公开(公告)号：US06172139B2

公开(公告)日：2001-01-09

申请号：US08146981

申请日：1993-11-02

申请人： Gwo S. Swei ,  David J. Arthur

发明人： Gwo S. Swei ,  David J. Arthur

IPC分类号： C08J305

CPC分类号： C08J9/26 ,  B29C41/28 ,  B29D7/01 ,  B29K2027/18 ,  B29K2105/04 ,  B29K2105/16 ,  B29K2995/0006 ,  C08J3/005 ,  C08J3/215 ,  C08J2327/12 ,  H05K1/034 ,  H05K1/0373 ,  H05K1/056 ,  H05K3/386 ,  H05K2201/015 ,  H05K2201/0209 ,  H05K2201/0212 ,  H05K2201/0215 ,  H05K2201/0239 ,  Y02P20/582

摘要： A method for making a particulate filled polymeric matrix composite film includes mixing a polymeric matrix material with a dispersion of particulate filler in a carrier liquid to form a casting composition and adjusting the viscosity of the casting composition to retard separation of the particulate filler from the composition. A layer of the viscosity-adjusted casting composition is cast on a substrate and the layer is consolidated to form the particulate filled polymer matrix composite film. Films made by the method include very thin, e.g less than 1.0 mil, fluoropolymeric matrix films highly filled with very small diameter, preferably spherical, particles for use as, e.g. dielectric substrate materials in laminar electrical circuits.

摘要翻译： 制备颗粒填充的聚合物基质复合膜的方法包括将聚合物基体材料与颗粒填料的分散体混合在载体液体中以形成流延组合物并调节流延组合物的粘度以阻止颗粒填料与组合物的分离 。 将粘度调节的浇铸组合物的一层浇铸在基材上，并将该层固结以形成填充颗粒的聚合物基质复合膜。 通过该方法制备的膜包括非常薄的，例如小于1.0密耳的高度填充有非常小直径，优选球形的颗粒的含氟聚合物基质膜，用于例如， 层状电路中的电介质基片材料。

公开(公告)号：US06521679B1

公开(公告)日：2003-02-18

申请号：US09786205

申请日：2001-03-02

申请人： Yasuo Okada ,  Hidenori Kaya ,  Suguru Tokita

发明人： Yasuo Okada ,  Hidenori Kaya ,  Suguru Tokita

IPC分类号： C08J305

CPC分类号： C08J3/03 ,  C08J2367/02 ,  C08L67/02 ,  C08L2201/50 ,  C08L2666/18

摘要： A polyester aqueous dispersion having excellent properties in waterproof, weatherproof, processibility and adhesion, which provides a large allowance for controlling liquid physical properties by post treatment and is advantageous in making dry powders from the dispersion, and an efficient method for preparing the aqueous dispersion at low costs in a simple manner. The polyester aqueous dispersion comprising (i) a water-insoluble polyester and (ii) a polyester containing a sulfonate group bound to a polymer in a concentration of 0.1 to 1.5 mmol equivalents when calculated as —SO3− group per gram of the polymer, and method for preparing a polyester aqueous dispersion comprises a step of melt-kneading a resin composition comprising the water-insoluble polyester (i) and polyester (ii) and a step of phase inversion of adding water or a basic aqueous solution to the molten kneaded mixture thereby to shift the resin composition into the aqueous dispersion.

摘要翻译： 一种聚酯水性分散体，其具有优异的防水性，耐候性，可加工性和粘合性，通过后处理提供了大量的液体物理性能的限制，并且有利于从分散体制备干燥粉末，以及制备水性分散体的有效方法 低成本简单。 所述聚酯水性分散体包含（i）水溶性聚酯和（ii）含有磺酸盐基团的聚酯，所述磺酸盐基团以每克聚合物的-SO 3 - 基团计算，浓度为0.1〜1.5mmol当量的聚合物，以及 制备聚酯水分散体的方法包括熔融捏合包含水不溶性聚酯（i）和聚酯（ii）的树脂组合物的步骤和将水或碱性水溶液加入到熔融混炼混合物中的相转化步骤 从而将树脂组合物转移到水性分散体中。

公开(公告)号：US06512024B1

公开(公告)日：2003-01-28

申请号：US09574926

申请日：2000-05-19

申请人： Richard A. Lundgard ,  James E. Pate, III ,  Christian Piechocki ,  Peter T. Keillor, III ,  Nanette E. Lutenske ,  Ira Thumma

