公开(公告)号：US20040181011A1

公开(公告)日：2004-09-16

申请号：US10734596

申请日：2003-12-15

发明人： Alexander Korzhenko ,  Alexander Pud ,  Galina Shapoval

IPC分类号： C08L033/00

CPC分类号： H01B1/128 ,  C08L27/04 ,  C08L27/12 ,  C08L27/16 ,  C08L27/18 ,  C08L27/20 ,  C08L79/02 ,  C08L2666/20 ,  C08L2666/04

摘要： The process of the present invention is a process to make a conductive fluorinated polymer composition (also called composite) wherein: a) an aqueous solution of an anilinium salt is mixed with an aqueous dispersion of a fluorinated polymer, b) then an oxidant is added to the mixture of step a) to make a blend of said fluorinated polymer and doped polyaniline (PANI), c) by-products and unreacted aniline are removed by washing with water or an alcohol to get a blend of purified fluorinated polymer and doped PANI, d) eventually the purified fluorinated polymer and doped PANI of step c) can be mixed with an acid, e) water is removed from the purified fluorinated polymer and doped PANI of step c) or d) if any and the remaining powder is melted and shaped in films, pellets or any object.

摘要翻译： 本发明的方法是制备导电氟化聚合物组合物（也称为复合物）的方法，其中：a）将苯胺盐的水溶液与含氟聚合物的水分散体混合，b）然后加入氧化剂 与步骤a）的混合物制备所述氟化聚合物和掺杂的聚苯胺（PANI）的共混物，c）通过用水或醇洗涤除去副产物和未反应的苯胺，得到纯化的氟化聚合物和掺杂的PANI的混合物 d）最终纯化的氟化聚合物和步骤c）的掺杂PANI可以与酸混合，e）从纯化的氟化聚合物和步骤c）或d）的掺杂PANI中除去水，如果有的话，剩余的粉末熔化 并以薄膜，颗粒或任何物体成型。

公开(公告)号：US20030232559A1

公开(公告)日：2003-12-18

申请号：US10174315

申请日：2002-06-17

发明人： Joel Erwin Goldstein ,  Jeffrey Allen Welty ,  Deborah Ann Matelan

IPC分类号： B32B005/18 ,  B32B005/24 ,  C08L033/00

CPC分类号： D06M15/248 ,  D04H1/587 ,  D04H1/64 ,  D06M15/227 ,  D06M15/29 ,  D06M15/333 ,  Y10T442/652

摘要： The invention relates to an improvement in adhesive polymeric binders for nonwoven products and to the nonwoven product. The basic polymeric binder is comprised of emulsion polymerized units of vinyl acetate, ethylene and self-crosslinking monomer(s), e.g., N-methylol acrylamide. The improvement in the adhesive polymeric binder for forming nonwoven webs comprised largely of synthetic fibers resides in the presence of vinyl chloride polymerized into the vinyl acetate/ethylene polymer backbone.

摘要翻译： 本发明涉及用于非织造产品和非织造产品的粘合剂聚合物粘合剂的改进。 碱性聚合物粘合剂由乙酸乙烯酯，乙烯和自交联单体（例如N-羟甲基丙烯酰胺）的乳液聚合单元组成。 用于形成主要由合成纤维构成的非织造纤维网的粘合聚合物粘合剂的改进在于聚合到乙酸乙烯酯/乙烯聚合物主链中的氯乙烯的存在。

