Integrated oil production and upgrading using molten alkali metal
    1.
    发明授权
    Integrated oil production and upgrading using molten alkali metal 有权
    使用熔融碱金属的综合石油生产和升级

    公开(公告)号:US09458385B2

    公开(公告)日:2016-10-04

    申请号:US13940336

    申请日:2013-07-12

    摘要: A method that combines the oil retorting process (or other process needed to obtain/extract heavy oil or bitumen) with the process for upgrading these materials using sodium or other alkali metals. Specifically, the shale gas or other gases that are obtained from the retorting/extraction process may be introduced into the upgrading reactor and used to upgrade the oil feedstock. Also, the solid materials obtained from the reactor may be used as a fuel source, thereby providing the heat necessary for the retorting/extraction process. Other forms of integration are also disclosed.

    摘要翻译: 将油馏分方法(或获得/提取重油或沥青所需的其它方法)与使用钠或其它碱金属升级的方法相结合的方法。 具体来说,从蒸馏/提取过程获得的页岩气或其他气体可以被引入升级反应器中并用于升级油原料。 此外,从反应器获得的固体材料可以用作燃料源,从而提供蒸煮/提取过程所需的热量。 还公开了其他形式的整合。

    Process for recovery of low-temperature carbonization oil
    3.
    发明授权
    Process for recovery of low-temperature carbonization oil 失效
    回收低温碳化油的工艺

    公开(公告)号:US4863586A

    公开(公告)日:1989-09-05

    申请号:US191017

    申请日:1988-05-06

    IPC分类号: C10G1/02 C10G9/02 C10G51/02

    摘要: In a first condensation stage (which is on the rising current end of the low-temperature carbonization drum and the equipment for which is integrated) quenching is done with a cooled low-temperature carbonization oil fraction containing solids. Simultaneously the whole discharge opening placed on the rising current end in the base region of the low-temperature carbonization drum for the volatile components of the low-temperature carbonization process is continuously scrubbed clean with the low-temperature carbonization oil fraction containing solids. Additionally, the volatile and liquid components are also drawn off simultaneously.

    摘要翻译: 在第一冷凝阶段(其在低温碳化鼓的上升端和其一体化设备上)通过含有固体的冷却的低温碳化油馏分进行淬火。 同时,低温碳化工艺的挥发性成分的低温碳化鼓的底部区域中的上升电流端的整个排出口被含有固体的低温碳化油馏分连续地清洗。 此外,挥发性和液体组分也被同时排出。

    Dephlegmatic phased method of organic waste utilization and dephlegmatic pyrolysis apparatus
    5.
    发明申请
    Dephlegmatic phased method of organic waste utilization and dephlegmatic pyrolysis apparatus 审中-公开
    有机废物利用和脱焦热解装置的分阶段分阶段方法

    公开(公告)号:US20050240068A1

    公开(公告)日:2005-10-27

    申请号:US11104064

    申请日:2005-04-11

    申请人: Victor Babiy

    发明人: Victor Babiy

    摘要: This invention relates to a method for thermal utilization of solid organic household and industrial waste, and may be applied in municipal economy, chemical, petrochemical and other branches of industry for the regeneration of hydrocarbons into fuel oil and fuel gas. The dephlegmatic phased method of organic waste utilization, comprising multistage pyrolysis of waste in a reactor without air access, at temperature not more than 1000° with obtaining of solid carbon residue and multi-component gas-vapor mixture, cooling of gas-vapor mixture in multiloop circulatory cooling system, extraction of a heavy fraction for repyrolysis and obtaining of a liquid fraction having indicated molecular mass and gas on a finite circuit. Organic waste are exposed stepwise to the pyrolysis with reloading of non-decomposed solid residue from a retort of the first stage reactor having temperature 150-180° C., sequentially to retorts for the pyrolysis at higher temperatures, and gas-vapor mixture from the retorts is directed to not less than one dephlegmator, there it is purified from tar composition, and tar composition being returned to a retort for the re-pyrolysis, gas-vapor mixture from the dephlegmator being conveyed to a fraction distributor for cooling, and combustion gases from a casing of the last retort being conveyed to casings of the preceding retorts, and then jointly with combustion gases generated by heaters under the casings of all retorts are delivered outside. The attained object is the provision of an apparatus for the pyrolysis of improved effectiveness, obviating overheating and reheating of the finished product, and providing for obtaining of qualitative oil and gas fuel and pyrographite.

    摘要翻译: 本发明涉及一种固体有机家用和工业废物热利用方法,可用于市政经济,化工,石油化工等行业,用于将碳氢化合物再生成燃料油和燃料气。 有机废物利用的分阶段分阶段方法,包括在没有空气通入的反应器中废物的多级热解,温度不超过1000°,获得固体碳残余物和多组分气体 - 蒸汽混合物,将气 - 气混合物冷却 多循环循环冷却系统,提取用于再溶解的重馏分,并在有限回路上获得具有指示分子量和气体的液体馏分。 将有机废物逐步暴露于热解过程中,将未分解的固体残余物从温度为150-180℃的第一阶段反应器的蒸馏器重新加载,依次加热至较高温度下进行热解的蒸馏器,并将来自 蒸馏器指向不少于一个分馏器,其中从焦油组合物中纯化,并将焦油组合物返回到蒸馏器中,以将来自分馏器的再热解气体 - 蒸汽混合物输送到馏分分配器进行冷却和燃烧 将来自最后蒸馏器的壳体的气体输送到先前的蒸馏器的壳体,然后与在所有蒸馏器的壳体下的加热器产生的燃烧气体一起被输送到外部。 所达到的目标是提供一种用于热解的设备,其改进的有效性,消除了成品的过热和再加热,并且提供了获得定性的油气和燃料和热解物。