发明人： Richard A. Lundgard ,  James E. Pate, III ,  Christian Piechocki ,  Peter T. Keillor, III ,  Nanette E. Lutenske ,  Ira Thumma

IPC分类号： C08J305

CPC分类号： C08J3/005 ,  B29C47/0004 ,  B29C47/0009 ,  B29C47/367 ,  C08G18/0804 ,  C08G18/0895 ,  C08J3/03 ,  C09D5/44

摘要： Stable aqueous dispersions or emulsions can be prepared by merging into a mechanical disperser a stream of a molten or liquid disperse phase with a stream of a molten or liquid continuous phase to form a dispersion or emulsion. The molten or liquid disperse phase stream contains a polymer that is preferably a solid at room temperature, but molten at some advanced temperature. The polymer is formed in a molten state or formed and melted by a continuous reaction process such as an extrusion process, including melt extrusion or compound extrusion. It has been discovered that low polydisperse submicron sized dispersion can be prepared by the method of the present invention.

摘要翻译： 稳定的水性分散体或乳液可以通过将熔融或液体分散相的物流与熔融或液体连续相流合并成机械分散器来形成分散体或乳液来制备。 熔融或液体分散相流含有在室温下优选为固体但在一些高温下熔融的聚合物。 聚合物形成为熔融状态，或通过包括熔融挤出或复合挤出在内的连续反应过程如挤出方法形成和熔融。 已经发现，可以通过本发明的方法制备低分散亚微米尺寸的分散体。

公开(公告)号：US06228931B1

公开(公告)日：2001-05-08

申请号：US09264883

申请日：1999-03-09

申请人： Werner Wilfinger ,  Ingo Kreissmann ,  Kurt Gossak ,  Johann Luttenberger

发明人： Werner Wilfinger ,  Ingo Kreissmann ,  Kurt Gossak ,  Johann Luttenberger

IPC分类号： C08J305

CPC分类号： C08G81/021 ,  C09D5/027

摘要： A low-solvent aqueous binder includes: a water-insoluble synthetic resin component A; and an emulsifier resin B in a mass ratio of A to B of from 70:30 to 30:70. The emulsifier resin B is a reaction product of a water-insoluble synthetic resin B1 that includes hydroxyl groups as functional groups, a synthetic resin B2 that includes carboxyl groups as functional groups, and a neutralizing agent for the carboxyl groups of B. The amount of the neutralizing agent is such that the neutralizing agent is able to neutralize from 5 to 200% of the carboxyl groups of B. A process for preparing a low-solvent aqueous binder includes: mixing the water-insoluble synthetic resin component B1 comprising hydroxyl functional groups and the synthetic resin B2 in bulk or dissolved in an organic solvent to form a mixture; removing the solvent by applying subatmospheric pressure and heating until the content of the mixture is at least 85% by mass; maintaining the mixture at a temperature from 90° to 150° C. until the reaction product of the mixture is homogeneously emulsifiable in a mass ratio of 3 parts of resin to 7 parts of water; neutralizing the reaction product by adding a neutralizing agent in an amount sufficient to neutralize from 5 to 200% of carboxyl groups that have remained following the reaction; adding the water-insoluble synthetic resin A in a mass ratio of A to B of from 70:30 to 30:70, and emulsifying the mixture in water.

摘要翻译： 低溶剂水性粘合剂包括：不溶于水的合成树脂组分A; 和A〜B的质量比为70:30〜30:70的乳化树脂B. 乳化树脂B是包含羟基作为官能团的水不溶性合成树脂B1，包含羧基作为官能团的合成树脂B2和B的羧基中和剂的反应产物。 中和剂使得中和剂能够中和B的羧基的5〜200％。制备低溶剂水性粘合剂的方法包括：将包含羟基官能团的水不溶性合成树脂组分B1 和合成树脂B2本体或溶解在有机溶剂中以形成混合物; 通过施加低于大气压并加热直到混合物的含量为至少85质量％除去溶剂; 将混合物保持在90℃至150℃的温度下，直到混合物的反应产物以3份树脂与7份水的质量比均匀乳化; 通过加入足以中和反应后残留的羧基的5〜200％的中和剂中和反应产物; 将A〜B的质量比为70:30〜30:70的水不溶性合成树脂A加入水中，使其混合。

