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公开(公告)号：US06967184B2
公开(公告)日：2005-11-22
申请号：US10780438
申请日：2004-02-17
Applicant: Timothy T. Wenzel , Zondra Dee Dixon
Inventor： Timothy T. Wenzel , Zondra Dee Dixon
CPC classification number: C08F10/00 , C07F7/003 , C08F210/16 , C08F210/14 , C08F4/64148
Abstract: A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 14 to Group 16 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.
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公开(公告)号：US07718566B2
公开(公告)日：2010-05-18
申请号：US12313854
申请日：2008-11-25
Applicant: Timothy T. Wenzel , Zondra Dee Dixon
Inventor： Timothy T. Wenzel , Zondra Dee Dixon
CPC classification number: C08F10/00 , C07F7/003 , C08F210/16 , C08F210/14 , C08F4/64148
Abstract: A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 15 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.
Abstract translation: 提供了一种用于烯烃聚合的催化剂组合物和方法。 在一个方面，催化剂组合物由式αa和bgr;bγgMXn表示，其中M是金属; X是卤代芳氧基; ＆bgr 并且γ是各自包含至少一个15族原子的基团; α是连接部分，其形成与每个化合物的化学键; 和γ; a，b，g和n分别为1〜4的整数。
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公开(公告)号：US20090082195A1
公开(公告)日：2009-03-26
申请号：US12313854
申请日：2008-11-25
Applicant: Timothy T. Wenzel , Zondra Dee Dixon
Inventor： Timothy T. Wenzel , Zondra Dee Dixon
CPC classification number: C08F10/00 , C07F7/003 , C08F210/16 , C08F210/14 , C08F4/64148
Abstract: A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 15 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.
Abstract translation: 提供了一种用于烯烃聚合的催化剂组合物和方法。 在一个方面，催化剂组合物由式alphamatabgammagMXn表示，其中M是金属; X是卤代芳氧基; β和γ是各自包含至少一个15族原子的基团; α是与β和γ各自形成化学键的连接部分; a，b，g和n分别为1〜4的整数。
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4.发明授权Fluoralcohol leaving group for non-metallocene olefin polymerization catalysts 有权非茂金属烯烃聚合催化剂的氟醇离去基团公开(公告)号：US07479529B2
公开(公告)日：2009-01-20
申请号：US11633197
申请日：2006-12-04
Applicant: Timothy T. Wenzel , Zondra Dee Dixon
Inventor： Timothy T. Wenzel , Zondra Dee Dixon
CPC classification number: C08F10/00 , C07F7/003 , C08F210/16 , C08F210/14 , C08F4/64148
Abstract: A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 14 to Group 16 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.
Abstract translation: 提供了一种用于烯烃聚合的催化剂组合物和方法。 在一个方面，催化剂组合物由式alphamatabgammagMXn表示，其中M是金属; X是卤代芳氧基; β和γ是各自包含至少一个第14族至第16族原子的基团; α是与β和γ各自形成化学键的连接部分; a，b，g和n分别为1〜4的整数。
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5.发明授权Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts 有权氟金属离去基团用于非茂金属烯烃聚合催化剂公开(公告)号：US07196032B2
公开(公告)日：2007-03-27
申请号：US11196622
申请日：2005-08-03
Applicant: Timothy T. Wenzel , Zondra Dee Dixon
Inventor： Timothy T. Wenzel , Zondra Dee Dixon
CPC classification number: C08F10/00 , C07F7/003 , C08F210/16 , C08F210/14 , C08F4/64148
Abstract: A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 14 to Group 16 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.
Abstract translation: 提供了一种用于烯烃聚合的催化剂组合物和方法。 在一个方面，催化剂组合物由下式表示：其中M（M） 是金属; X是卤代芳氧基; β和γ是各自包含至少一个第14族至第16族原子的基团; α是与β和γ各自形成化学键的连接部分; a，b，g和n分别为1〜4的整数。
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Patent Agency Ranking
公开(公告)号：US07163991B2
公开(公告)日：2007-01-16
申请号：US11193663
申请日：2005-07-29
Applicant: Timothy T. Wenzel , Zondra Dee Dixon
Inventor： Timothy T. Wenzel , Zondra Dee Dixon
CPC classification number: C08F10/00 , C07F7/003 , C08F210/16 , C08F210/14 , C08F4/64148
Abstract: A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 14 to Group 16 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.