公开(公告)号：US20030225203A1

公开(公告)日：2003-12-04

申请号：US10156110

申请日：2002-05-29

申请人： JSR CORPORATION

发明人： Osamu Kurita ,  Fumihisa Miyajima ,  Osamu Ishikawa

IPC分类号： C08L033/00

CPC分类号： D21H19/58 ,  C08F236/12 ,  D21H19/42 ,  D21H21/54 ,  C08F2/22

摘要： The present invention provides a copolymer latex capable of remarkably improving the bond strength of coated paper, excelling in coated paper properties such as print gloss, and excelling in coating operability such as redispersibility, mechanical stability, and anti-stick properties, a process for producing the copolymer latex, and a paper coating composition. In the copolymer latex of the present invention, the content of components detected before an elution time at which a component having a polystyrene-reduced molecular weight of 1,000,000 is detected in a molecular-weight distribution measured by gel permeation chromatography (GPC) is 31% or more, the weight average molecular weight of components detected after the elution time at which the component having a polystyrene-reduced molecular weight of 1,000,000 is detected is 30,000-400,000, and the toluene insoluble content is 31 wt % or more.

摘要翻译： 本发明提供能够显着提高涂布纸的粘合强度的共聚物胶乳，优异的涂布纸性能如印刷光泽度以及优异的涂布操作性，如再分散性，机械稳定性和防粘性能，生产方法 共聚物胶乳和纸张涂料组合物。 在本发明的共聚物胶乳中，在通过凝胶渗透色谱法（GPC）测定的分子量分布中检测到具有聚苯乙烯换算分子量为1,000,000的成分的洗脱时间之前检测到的成分的含量为31％ 检测到聚苯乙烯换算分子量为1,000,000以上的成分的洗脱时间后检测到的成分的重均分子量为30,000〜40000，甲苯不溶成分为31重量％以上。

公开(公告)号：US20020156178A1

公开(公告)日：2002-10-24

申请号：US09809007

申请日：2001-03-16

发明人： Jean-Marc Ascione ,  Michael De George

IPC分类号： C08L033/00

CPC分类号： A61K8/8152 ,  A61K8/86 ,  A61K2800/52 ,  A61K2800/5424 ,  A61K2800/594 ,  A61Q19/00

摘要： Compositions comprising at least one anionic associative polymer comprising at least one carboxylic acid group and at least one ester derived from a fatty alcohol and a carboxylic acid; and at least one additional anionic associative polymer comprising at least one carboxylic acid group and at least one ester derived from an alkoxylated fatty alcohol and a carboxylic acid, wherein the fatty chain of the alkoxylated fatty alcohol comprises more than 18 carbon atoms, and processes for providing physical stability to at least one non-solid composition comprising the same, and for making up, caring for or treating at least one keratinous material.

摘要翻译： 包含至少一种包含至少一个羧酸基团的至少一种阴离子缔合聚合物和至少一种衍生自脂肪醇和羧酸的酯的组合物; 和包含至少一个羧酸基团和至少一种衍生自烷氧基化脂肪醇和羧酸的酯的至少一种另外的阴离子缔合聚合物，其中所述烷氧基化脂肪醇的脂肪链包含大于18个碳原子， 为至少一种包含该固体组合物的非固体组合物提供物理稳定性，并且用于组合，照顾或治疗至少一种角质材料。

