Stabilization of organic amide solvents and polymer solutions thereof
    1.
    发明授权
    Stabilization of organic amide solvents and polymer solutions thereof 失效
    有机酰胺溶剂及其聚合物溶液的稳定化

    公开(公告)号:US4144213A

    公开(公告)日:1979-03-13

    申请号:US797842

    申请日:1977-05-17

    申请人: Tad L. Patton

    发明人: Tad L. Patton

    CPC分类号: C08K5/42 C08K5/20 C08K5/49

    摘要: Organic amides, solutions of polymers thereof, which polymers are subject to hydrolysis and degradation in the presence of amines, and polymers isolated therefrom are stabilized by the presence of aromatic sulfonic acid esters of aliphatic, arylaliphatic and alicyclic alcohols and polyols.

    摘要翻译: 有机酰胺,其聚合物溶液,聚合物在胺存在下进行水解和降解,以及从其中分离的聚合物通过脂族,芳基脂族和脂环族醇和多元醇的芳族磺酸酯的存在来稳定。

    Process for the production of 1,3-propanediol
    4.
    发明授权
    Process for the production of 1,3-propanediol 失效
    1,3-丙二醇生产工艺

    公开(公告)号:US6140543A

    公开(公告)日:2000-10-31

    申请号:US16444

    申请日:1998-01-30

    CPC分类号: C07C45/64 C07C29/141 C08F8/00

    摘要: A process for the production of 1,3-propanediol by hydrating acrolein in the presence of an ion exchanger to form 3-hydroxypropionaldehyde includes reacting acrolein and water in a ratio by weight of 1:2 to 1:20 at 30.degree. to 120.degree. C. and a pressure in the range from 1 to 20 bar, in the presence of an ion exchange hydration catalyst. The ion exchanger and any unreacted acrolein are separated from the reaction mixture. The 3-hydroxypropionaldehyde is then catalytically hydrogenated in a liquid or gas phase using hydrogenation catalysts. The ion exchanger hydration catalyst includes polyamine/polycarboxylic acid resins produced by reacting polyamine resins based on a crosslinked polyacrylamide matrix with acrylic acid, acrylic acid derivatives or a salt of an .omega.-haloalkanoic acid. An ion exchanger includes reaction product of reacting a polyamine resin based on a crosslinked polyacrylamide matrix with acrylic acid, acrylic acid derivatives or .omega.-haloalkanoic acid salts.

    摘要翻译: 在离子交换剂存在下,通过水合丙烯醛形成3-羟基丙醛生产1,3-丙二醇的方法包括使丙烯醛与水的重量比在1:20至1:20的范围内,在30°至120° 并且在离子交换水合催化剂存在下,在1至20巴的范围内的压力。 将离子交换剂和任何未反应的丙烯醛与反应混合物分离。 然后使用氢化催化剂在液相或气相中将3-羟基丙醛催化氢化。 离子交换剂水合催化剂包括通过基于交联聚丙烯酰胺基质的聚胺树脂与丙烯酸,丙烯酸衍生物或ω-卤代烷酸的盐反应制备的多胺/多元羧酸树脂。 离子交换剂包括使基于交联的聚丙烯酰胺基质的聚胺树脂与丙烯酸,丙烯酸衍生物或ω-卤代烷酸盐反应的反应产物。

    Method for the production of aluminum coatings
    8.
    发明授权
    Method for the production of aluminum coatings 失效
    生产铝涂层的方法