公开(公告)号：US06774181B1

公开(公告)日：2004-08-10

申请号：US10612576

申请日：2003-07-01

申请人： Ibrahim Bechara ,  Pavel Ilmenev ,  Oleg Tselnik

发明人： Ibrahim Bechara ,  Pavel Ilmenev ,  Oleg Tselnik

IPC分类号： C08J305

CPC分类号： C08J7/047 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/6541 ,  C08G18/698 ,  C08J3/03 ,  C08J2323/08 ,  C08J2423/00 ,  C08J2475/00 ,  C08L23/12 ,  C08L71/02 ,  C08L2205/05 ,  C09D123/0869 ,  C09D175/04 ,  C08G18/3231 ,  C08L2666/04 ,  C08L2666/22 ,  C08L2666/06

摘要： A process for making an aqueous emulsion of self-emulsifiable polyolefin employs a high molecular weight functionalized polyolefin and a hydrophilic polymer. The aqueous emulsion can be used to prepare a hybrid polyolefin-polyurethane dispersion useful, inter alia, as an adhesion-promoting coating for polymers such as the polyolefins.

摘要翻译： 制备自乳化聚烯烃水乳液的方法采用高分子量官能化聚烯烃和亲水聚合物。 水性乳液可以用于制备混合聚烯烃 - 聚氨酯分散体，特别是可用作聚合物如聚烯烃的粘合促进涂层。

公开(公告)号：US06437036B1

公开(公告)日：2002-08-20

申请号：US09441810

申请日：1999-11-17

申请人： Michael A. Gessner ,  Timothy P. Kandow

发明人： Michael A. Gessner ,  Timothy P. Kandow

IPC分类号： C08J305

CPC分类号： C09D175/04 ,  C08G18/0819 ,  C08L75/04 ,  C09D133/06 ,  Y10T428/31551 ,  Y10T428/31605 ,  C08L2666/14

摘要： The invention provides a thermosetting aqueous primer composition that includes a polyurethane polymer, an acrylic polymer, and a crosslinking component that is reactive with at least one of the polyurethane polymer and the acrylic polymer. The polyurethane polymer has a glass transition temperature of 0° C. or less. The acrylic polymer has a glass transition temperature that is at least about 20° C. higher than the glass transition temperature of polyurethane resin. The invention further provides a composite coating having as a primer layer a cured layer of the primer composition of the invention and having at least one topcoat layer.

摘要翻译： 本发明提供一种热固性水性底漆组合物，其包含聚氨酯聚合物，丙烯酸聚合物和与至少一种聚氨酯聚合物和丙烯酸聚合物反应的交联组分。 聚氨酯聚合物的玻璃化转变温度为0℃以下。 丙烯酸类聚合物的玻璃化转变温度比聚氨酯树脂的玻璃化转变温度高至少约20℃。 本发明还提供一种复合涂层，其具有底漆层本发明的底漆组合物的固化层并具有至少一个外涂层。

公开(公告)号：US06221952B1

公开(公告)日：2001-04-24

申请号：US09093343

申请日：1998-06-09

申请人： Masato Nakamae

发明人： Masato Nakamae

IPC分类号： C08J305

CPC分类号： C08J3/03 ,  C08J2357/00 ,  C08L31/04 ,  C08L33/12 ,  C08L61/18 ,  C08L2666/14 ,  C09J131/04

摘要： An aqueous emulsion composition is provided that includes, as the dispersoid, a (co)polymer that contains at least one monomer unit selected from ethylenic unsaturated monomers and dienic monomers, and, as the dispersant, (A) a polyvinyl alcohol (co)polymer, and (B) a condensate of an alkali metal salt of an aromatic sulfonic acid with formaldehyde in a ratio, (A)/(B), of from 100/0.05 to 100/100 in terms of the solid content of the two. The composition is characterized by its fluidity such that the apparent viscosity of the composition is prevented from being lowered relative to the increase in the shear rate of the composition, and that the apparent viscosity of the composition is increased relative to the increase in the shear rate thereof. In addition, the composition has excellent high initial adhesiveness and viscosity-increasing ability.

