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    Polyacrylate reaction products
    4.
    发明授权
    Polyacrylate reaction products 失效
    聚丙烯酸酯反应产物

    公开(公告)号：US4076665A

    公开(公告)日：1978-02-28

    申请号：US753612

    申请日：1976-12-22

    申请人： Nelson E. Lawson

    发明人： Nelson E. Lawson

    IPC分类号： C08G63/46 ,  C08G63/47 ,  C08G63/52 ,  C08G63/553 ,  C09D11/10 ,  C09D3/66 ,  C09D3/81

    CPC分类号： C09D11/101 ,  C08G63/46 ,  C08G63/47 ,  C08G63/52 ,  C08G63/553 ,  Y10S260/38 ,  Y10S522/909

    摘要： Disclosure is made of radiation curable, solvent-less compositions useful in coatings, films and in preparing printing inks. The compositions comprise the reaction product of an equivalent excess of an acrylic type acid with a particular class of polyester polyol. The polyester polyol is the condensation product of an excess of an aliphatic polyol having at least two hydroxyl groups and a molecular weight of from 60 to 250 with a specific class of aliphatic polycarboxylic acids derived from fatty and resin acids.

    摘要翻译： 披露了可用于涂料，薄膜和制备印刷油墨的可辐射固化的无溶剂组合物。 组合物包含等量过量的丙烯酸类与特定类别的聚酯多元醇的反应产物。 聚酯多元醇是过量的具有至少两个羟基并且分子量为60至250的脂族多元醇与来自脂肪和树脂酸的特定类型的脂肪族多元羧酸的缩合产物。

    Air-curing acrylic polymers
    5.
    发明授权
    Air-curing acrylic polymers 失效
    空气固化丙烯酸聚合物

    公开(公告)号：US4547556A

    公开(公告)日：1985-10-15

    申请号：US436258

    申请日：1982-10-25

    申请人： Kathleen A. Hughes ,  Graham Swift

    发明人： Kathleen A. Hughes ,  Graham Swift

    IPC分类号： C08F242/00 ,  C09D5/44 ,  C09D133/06 ,  C09D3/81 ,  C08L91/00 ,  C09D5/02

    CPC分类号： C09D133/062 ,  C08F242/00 ,  C09D5/4407

    摘要： A composition comprising a water reducible vinyl additional polymer having pendant unsaturated air drying fatty acid ester groups and additional pendant groups selected from secondary amine, tertiary amine, and combinations thereof are disclosed, as are methods for preparing such polymers, solvent coatings, water reducible coatings, and electrodeposition coatings containing such polymers.

    摘要翻译： 公开了包含具有侧链不饱和空气干燥脂肪酸酯基团的另外的可水稀释的乙烯基附加聚合物和选自仲胺，叔胺及其组合的另外的侧基的组合物，以及制备这种聚合物，溶剂涂料，水可稀释涂层 ，以及含有这种聚合物的电沉积涂层。

    Paint adapted for use as repair paint for damaged painted surfaces
    6.
    发明授权
    Paint adapted for use as repair paint for damaged painted surfaces 失效
    油漆适用于损坏油漆表面的修复漆

    公开(公告)号：US4400479A

    公开(公告)日：1983-08-23

    申请号：US278995

    申请日：1981-06-30

    申请人： Teunis M. Bos

    发明人： Teunis M. Bos

    IPC分类号： C09D101/08 ,  C08L1/14 ,  C08L55/00 ,  C09D133/04 ,  C09D133/08 ,  C09D167/00 ,  C09D3/81 ,  C08L1/10 ,  C08L1/16

    CPC分类号： C09D133/08 ,  C08L1/14 ,  C08L55/005

    摘要： A coating composition adapted for repairing a damaged coating on a substrate comprises as the binder a mixture of a polyacrylate, an acrylated alkyd resin and a cellulose ester which form 100 percent of the binder. The coating composition is particularly well suited for use in preparing damaged paint on a motor vehicle body. The binder may be mixed with a volatile inert organic solvent for the binder in making the composition. The composition has a higher solids content than composition usually used for repairing damaged coatings and much thicker layers of the coating composition may be applied. By mixing the components of the binder in the ratio of 10 to 60 parts by weight of polyacrylate to 30 to 75 parts by weight of acrylated alkyd resin and 5 to 45 parts by weight cellulose ester to form the binder a coating composition having reduced tendency to crack and of improved solids content is obtained.