公开(公告)号：US20020090451A1

公开(公告)日：2002-07-11

申请号：US09864278

申请日：2001-05-25

发明人： Takayoshi Yamazaki ,  Takashi Sunamori

IPC分类号： B05D005/06 ,  B05D003/02 ,  C08J003/00 ,  C08K003/00 ,  C08L039/00 ,  C08L031/00 ,  C08L033/00

CPC分类号： C09D175/04 ,  C08G18/10 ,  C08G18/6283 ,  C08G18/285

摘要： A process for producing a weather resistant coating film which can keep a gloss retention of 80% or more for 1,000 hours or more in an accelerated weathering test by a carbon sunshine weather-o-meter by preparing a weather resistant coating material comprising a binder and a curing agent as main constituents and coating an article to be coated with the coating material, followed by drying, which process comprises chemically bonding an ultraviolet absorptive compound having the maximum value of its light absorption spectrum in a wavelength region shorter than 380 nm and having a molecular extinction coefficient at the absorption maximum wavelength of 5,000 to 50,000 to either or both of the binder and the curing agent constituting the coating material, preparing a coating material with the above-mentioned bonding and the constitution of the coating material being designed such that when the coating material is coated on an article and dried, the concentration C (mol/L) of the residual group of the ultraviolet absorptive compound in the dry coating film may satisfy the expressionnulldCnull129nulllog nullnull367wherein null is the molecular extinction coefficient of the residual group of the above-mentioned compound in the dry film, d is the thickness (cm) of the dry coating film when in use and null is the time (hour) of exposure in the accelerated weathering test that shows a gloss retention of 80% or more which is determined according to the requirements of intended uses, and coating the coating material on the article, followed by drying, so that the thickness of the dry coated film may become the above-mentioned d, and a coating material which provides the film. Provided are a process for producing a coating film excellent in such weather resistances as gloss retainability, resistance to discoloration and resistance to cracking necessary for long-term outdoor uses, and a coating material which gives the film.

公开(公告)号：US20020032269A1

公开(公告)日：2002-03-14

申请号：US09850299

申请日：2001-05-08

申请人： EMTEC MAGNETICS GmbH

发明人： Volker Schobe ,  Christoph Roth ,  Angela Kuhrt ,  Wilfried Weigt

IPC分类号： C08L001/00 ,  C08J003/00 ,  C08K003/34 ,  C08K003/00 ,  C08L031/00 ,  C08L033/00

CPC分类号： B41M5/52 ,  B41M5/506 ,  B41M5/5218 ,  B41M5/5227 ,  B41M5/5245 ,  B41M5/5254 ,  B41M5/529

摘要： Water-resistant pigmented recording material which is useful for inkjet printers. The ink-receiving layer comprises silica dispersions modified with alkylsilanes, water-soluble plasticizers and polymeric ink fixatives. The material provides image recording in photo quality on conventional types of printers.

摘要翻译： 用于喷墨打印机的防水着色记录材料。 油墨接收层包括用烷基硅烷改性的二氧化硅分散体，水溶性增塑剂和聚合物油墨固定剂。 该材料在常规类型的打印机上提供照片质量的图像记录。

公开(公告)号：US20010056154A1

公开(公告)日：2001-12-27

申请号：US09272882

申请日：1999-03-19

发明人： HARALD BLUM ,  WIELAND HOVESTADT ,  KARL LUDWIG NOBLE

IPC分类号： C08L033/00

CPC分类号： C08F285/00 ,  C08F265/06 ,  C08F212/00 ,  C08F220/10

摘要： The present invention relates to aqueous solutions or dispersions of copolymers A) containing a hydroxy-functional, hydrophobic copolymer I) containing 30 to 85% by weight of (meth)acrylic acid esters having C1 to C18 hydrocarbon radicals in the alcohol portion, aromatic vinyl compounds and/or vinyl esters and 5 to 45% by weight of hydroxy-functional monomers; a hydroxy- and carboxy-functional, hydrophilic-hydrophobic copolymer II) containing 4 to 20% by weight of (meth)-acrylic acid esters having C1 to C18 hydrocarbon radicals in the alcohol portion, aromatic vinyl compounds and/or vinyl esters, 4 to 15% by weight of hydroxy-functional monomers and 0.8 to 3.0% by weight of acid-functional monomers; and optionally a hydroxy-functional hydrophobic copolymer III) containing 0 to 16% by weight of hydroxy- and/or non-functional (meth)acrylic acid esters or aromatic vinyl compounds, wherein 1) the sum of Ia), Ib), IIa), IIb) IIc) and IIIa) is 100%, based on the weight of these components, 2) copolymer A) has an acid number, based on solids, of 10 to 28 mg KOH/g substance, 3) the weight percent of monomers IIc) in monomer II) is less than 25% by weight and 4) the weight percent of hydroxy-functional monomers IIb) in copolymer II) is higher than the weight percent of hydroxy-functional monomers Ib) in copolymer I). The present invention also relates to a method of preparing these dispersions or solutions of copolymers A) and to their use in binder compositions with at least one crosslinking resin selected from aminoplast resins, blocked polyisocyanates and polyisocyanates containing free isocyanate groups.