    公开(公告)号:US3761432A

    公开(公告)日:1973-09-25

    申请号:US3761432D

    申请日:1971-06-03

    发明人: FRITSCHE P

    摘要: IMPROVED FILM-FORMING ORGANIC RESIN PAINT AQUEOUS BINDER REPLENISHMENT CONCENTRATED COMPOSITION ADAPTED FOR DISPERSING IN AN AQUEOUS ELECTROCOATING BATH CONTAINING SUSPENDED ALUMINUM POWDER AND SUFFICIENT ADDITIONAL WATER-SOLUBLE AMINO COMPOUND TO IMPART ANIONIC POLYELECTROLYTE BEHAVIOR IN SAID BATH TO RESIN IN SAID BINDER CONCENTRATE COMPOSITION, SAID BINDER CONCENTRATE COMPOSITION COMPRISING: (I) ABOUT 10-50 PERCENT WEIGHT OF A NON-HEAT REACTVE PHENOL-ALDEHYDE RESIN; AND (II) ABOUT 50-90 PERCENT BY WEIGHT OF A A COPOLYMER, SAID COPOLYMER COMPRISING: (A) ABOUT 50-85 PERCENT BY WEIGHT OF AN ESTER OF METHACRYLIC ACID OR ACRYLIC ACID WITH AN ALCOHOL HAVING 1-10 CARBON ATOMS; (B) ABOUT 5-20 PERCENT BY WEIGHT OD DRYING OILS OR DRYING OIL FATTY ACIDS CONTAINING OLEFINICALLY UNSATURATED FATTY ACIDS; (C) ALBOUT 5-15 PERCENT BY WEIGHT OF AN A,B-OLEFINICALLY UNSATURATED CARBOXYLIC ACID HAVING 3-5 CARBON ATOMS; (D) ABOUT 3-20 PERCENT BY WEIGHT OF METHACRYLAMIDE, ACRYLAMIDE, METHYLOL METHACRYLAMIDE, METHYLOL ACRYLAMIDE, AN ETHER OF METHYLOL METHACRYLAMIDE WITH AN ALCOHOL HAVING 1-8 CARBON ATOMS, AN ETHER OF METHYLOL ACRYLAMIDE HAVING 1-8 CARBON ATOMS OR A MIXTURE THEREOF; AND OPTIONALLY (E) UP TO 20 PERCENT BY WEIGHT OF FURTHER COPOLYMERIZABLE OLEFINICALLY UNSATURATD COMPOUNDS.

    Oil modified polyurethane coatings
    9.
    发明授权
    Oil modified polyurethane coatings 失效
    油改性聚氨酯涂料

    公开(公告)号:US3749686A

    公开(公告)日:1973-07-31

    申请号:US3749686D

    申请日:1971-02-22

    发明人: PAWLAK J BEAN C

    CPC分类号: C08G8/28 C08G18/28 C08G18/546

    摘要: THIS INVENTION RELATES TO OIL MODIFIED POLYURETHANE COATINGS AND THE PROCESS FOR MAKING SAID COATINGS, COMPRISING THE STEPS OF REACTING FROM ABOUT 0.95 TO 1.1 ISOCYANATE GROUPS ON AN ORGANIC POLYISOCYANATE WITH EACH HYDROXYL GROUPS ON A POLYOL, WHEREIN THE POLYOL IS FORMED BY REACTING FROM 1.1 TO 4 MOLES OF PHENOL WITH EACH MOLE OF AN ALDEHYDE SO AS TO FORM A NOVOLAK RESIN WHICH HAS FROM ABOUT 1.1/1 TO 2/1 PHENOLIC GROUPS PER ALDEHYDIC GROUP PER MOLECULE, ALKYLATING THE NOVOLAK RESIN WITH FROM ABOUT 0.1 TO 2 MOLES OF ALKYLATING AGENT PER MOLE OF PHENOLIC NUCLEUS ON THE NOVOLAK RESIN, HYDROXYALKYLATING THE NOVOLAK RESIN WITH FROM ABOUT 1 TO 6 MOLES OF HYDROXYALKYLATING AGENT PER MOLE OF PHENOLIC HYDROXYL ON THE NOVOLAK RESIN, AND ESTERIFYING OR TRANSESTERIFYING THE HYDROXYALKYLATED PRODUCT WITH FROM 0.33 TO 1 MOLE OF ESTERFYING OR TRANSESTERIFYING AGENT PER MOLE OF HYDROXYL ON THE HYDROXYALKYLATED PRODUCT. VARNISHES AND OTHER COATINGS CAN BE PREPARED FROM THE OIL MODIFIED POLYURETHANES OF THIS INVENTION AND EXHIBIT SUPERIOR RESISTANCE TO CAUSTIC.