life decomposition temperature from 160° C. to 250° C. with the polyethylene resin under conditions sufficient to increase the melt strength of the polyethylene resin is provided. Also provided are a masterbatch composition and a polymeric composition.

Abstract translation: 一种提高聚乙烯树脂的熔体强度的方法，包括：a）选择聚乙烯树脂，其具有i）根据ASTM D792测定的密度在0.865g / cm 3至0.97g / cm 3的范围内，和ii） 熔体指数I2，根据ASTM D1238（2.16kg，190℃）测定，范围为0.01g / 10min至100g / 10min; b）使聚乙烯树脂在足以提高聚乙烯树脂的熔体强度的条件下，使10ppm至1000ppm的至少一种具有1小时半衰期分解温度从160℃至250℃的过氧化物反应为 提供。 还提供了母料组合物和聚合物组合物。

公开(公告)号：US20220411614A1

公开(公告)日：2022-12-29

申请号：US17779726

申请日：2020-11-11

Applicant: Dow Global Technologies LLC

Inventor： Arkady L. Krasovskiy ,  Ivan A. Konstantinov ,  Sarat Munjal ,  Sean W. Ewart

IPC: C08L23/08 ,  C08F36/06 ,  C08F2/01

Abstract: The present disclosure provides a composition. In an embodiment, the composition is an ethylene-based polymer composition formed by high pressure (greater or equal to 100 MPa) free radical polymerization. The ethylene-based polymer composition includes ethylene monomer and a mixture of hydroxyl-terminated polybutadiene molecules (PB-OH). Each PB-OH molecule includes internal alkene groups and terminal alkene groups. Each PB-OH molecule has more internal alkene groups than terminal alkene groups.

公开(公告)号：US11078441B2

公开(公告)日：2021-08-03

申请号：US16332579

申请日：2017-09-19

Applicant: Dow Global Technologies LLC

Inventor： Sean W. Ewart ,  Sarat Munjal ,  Kefu Sun

IPC: C08F10/02 ,  C08F110/02 ,  C10M175/00 ,  C10M129/16 ,  C10M133/40 ,  C10M135/36 ,  C10N40/30

Abstract: A process to prepare an ethylene-based polymer, said process comprising polymerizing a mixture comprising ethylene, at a pressure greater than, or equal to, 100 MPa, in the presence of at least one free-radical initiator; and in a reactor system comprising at least one reactor and at least one Hyper-compressor, and wherein at least one oil formulation, optionally comprising one or more lubrication agents, is added to the Hyper-compressor; and wherein at least one of the following steps takes place: A) thermally treating the one or more lubrication agents, in an oxygen-free atmosphere, to achieve a peroxide level ≤10 ppm, based on the weight of the lubrication agent(s), and then adding said agent(s) to the oil formulation, prior to adding the oil formulation to the Hyper-compressor; or B) thermally treating the oil formulation, in an oxygen-free atmosphere, to achieve a peroxide level ≤10 ppm, based on the weight of the oil formulation, prior to adding the oil formulation to the Hyper-compressor; C) a combination of A and B.

公开(公告)号：US20210205729A1

公开(公告)日：2021-07-08

申请号：US17059757

申请日：2019-05-31

Applicant: Dow Global Technologies LLC

Inventor： Bradley K. Blanchard ,  Maria Pollard ,  Sean W. Ewart

IPC: B01D1/22 ,  B01D1/00 ,  B01D3/06 ,  C08F6/00 ,  F28D1/03 ,  F28D7/12 ,  F28D9/00 ,  F28F3/08 ,  F28F13/08

Abstract: Disclosed herein is a distributor comprising a first conduit; where the first conduit has an inlet port for charging a heating fluid into the distributor; a second conduit; where the first conduit lies inside the second conduit to define a first annular space therebetween; where the second conduit has an exit port for removing the heating fluid from the distributor; a plurality of plate stacks disposed around the second conduit to define a narrowing second annular space from top to bottom of the distributor; where each successive plate stack has smaller inner diameter than the plate stack located above it; where each plate stack comprises a plurality of plates; where the plurality of plates further define a plurality of conduits, each conduit having a varying width over its length and extending radially outwards from the central passage.

公开(公告)号：US09932425B2

公开(公告)日：2018-04-03

申请号：US14569956

申请日：2014-12-15

Applicant: Dow Global Technologies LLC

Inventor： Anthony J. Castelluccio ,  Jeffrey J. Dean ,  Alec Y. Wang ,  Lindsey A. Clark ,  Pradeep Jain ,  Roger L. Kuhlman ,  Angela N. Taha ,  Larry S. Green ,  Gary R. Marchand ,  Sean W. Ewart ,  Jeffrey A. Sims ,  Chris E. Blaschke ,  Brandon Fails

IPC: C08F210/14 ,  C08K5/52 ,  C08K5/12 ,  C08K5/17 ,  C08L23/08 ,  C08F297/08 ,  C08L53/00 ,  C08F6/02 ,  C08K5/098 ,  C08F210/16