摘要翻译： 本发明涉及包含30至85重量％的在醇部分中具有C1至C18烃基的（甲基）丙烯酸酯的含羟基官能的疏水性共聚物I）的共聚物A）的水溶液或分散体，芳族乙烯基 化合物和/或乙烯基酯和5至45重量％的羟基官能单体; 含有4至20重量％的在醇部分中具有C1至C18烃基的（甲基）丙烯酸酯，芳香族乙烯基化合物和/或乙烯基酯的4〜20重量％的羟基和羧基官能的亲水疏水性共聚物II），4 至15重量％的羟基官能单体和0.8-3.0重量％的酸官能单体; 和任选的含有0至16重量％羟基和/或非官能（甲基）丙烯酸酯或芳族乙烯基化合物的羟基官能疏水性共聚物III），其中1）Ia），Ib），IIa ），IIb）IIc）和IIIa）为100％，基于这些组分的重量，2）共聚物A）具有基于固体的10至28mg KOH / g物质的酸值，3）重量百分数 单体II）中的单体IIc）小于25重量％，和4）共聚物II）中羟基官能单体IIb）的重量百分比高于共聚物I）中羟基官能单体Ib）的重量百分数。 本发明还涉及制备这些共聚物A）的这些分散体或溶液的方法，以及它们在粘合剂组合物中的用途，所述粘合剂组合物含有至少一种选自氨基塑料树脂，封端多异氰酸酯和含有游离异氰酸酯基团的多异氰酸酯的交联树脂。

公开(公告)号：US20040254290A1

公开(公告)日：2004-12-16

申请号：US10860305

申请日：2004-06-03

发明人： Klein A. Rodrigues ,  James C. Long

IPC分类号： C08K003/00 ,  C08L061/04 ,  C08L033/00

CPC分类号： C08F220/04 ,  C03C25/28 ,  C03C25/40 ,  C08L33/14 ,  C08L43/04 ,  C08L2666/04 ,  C09J133/04 ,  Y10T428/2964

摘要： A glass adhesion composition containing a copolymer having an acid and a substituted amide, silanol, or amine oxide functionality. The substituted amide, silanol, or amine oxide functionality provide excellent adhesion of the copolymer to glass, silica, sand and other silicon-based substances. The copolymer is useful as a fiberglass binder, and also useful in providing protective coatings on glass sheets. A fiberglass sizing composition is also provided having a copolymer that includes at least one acid group derived from at least one acid monomer, a hydrophobic comonomer, and a crosslinker. Additives can be added to the compositions to provide other functionality such as corrosion inhibitors, hydrophobic additives, additives for reducing leaching of glass, release agents, acids for lowering pH, anti-oxidants/reducing agents, emulsifiers, dyes, pigments, oils, fillers, colorants, curing agents, anti-migration aids, biocides, plasticizers, waxes, anti-foaming agents, coupling agents, thermal stabilizers, flame retardants, enzymes, wetting agents, and lubricants.

摘要翻译： 含有具有酸和取代酰胺，硅烷醇或胺氧化物官能团的共聚物的玻璃粘合组合物。 取代的酰胺，硅烷醇或胺氧化物官能团提供了共聚物对玻璃，二氧化硅，沙子和其它硅基物质的极好的粘附性。 共聚物可用作玻璃纤维粘合剂，也可用于在玻璃板上提供保护涂层。 还提供了具有包含至少一种衍生自至少一种酸单体，疏水性共聚单体和交联剂的酸基的共聚物的玻璃纤维上胶组合物。 可以向组合物中加入添加剂以提供其它功能，例如腐蚀抑制剂，疏水添加剂，用于减少玻璃浸出的添加剂，脱模剂，用于降低pH的酸，抗氧化剂/还原剂，乳化剂，染料，颜料，油，填料 ，着色剂，固化剂，抗迁移助剂，杀生物剂，增塑剂，蜡，消泡剂，偶联剂，热稳定剂，阻燃剂，酶，润湿剂和润滑剂。