    摘要翻译： 用于修复基材上的损伤涂层的涂料组合物包含作为粘合剂的聚丙烯酸酯，丙烯酸酯化的醇酸树脂和形成100％粘合剂的纤维素酯的混合物。 涂料组合物特别适合用于制备机动车身上的损伤油漆。 在制造组合物时，粘合剂可以与用于粘合剂的挥发性惰性有机溶剂混合。 组合物具有比通常用于修复受损涂层的组合物更高的固体含量，并且可以施加更厚的涂层组合物层。 通过将粘合剂的组分以10至60重量份的聚丙烯酸酯与30至75重量份的丙烯酸酯化的醇酸树脂和5至45重量份的纤维素酯的比例混合以形成粘合剂，该涂料组合物具有降低的 获得裂纹和改善的固体含量。

    Autoxidizable compositions containing low molecular weight polymers of dicyclopentenyl methacrylate or dicyclopentenyloxyalkyl methacrylate
    7.
    发明授权
    Autoxidizable compositions containing low molecular weight polymers of dicyclopentenyl methacrylate or dicyclopentenyloxyalkyl methacrylate 失效
    含有甲基丙烯酸二环戊烯酯或甲基丙烯酸二环戊烯氧基烷基酯的低分子量聚合物的可自动氧化组合物

    公开(公告)号：US4387190A

    公开(公告)日：1983-06-07

    申请号：US289638

    申请日：1981-08-03

    申请人： Wayne E. Feely

    发明人： Wayne E. Feely

    IPC分类号： C08F32/00 ,  C08F20/10 ,  C08F20/12 ,  C08F20/26 ,  C08F20/28 ,  C08F242/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/04 ,  C08L33/06 ,  C08L67/00 ,  C08L67/08 ,  C08L91/00 ,  C09D133/04 ,  C09D133/06 ,  C09D133/10 ,  C09D157/00 ,  C09D167/08 ,  C09D191/00 ,  C09D3/66 ,  C09D3/81

    CPC分类号： C09D133/10 ,  C09D167/08 ,  C08L67/08

    摘要： An improved autoxidizable coating and/or impregnating composition consisting essentially of:(1) from about 35% to about 80% by weight, based on the total weight of components (1), (2), and (3), of a film-forming component selected from the group consisting of drying oils, alkyd resins, and mixtures of drying oils and alkyd resins,(2) from about 10% to about 50% by weight, based on the total weight of components (1), (2), and (3), of a polymer of a molecular weight in the range of 1,000-50,000 (Mn) polymerized from a monomer system comprising:(a) from about 40% to 100% by weight of at least one monomer selected from the group consisting of dicyclopentenyl methacrylate and dicyclopentenyloxyalkyl methacrylate, and(b) from about 60% to 0% by weight of at least one compatible monomer,(3) from 0 to about 40% by weight, based on the total weight of components (1), (2), and (3), of a reactive, non-volatile diluent monomer, and(4) an effective amount of at least one polyvalent metal salt or complex that catalyzes the oxidative curing of components (1), (2), and (3), wherein the total of the percentages of components (1), (2), and (3) is 100.

    摘要翻译： 一种改进的可自动氧化的涂层和/或浸渍组合物，其基本上由以下组成：（1）基于组分（1），（2）和（3）的总重量的约35重量％至约80重量％ 选自干油，醇酸树脂以及干性油和醇酸树脂的混合物的成分组分，（2）约10％至约50％重​​量，基于组分（1），（ 2）和（3）分子量在1,000-50,000（Mn）范围内的聚合物的聚合物，该单体体系包含：（a）约40％至100％重量的至少一种所选择的单体 来自由二环戊烯基甲基丙烯酸酯和甲基丙烯酸二环戊烯氧基烷基酯组成的组，和（b）约60重量％至0重量％的至少一种相容单体，（3）0至约40重量％，基于组分 （1），（2）和（3）的反应性非挥发性稀释剂单体，和（4）有效量的至少一种多价金属盐 或催化组分（1），（2）和（3）的氧化固化的络合物，其中组分（1），（2）和（3）的百分比的合计为100。

    Composition and process for the protection of materials against spots or stains
    8.
    发明授权
    Composition and process for the protection of materials against spots or stains 失效
    保护材料免受斑点或污渍的组成和过程

    公开(公告)号：US4366300A

    公开(公告)日：1982-12-28

    申请号：US265941

    申请日：1981-05-21

    申请人： Charles L. L. Delescluse

    发明人： Charles L. L. Delescluse

    IPC分类号： C09D5/00 ,  C08L33/14 ,  C09D133/04 ,  D06M15/295 ,  C09D3/81 ,  C09D5/14

    CPC分类号： D06M15/295 ,  C08L33/14

    摘要： The invention relates to a composition for the protection of materials against contaminations, spots and stains.This liquid composition comprises by weight 0.1 to 1% of at least one fluorinated resin based on acrylic or methacrylic esters of fluorinated sulfonamido-alcohol, associated or not with non-fluorinated monomers, 0.4 to 10% of at least one adjuvant selected from aminoplast resins based on melamine, thermoplastic resins and waxes, and 89 to 99.5% of at least one organic solvent.Applied on materials such as walls, facades, monuments or sculptures in cement, bricks, concrete or stones and other construction elements, the composition according to the invention confers on the materials an excellent protection against natural or artificial contaminations.