CPC classification number: C08F210/14 ,  C08F6/02 ,  C08F210/16 ,  C08F297/08 ,  C08F297/083 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/20 ,  C08K5/098 ,  C08K5/12 ,  C08K5/17 ,  C08K5/52 ,  C08L23/0815 ,  C08L53/00 ,  C08L2666/02

Abstract: Improved reaction processes comprise reacting a mixture to form a product comprising a metal alkyl, metal oxide, or mixture thereof and then passing said product to a post-reactor heat exchanger. The improvement comprises one or more of the following: (1) reacting said metal alkyl compound with an acid to produce a soluble metal ester; or (2) adding an ionic surfactant; or (3) adding a mixture comprising an antioxidant to the product under conditions sufficient to avoid formation of significant amounts of insoluble metal or metal compounds derived from said metal alkyl compound; or (4) purging said post-reactor heat exchanger with an inert gas under conditions to remove metal oxide from the post-reactor heat exchanger.

公开(公告)号：US20170335034A1

公开(公告)日：2017-11-23

申请号：US15646322

申请日：2017-07-11

Applicant: Dow Global Technologies LLC

Inventor： Otto J. Berbee ,  Stefan Hinrichs ,  Christopher R. Eddy ,  Sarat Munjal ,  John O. Osby ,  Sean W. Ewart

IPC: C08F210/02 ,  C09D123/04

CPC classification number: C08F210/02 ,  C09D123/04 ,  Y02P20/582 ,  C08F2220/281 ,  C08F2220/282 ,  C08F2/01

Abstract: A process to form an ethylene-based polymer including polymerizing ethylene and at least one asymmetrical polyene comprising an “alpha, beta unsaturated-carbonyl end” (“α,β unsaturated-carbonyl end”) and a “C—C double bond end,” wherein the polymerization takes place in the presence of at least one free-radical initiator; and wherein the polymerization takes place in a reactor configuration comprising at least two reaction zones, reaction zone 1 and reaction zone i (i≧2), wherein reaction zone i is downstream from reaction zone 1.

公开(公告)号：US09328180B2

公开(公告)日：2016-05-03

申请号：US14404876

申请日：2013-03-08

Applicant: Dow Global Technologies LLC

Inventor： Sean W. Ewart ,  Teresa P. Karjala ,  Michael J. Zogg, Jr. ,  Sarat Munjal

IPC: C08F2/38 ,  C08F4/00 ,  C08F4/44 ,  C08F4/28 ,  C08F210/00 ,  C08F110/02

CPC classification number: C08F110/02 ,  C08F2/38 ,  C08F4/34 ,  C08F4/52 ,  C08F2500/03 ,  C08F2500/10 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/26

Abstract: The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene in presence of at least the following: A) a free-radical agent; B) an alkylated phenol selected from Formula (I), wherein R1, R2,R3, R4 and R5 are each, independently, hydrogen or an alkyl; and C) a “metal alkyl-containing compound” selected from the group consisting of the following: i) at least one “Group II metal alkyl-containing compound,” ii) at least one “Group III metal alkyl-containing compound,” and iii) a combination of i) and ii).

Abstract translation: 本发明提供一种形成乙烯基聚合物的方法，所述方法包括在至少以下条件下聚合乙烯：A）自由基试剂; B）选自式（I）的烷基化苯酚，其中R 1，R 2，R 3，R 4和R 5各自独立地为氢或烷基; 和C）选自以下的“含金属烷基的化合物”：i）至少一种“第II族金属烷基化合物”，ii）至少一种“含III族金属烷基的化合物”， 和iii）i）和ii）的组合。

公开(公告)号：US11236182B2

公开(公告)日：2022-02-01

申请号：US16977287

申请日：2019-03-25

Applicant: Dow Global Technologies LLC

Inventor： Evelyn Auyeung ,  Sean W. Ewart ,  Daniela Ferrari ,  Thomas Davidian ,  Rony Vanspeybroeck

IPC: C08F10/02 ,  C08F2/06 ,  C08F6/02 ,  C08F2/42 ,  C08F110/14

Abstract: A solution polymerization process for producing ethylene-based polymer includes introducing ethylene monomer, hydrocarbon solvent, and Ziegler-Natta catalyst into an entrance of a solution polymerization reactor. An ethylene-based polymer is produced by solution polymerizing the ethylene monomer in hydrocarbon solvent. Subsequently, a catalyst deactivator is introduced into x the exit of the solution polymerization reactor, thereby producing hydrochloric acid byproduct. The catalyst deactivator includes long chain carboxylate and at least one cation selected from Groups 1, 2, and 12 of the IUPAC periodic table, with the exception of calcium. The catalyst deactivator reduces the effectiveness of the Ziegler-Natta catalyst and neutralizes the hydrochloric acid by forming a chloride salt other than calcium chloride.