摘要翻译： 提供一种水性乳液组合物，其包含作为分散质的包含至少一种选自烯属不饱和单体和二烯单体的单体单元的（共）聚合物，并且作为分散剂，（A）聚乙烯醇（共）聚合物 ，和（B）芳族磺酸的碱金属盐与甲醛的比例（A）/（B）为100 / 0.05〜100/100的两者的固体含量的缩合物。 组合物的特征在于其流动性，使得防止组合物的表观粘度相对于组合物的剪切速率的增加而降低，并且组合物的表观粘度相对于剪切速率的增加而增加 其中。 此外，该组合物具有优异的高初始粘合性和增粘能力。

公开(公告)号：US06818698B1

公开(公告)日：2004-11-16

申请号：US10334468

申请日：2002-12-31

申请人： Sanjay Kashikar

发明人： Sanjay Kashikar

IPC分类号： C08J305

CPC分类号： C08J3/03 ,  C03C25/30 ,  C08F255/02 ,  C08J3/05 ,  C08J2323/00 ,  C08J2323/02 ,  C08L51/06 ,  C09D151/06 ,  C08L2666/02

摘要： A one-step direct method of making a high molecular weight functionalized polyolefin aqueous emulsion is provided. In this one-step direct method, a functionalized polyolefin having a molecular weight of at least 10,000, a fatty acid, a base, a surfactant, and water are heated in a pressure reaction vessel to a temperature above the emulsification temperature of the polyolefin with agitation for a period of time sufficient to form an aqueous emulsion. This high molecular weight functionalized polyolefin aqueous emulsion can be added to a sizing composition and applied directly onto glass fibers in the glass fiber manufacturing process.

摘要翻译： 提供制备高分子量官能化聚烯烃水乳液的一步法直接法。 在该一步直接法中，将分子量为至少为10,000的官能化聚烯烃，脂肪酸，碱，表面活性剂和水在压力反应容器中加热到高于聚烯烃的乳化温度的温度， 搅拌足以形成水乳液的一段时间。 该高分子量官能化聚烯烃水性乳液可以加入到施胶组合物中并在玻璃纤维制造过程中直接施加到玻璃纤维上。

公开(公告)号：US06767956B2

公开(公告)日：2004-07-27

申请号：US10220376

申请日：2003-03-11

申请人： Riaz Ahmad Choudhery ,  Kenneth Andrew Murray ,  Stephen Barry Downing ,  David John Southgate

发明人： Riaz Ahmad Choudhery ,  Kenneth Andrew Murray ,  Stephen Barry Downing ,  David John Southgate

IPC分类号： C08J305

CPC分类号： C08J3/05 ,  B29C47/0004 ,  B29C47/0021 ,  B29C47/40 ,  B29K2067/00 ,  C08J2323/02 ,  C08J2367/02

摘要： A process for producing an aqueous dispersion of a polymer in an aqueous medium having a viscosity below 10 Pa.s, in which the polymer is dispersed in an aqueous medium in an extruder at a temperature above 100° C., the pressure inside the extruder being maintained above atmospheric pressure so that the aqueous medium does not boil inside the extruder.

公开(公告)号：US06518354B1

公开(公告)日：2003-02-11

申请号：US09623916

申请日：2000-09-11

申请人： Ginpei Suzuki ,  Yukihiro Okubo ,  Toshiyuki Nishitani ,  Masayo Kuze

发明人： Ginpei Suzuki ,  Yukihiro Okubo ,  Toshiyuki Nishitani ,  Masayo Kuze

IPC分类号： C08J305

CPC分类号： C08L95/00 ,  C08L21/02 ,  C08L95/005 ,  Y10S516/92 ,  C08L2666/08 ,  C08L53/00

摘要： There is provided a dispersing emulsion excellent in storage stability and mechanical stability, particularly an asphalt modifier of an water based dispersing emulsion, which can be mixed with a hot asphalt or an asphalt emulsion, and can improve rutting resistance, toughness, and flexibility at a low temperature without losing workability. There is provided a dispersing emulsion of a thermoplastic elastomer, which is emulsified and dispersed in the presence of at least one nonionic emulsifier selected from the group consisting of a styrenated phenol poly(alkylene oxide), a poly(alkylene polyamine) poly(alkylene oxide), polyalcohol fatty acid esters, polyalcohol fatty acid esters poly(alkylene oxide), and a benzylated phenol poly(alkylene oxide).

摘要翻译： 本发明提供了储存稳定性和机械稳定性优异的分散乳液，特别是水性分散乳液的沥青改性剂，其可与热沥青或沥青乳液混合，并且可以提高耐磨性，韧性和柔韧性 低温不失操作性。 提供了一种热塑性弹性体的分散乳液，其在至少一种非离子乳化剂的存在下被乳化和分散，所述非离子乳化剂选自苯乙烯化的酚聚（环氧烷），聚（亚烷基多胺）聚（烯化氧） ），多元醇脂肪酸酯，多元醇脂肪酸酯聚（环氧烷）和苄基化酚聚（环氧烷）。