公开(公告)号：US20040186229A1

公开(公告)日：2004-09-23

申请号：US10765152

申请日：2004-01-28

申请人： BASF Aktiengesellschaft

发明人： Wilfried Heide ,  Stefan Wickel ,  Thomas Daniel ,  Joachim Nilges ,  Jurgen Hofmann

IPC分类号： C08L033/00

CPC分类号： C08F2/01 ,  B01J14/00 ,  B01J19/0013 ,  B01J19/20 ,  B01J2219/00033 ,  B01J2219/00063 ,  B01J2219/00085 ,  B01J2219/00094 ,  B01J2219/00123 ,  B01J2219/00128 ,  B01J2219/00162 ,  B01J2219/00166 ,  C08F2/10

摘要： A process for continuous production of crosslinked fine particles of polymer gel by copolymerizing a) water-soluble monoethylenically unsaturated monomers, b) from 0.001 to 5 mol % based on the monomers (a) of monomers containing at least two ethylenically unsaturated double bonds, and c) from 0 to 20 mol % based on the monomers (a) of water-insoluble monoethylenically unsaturated monomers in from 20 to 80% by weight aqueous solution in the presence of an initiator at from 0 to 140null C. by feeding the aqueous solution of the monomers together with the initiator and an inert gas continuously into a mixing kneader having at least two axially parallel rotating shafts equipped with a plurality of kneading and transporting elements which convey the substances introduced at the upstream end of the mixing kneader in the axial direction toward the downstream end of the mixer, comprises the fraction of heat being removed by evaporation of water from the reaction mixture being not less than 5% of the heat of reaction and the fraction of heat being removed by product discharge being not less than 25% of the heat of reaction and the rest of the heat being removed via cooling of the reactor walls.

摘要翻译： 一种通过共聚a）水溶性单烯属不饱和单体，b）相对于含有至少两个烯键式不饱和双键的单体（a）为0.001〜5摩尔％的连续制造交联微粒的方法，以及 c）0至20摩尔％，基于单体（a）的水不溶性单烯属不饱和单体，在20至80重量％的水溶液中，在0-140℃的引发剂存在下，通过加入水 将单体与引发剂和惰性气体的溶液连续混合到具有至少两个轴向平行的旋转轴的混合捏合机中，所述两个轴向平行的旋转轴装备有多个捏合和输送元件，其将在混合捏合机的上游端引入的物质沿轴向 朝向混合器下游端的方向包括通过蒸发反应混合物中的水而除去的热分数不小于5％ 反应热和通过产物排放除去的热分数不低于反应热的25％，剩余的热量通过反应器壁的冷却除去。

公开(公告)号：US20040132937A1

公开(公告)日：2004-07-08

申请号：US10336255

申请日：2003-01-03

发明人： Jan G. Stannard ,  Kenneth J. Berk

IPC分类号： C08L033/00

CPC分类号： A61K6/083 ,  A61K6/09 ,  C08F2/44 ,  C08F30/02 ,  C08L75/16 ,  C08L33/00

摘要： This invention relates to a polymerizable composite material and method of making same including at least one multifunctional acid containing monomer having a concentration ranging from about 10% to about 85%, a non-reactive filler having a concentration ranging from about 1% to about 80%, a polymerization system having a concentration ranging from about 1.5% to about 15%, and water having a concentration ranging from about 0.1% to about 25%.

摘要翻译： 本发明涉及可聚合复合材料及其制备方法，其包括至少一种浓度范围为约10％至约85％的多官能含酸单体，浓度范围为约1％至约80的非反应性填料 ％，浓度范围为约1.5％至约15％的聚合体系，以及浓度范围为约0.1％至约25％的水。