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7.发明申请公开(公告)号：US20150148502A1
公开(公告)日：2015-05-28
申请号：US14116788
申请日：2012-05-11
Applicant: Matthew D. Christianson , Timothy S. De Vries , Robert D. Froese , Matthias S. Ober , Jasson T. Patton , Duane R. Romer , Gordon R. Roof , Lixin Sun , Endre Szuromi , Curt N. Theriault , Dean M. Welsh , Timothy T. Wenzel , Paul H. Moran
Inventor： Matthew D. Christianson , Timothy S. De Vries , Robert D. Froese , Matthias S. Ober , Jasson T. Patton , Duane R. Romer , Gordon R. Roof , Lixin Sun , Endre Szuromi , Curt N. Theriault , Dean M. Welsh , Timothy T. Wenzel , Paul H. Moran
IPC: C08F4/78 , C08F210/06 , C07F11/00 , C08F110/06
CPC classification number: C08F4/78 , C07F11/00 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F4/69112 , C08F210/16 , C08F2500/15
Abstract: Provided is a non-cyclopentadienyl-based chromium-ligand complex, preferably a chromium-ligand complex of formula (J): LCr(RA)m(D)k (J), wherein L is a non-Cp monoanionic ligand; Cr (chromium) is in a formal oxidation state of +3 or +2; when Cr formally is Cr+3, either m is 1 and RA is hydrocarbylene (a hydrocarbylene chromium-ligand complex of formula (J)) or m is 2 and each RA independently is hydrocarbyl (a dihydrocarbyl chromium-ligand complex of formula (J)), wherein each hydrocarbyl or hydrocarbylene of RA independently is unsubstituted or substituted by from 1 to 5 RAS; each RAS independently is a neutral aprotic heteroalkyl, neutral aprotic heterocycloalkyl, neutral aprotic heteroaryl, or neutral aprotic aryl; when Cr formally is Cr+2, m is 1 and RA is hydrocarbyl (a hydrocarbyl chromium-ligand complex of formula (J)); k is an integer of 0 or 1; D is absent when k is 0 or D is a neutral ligand when k is 1; wherein the chromium-ligand complex of formula (J) is overall neutral and lacks a cyclopentadienyl-based (Cp-based) moiety. Also provided is a chromium catalyst comprising or prepared from the complex. Also provided is a process of making the catalyst and a process employing the chromium catalyst for polymerizing the olefin monomer, especially a straight chain 1-alkene, to prepare the polyolefin, especially a partially chain-straightened poly(1-alkene) or olefin block copolymer. Further provided is the partially chain-straightened poly(1-alkene) or olefin block copolymer prepared thereby. Also provided is a high throughput workflow.
Abstract translation: 提供非环戊二烯基铬配体络合物，优选式（J）的铬 - 配体络合物：LCr（RA）m（D）k（J），其中L是非-C 1单阴离子配体; Cr（铬）处于+3或+2的正式氧化态; 当Cr正式为Cr + 3时，m为1，RA为亚烃基（式（J））的亚烃基铬 - 配体配合物）或m为2，各RA独立地为烃基（式（J）的二烃基铬 - 配体络合物 ）），其中RA的各个烃基或亚烃基独立地未被取代或被1至5个RAS取代; 每个RAS独立地是中性非质子杂烷基，中性非质子性杂环烷基，中性非质子杂芳基或中性非质子性芳基; 当Cr正式为Cr + 2时，m为1，RA为烃基（式（J））的烃基铬 - 配体络合物）; k是0或1的整数; 当k为0时，D不存在，或当k为1时D为中性配体; 其中式（J）的铬配体络合物是总体中性的，并且缺少基于环戊二烯基的（Cp-基）部分。 还提供了包含或由络合物制备的铬催化剂。 还提供了制备催化剂的方法和使用铬催化剂聚合烯烃单体，特别是直链1-烯烃的方法，以制备聚烯烃，特别是部分链改性的聚（1-烯烃）或烯烃嵌段 共聚物。 进一步提供由其制备的部分链直链化的聚（1-烯烃）或烯烃嵌段共聚物。 还提供了高吞吐量的工作流程。
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8.发明授权公开(公告)号：US08048961B2
公开(公告)日：2011-11-01
申请号：US12377030
申请日：2007-08-23
Applicant: Daniel J. Arriola , Brian A. Jazdzewski , Francis J. Timmers , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
Inventor： Daniel J. Arriola , Brian A. Jazdzewski , Francis J. Timmers , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
IPC: C08F8/00
CPC classification number: C08L53/00 , C08F299/00 , C08L53/005 , C08L2666/02
Abstract: A cross-metathesized product mixture is prepared by contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more chemically distinguishable ethylenically unsaturated polymers, at least one of said ethylenically unsaturated polymers (first polymer) having from 0.001 to 50 mole percent unsaturation and at least one other of said ethylenically unsaturated polymers (second polymer) being an amorphous polymer having a Tg less than 0° C. and having from 0.001 to 5 mole percent unsaturation.