    摘要翻译： 本发明涉及一种用于保护材料免受污染，斑点和污渍的组合物。 该液体组合物包含0.1至1％的至少一种氟化树脂，其基于氟化亚磺酰氨基醇的丙烯酸或甲基丙烯酸酯，与非氟化单体缔合或不相结合，0.4-10％的至少一种佐剂，其选自氨基塑料树脂 基于三聚氰胺，热塑性树脂和蜡，以及89至99.5％的至少一种有机溶剂。 用于水泥，砖，混凝土或石头等建筑构件的墙体，立面，古迹或雕塑等材料，根据本发明的组合物赋予材料优良的防止天然或人造污染的保护。

    Radiation curable compositions
    9.
    发明授权
    Radiation curable compositions 失效
    辐射固化组合物

    公开(公告)号：US4035320A

    公开(公告)日：1977-07-12

    申请号：US604488

    申请日：1975-08-14

    申请人： Nelson E. Lawson

    发明人： Nelson E. Lawson

    IPC分类号： C08G63/47 ,  C09D11/10 ,  C09D3/66 ,  C09D3/81

    CPC分类号： C09D11/101 ,  C08G63/47 ,  Y10S260/38 ,  Y10S522/909

    摘要： Disclosure is made of radiation curable, solventless compositions useful in coatings, films and in preparing printing inks. The compositions comprise the reaction product of an equivalent excess of an acrylic type acid with a particular class of polyester polyol. The polyester polyol is the condensation product of an excess of an aliphatic polyol having at least two hydroxyl groups and a molecular weight of from 60 to 250 with a specific class of aliphatic polycarboxylic acids derived from fatty and resin acids.

    摘要翻译： 披露了可用于涂料，薄膜和制备印刷油墨的可辐射固化的无溶剂组合物。 组合物包含等量过量的丙烯酸类与特定类别的聚酯多元醇的反应产物。 聚酯多元醇是过量的具有至少两个羟基并且分子量为60至250的脂族多元醇与来自脂肪和树脂酸的特定类型的脂肪族多元羧酸的缩合产物。

    Pigment dispersions and lacquers containing copolymer of isobornyl methacrylate
    10.
    发明授权
    Pigment dispersions and lacquers containing copolymer of isobornyl methacrylate 失效
    含有甲基丙烯酸异冰片酯共聚物的颜料分散体和漆

    公开(公告)号：US3940353A

    公开(公告)日：1976-02-24

    申请号：US468942

    申请日：1974-05-08

    申请人： Richard Martorano

    发明人： Richard Martorano

    IPC分类号： C08L33/06 ,  C09D11/10 ,  C09D115/02 ,  C09D133/06 ,  C09D201/00 ,  C09D3/48 ,  C09D3/66 ,  C09D3/81

    CPC分类号： C09D133/06 ,  C09D11/10 ,  C09D115/02 ,  C09D201/00 ,  C08L2205/02 ,  C08L33/06

    摘要： Low molecular weight copolymers (1) acrylic acid esters or methacrylic acid esters of alcohols such as methanol with (2) esters of bicyclic alcohols such as isobornyl alcohol and unsaturated acids such as methacrylic acid, as contrasted with high molecular weight copolymers of such monomers (1) and (2) (see U.S. Pat. No. 3,485,775) and as contrasted to other acrylic polymers, are found to be exceptional in compatibility with practically all types of polyesters and alkyds and with many other types of lacquer film-forming materials. The modifiers, particulary for alkyds, need not be selected on the basis of the oil length or solvent (aromatic or aliphatic), the modifiers being compatible with long oil alkyds, medium oil alkyds, and short oil alkyds. When small amounts of unsaturated amine-containing monomers or unsaturated carboxylic acids, or other polar monomers and combinations thereof, are incorporated in the polymer solutions, they become improved pigment dispersants. Such pigment dispersions, unexpectedly, can be let down with many types of synthetic resins and used by air-drying or baking the coated articles. Lacquers for metals, paints, and printing inks are examples of uses for such blends.

    摘要翻译： 低分子量共聚物（1）醇类如甲醇的丙烯酸酯或甲基丙烯酸酯与（2）双环醇如异冰片醇和不饱和酸如甲基丙烯酸的酯，与这些单体的高分子量共聚物形成对比（ 发现与其他丙烯酸类聚合物形成对比的是，与实际上所有类型的聚酯和醇酸树脂以及许多其他类型的漆膜形成材料相容，这是非常特别的（1）和（2）（见美国专利号3,485,775）。 特别适用于醇酸树脂的改性剂不需要根据油长度或溶剂（芳香族或脂肪族）选择，改性剂与长油醇酸树脂，中油醇酸树脂和短油醇酸树脂相容。 当少量含不饱和胺的单体或不饱和羧酸或其它极性单体及其组合引入聚合物溶液中时，它们变成改进的颜料分散剂。 意外地，这种颜料分散体可以用许多类型的合成树脂放下，并通过空气干燥或烘烤涂覆的制品来使用。 用于金属，油漆和印刷油墨的油漆是用于这种共混物的实例。