    Multi-hydrotorting of coal
    6.
    发明授权
    Multi-hydrotorting of coal 失效
    煤的多次加氢

    公开(公告)号:US3715301A

    公开(公告)日:1973-02-06

    申请号:US3715301D

    申请日:1971-06-30

    申请人: TEXACO INC

    IPC分类号: C10G1/00 C10G1/06 C10G9/02

    摘要: A NONCATALYTIC MULTI-HYDROTORTING PROCESS FOR MAXIMIZING THE CONVERSION OF COAL INTO COAL OIL. A PUMPABLE COAL-WATER SLURRY IN ADMIXTURE WITH A STREAM OF SYNTHESIS GAS IS PASSED THROUGH A TUBULAR RETORT WHERE IT IS HEATED TO A TEMPERATURE IN THE RANGE OF ABOUT 600 TO 950* F. IN THE ABSENCE OF AIR. THE SOLID COAL PARTICLES ARE FRAMENTIZED AND CARBONIZED IN THE TUBULAR RETORT, THE VOLATILE CONSTITUENTS IN SAID SLURRY ARE VOLATILIZED AND SIMULTANEOUSLY HYDROGENATION OF THE PROCESS STREAM TAKES PLACE. THE EFFLUENT FROM THE TUBULAR RETORT IS THEN INTRODUCED INTO A FLUIDIZED BED RETORT ALONG WITH A SECOND STREAM OF SYNTHESIS GAS. THERMAL DECOMPOSITION OF THE CARBONACEOUS MATERIALS TAKES PLACE IN THE ABSENCE OF AIR AND THE PROCESS STREAM IS HYDROGENATED FOR A SECOND TIME. THE PROCESS STREAM LEAVING THE FLUIDIZED BED RETORT IS COOLED TO CONDENSE OUT AND SEPARATE WATER AND RAW COAL-OIL IN A GAS-LIQUID SEPARATION ZONE. A PORTION OF THE OFF-GAS FROM THE GAS-LIQUID SEPARATOR MAY BE SCRUBBED AND PURIFIED TO PRODUCE NONPOLLUTING FUEL GAS HAVING A HIGH HEATING VALUE. SPENT CARBONACEOUS PARTICLES LEAVING THE FLUIDIZED BED RETORT AND OPTIONALLY A PORTION OF THE OFF-GAS FROM THE GAS-LIQUID SEPARATOR ARE INTRODUCED INTO A FREE-FLOW NONCATALYTIC GAS GENERATOR FOR CONVERSION INTO PREFERABLY HYDROGEN-RICH SYNTHESIS GAS BY PARTIAL OXIDATION FOR USE IN THE AFORESAID TWO HYDROTORTING STAGES.

    Pyrolysis of residual hydrocarbons
    9.
    发明授权
    Pyrolysis of residual hydrocarbons 有权
    残余烃的热解

    公开(公告)号:US08057662B2

    公开(公告)日:2011-11-15

    申请号:US11383137

    申请日:2006-05-12

    申请人: Columba K. Yeung

    发明人: Columba K. Yeung

    IPC分类号: C10G9/28 C10G9/02

    摘要: A process and apparatus for upgrading heavy hydrocarbons such as asphaltenes to lighter oil and gas components is disclosed. The process provides a reaction environment that promotes fast and selective cracking of heavy hydrocarbons, while minimizing coke formation and fouling and enhancing product yields.

    摘要翻译: 公开了一种用于将诸如沥青质的重质烃更新为较轻油和气体组分的方法和装置。 该方法提供了促进重质烃快速和选择性裂化的反应环境,同时使焦炭形成和结垢最小化并提高产物产率。

    Process for treating heavy oil
    10.
    发明授权
    Process for treating heavy oil 失效
    重油处理方法

    公开(公告)号:US3957620A

    公开(公告)日:1976-05-18

    申请号:US387551

    申请日:1973-08-13

    CPC分类号: C10G9/00 C10B55/02 C10G19/073

    摘要: In the treatment of petroleum heavy oil by thermally cracking a petroleum heavy oil mixed with an alkali metal carbonate or carbonates at a cracking temperature of 450.degree. to 650.degree.C and recovering the resulting low sulfur liquid hydrocarbon and light hydrocarbon gas, (1) gasification of residual coke produced by said cracking, in the presence of the alkali metal carbonate or carbonates and an alkali metal sulfide or sulfides by-produced during the cracking, with steam alone or steam together with an oxygen-containing gas, at 550.degree. to 800.degree.C and under the atmospheric pressure to 10 atm. to produce a hydrogen- and CO.sub.2 -- rich gas, and (2) regeneration from said by-produced alkali metal sulfide or sulfides to said alkali metal carbonate or carbonates, with CO.sub.2 gas produced by said gasification and steam, are simultaneously carried out in the same reaction zone.

    摘要翻译: 在石油重油的处理中,通过在450〜650℃的裂解温度下将与碱金属碳酸盐或碳酸盐混合的石油重油热裂解并回收得到的低硫液烃和轻烃气体,(1)气化 在碱金属碳酸盐或碳酸盐存在下产生的残留焦炭,以及在裂化过程中副产的碱金属硫化物或硫化物,单独的蒸汽或与含氧气体一起蒸汽在550至800℃ ℃,大气压至10atm。 以产生富含氢和二氧化碳的气体,以及(2)通过所述气化和蒸汽产生的CO 2气体从所述副产物碱金属硫化物或硫化物再生到所述碱金属碳酸盐或碳酸盐,同时进行 相同的反应区。