Abstract translation: 通过在复分解条件下使复分解催化剂与包含两种或多种化学上可区分的烯键式不饱和聚合物的组合物，至少一种所述烯键式不饱和聚合物（第一聚合物）具有0.001至50摩尔％的不饱和度和 所述烯属不饱和聚合物（第二聚合物）中的至少一种是具有Tg小于0℃并具有0.001至5摩尔％不饱和度的无定形聚合物。
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9.发明申请Catalyst Composition Comprising Shuttling Agent for Ethylene Multi-Block Copolymer Formation 有权催化剂组合物包含乙烯多嵌段共聚物形成的穿梭剂公开(公告)号：US20110118416A1
公开(公告)日：2011-05-19
申请号：US12962800
申请日：2010-12-08
Applicant: Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
Inventor： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
IPC: C08F210/16
CPC classification number: B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
Abstract translation: 一种用于形成多嵌段共聚物的组合物，所述共聚物中含有两个或更多个化学或物理性质不同的链段或嵌段，使用该多嵌段共聚物的聚合方法和所得聚合物，其中组合物包含混合物或反应产物 由（A）第一金属络合物烯烃聚合催化剂，（B）能够在等效聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二金属络合物烯烃聚合催化剂，以及 （C）链式穿梭剂。
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公开(公告)号：US20100069573A1
公开(公告)日：2010-03-18
申请号：US12377034
申请日：2007-08-23
Applicant: Daniel J. Arriola , Francis J. Timmers , Brian A. Jazdzewski , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
Inventor： Daniel J. Arriola , Francis J. Timmers , Brian A. Jazdzewski , Paul C. Vosejpka , Nicole L. Wagner , Brian G. Landes , Guenter A. Jueptner , David H. Bank , Timothy T. Wenzel
CPC classification number: C08G81/00 , C08F36/04 , C08F210/02 , C08F210/18 , C08F295/00 , C08F297/00 , C08F297/04 , C08F297/044 , C08F297/06 , C08F299/00 , C08F299/04 , C08F299/0478 , C08G81/024 , C08L53/00 , C08L53/02 , C08L2666/02 , C08F236/06 , C08F210/14
Abstract: Meta-block copolymers and a process for preparing a product mixture comprising meta-block copolymers by contacting a metathesis catalyst under metathesis conditions with a composition comprising two or more ethylenically unsaturated polymers, said unsaturation defining one or more polymer segments in each ethylenically unsaturated polymer, at least one polymer segment in at least one ethylenically unsaturated polymer being chemically distinguishable from at least one polymer segment in at least one other ethylenically unsaturated polymer, characterized in that each meta-block copolymer in the product mixture comprises a random distribution of said chemically distinguishable polymer blocks.
Abstract translation: 元嵌段共聚物和通过使复分解催化剂在复分解条件下与包含两种或更多种烯属不饱和聚合物的组合物接触的复分解催化剂来制备产物混合物的方法，所述不饱和键定义每个烯属不饱和聚合物中的一个或多个聚合物链段， 至少一种烯键式不饱和聚合物中的至少一个聚合物链段与至少一种其它烯属不饱和聚合物中的至少一个聚合物链段在化学上是可区分的，其特征在于产物混合物中的每个间位嵌段共聚物包括所述化学可区分的 聚合物嵌段。
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