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公开(公告)号:US12070738B2
公开(公告)日:2024-08-27
申请号:US17642885
申请日:2020-09-15
CPC分类号: B01J23/20 , B01J21/08 , B01J35/615 , B01J35/617 , B01J37/0213 , B01J37/0236 , B01J37/088 , C07C1/2072 , C07C2521/08 , C07C2523/20
摘要: The invention relates to a process for the production of 1,3-butadiene from a feed comprising ethanol and acetaldehyde in the presence of a supported tantalum catalyst obtainable by aqueous impregnation of the support with a water-soluble tantalum precursor. Furthermore, the present invention relates to a process for the production of a supported tantalum catalyst, and the supported tantalum catalyst. Finally, the invention relates to the use of the supported tantalum catalyst for the production of 1,3-butadiene from a feed comprising ethanol and acetaldehyde to increase one or both of selectivity and yield of the reaction.
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2.
公开(公告)号:US20240166576A1
公开(公告)日:2024-05-23
申请号:US18552765
申请日:2022-03-31
CPC分类号: C07C1/2072 , C07C45/29 , C07C2521/08 , C07C2523/20
摘要: The invention relates to a process for the production of 1,3-butadiene comprising reacting a feed comprising ethanol and acetaldehyde in a 1,3-butadiene producing reactor having at least one adiabatic reaction zone. Moreover, the invention relates to a process for the production of 1,3-butadiene from ethanol ater comprising i. producing acetaldehyde from ethanol in an acetaldehyde producing reactor, and ii. producing 1,3-butadiene from ethanol and acetaldehyde in a 1,3-butadiene producing reactor. The invention further relates to a plant for the production of 1,3-butadiene comprising at least one 1,3-butadiene producing reactor producing 1,3-butadiene from ethanol and acetaldehyde. Finally, the invention relates to a plant for the production of 1,3-butadiene from ethanol, comprising i. an acetaldehyde producing reactor, and ii. a 1,3-butadiene producing reactor.
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公开(公告)号:US11851384B2
公开(公告)日:2023-12-26
申请号:US17713686
申请日:2022-04-05
CPC分类号: C07C1/2076 , C07C7/04 , C07C45/68 , C07C2521/04 , C07C2521/06 , C07C2521/18 , C07C2523/44 , C07C2523/656
摘要: Disclosed herein are embodiments of a method and system for converting ethanol to para-xylene. The method also provides a pathway to produce terephthalic acid from biomass-based feedstocks. In some embodiments, the disclosed method produces p-xylene with high selectivity over other aromatics typically produced in the conversion of ethanol to xylenes, such as m-xylene, ethyl benzene, benzene, toluene, and the like. And, in some embodiments, the method facilitates the ability to use ortho/para mixtures of methylbenzyaldehyde for preparing ortho/para xylene product mixtures that are amendable to fractionation to separate the para- and ortho-xylene products thereby providing a pure feedstock of para-xylene that can be used to form terephthalic anhydride and a pure feedstock of ortho-xylene that can be used for other purposes, such as phthalic anhydride.
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公开(公告)号:US11845903B2
公开(公告)日:2023-12-19
申请号:US17930468
申请日:2022-09-08
发明人: Patrick L. Hanks
IPC分类号: C10G69/02 , C07D323/02 , C07C51/34 , C10G3/00 , C11C1/04 , B01J10/00 , B01D3/14 , B01J19/24 , C07C1/20 , C07C1/207 , C07C1/24 , C07C1/22
CPC分类号: C10G69/02 , B01D3/14 , B01J10/00 , B01J19/245 , C07C1/20 , C07C1/207 , C07C1/22 , C07C1/24 , C07C51/34 , C07D323/02 , C10G3/50 , C11C1/04 , B01J2219/0004 , C10G2300/1011 , C10G2400/08
摘要: A method for producing jet range hydrocarbons may include reacting at least a portion a fatty acid stream comprising C18:1 free fatty acid with ozone in an ozonolysis unit to form at least a C18:1 ozonide intermediate; introducing the C18:1 ozonide intermediate into a reactor, wherein at least a portion of the C18:1 ozonide intermediate is reacted with a reductive agent to produce oxidized products comprising azelaic acid and nonanoic acid; and introducing the oxidized products into a hydrotreating unit, wherein at least a portion of the oxidized products is hydrotreated to produce a paraffin product comprising nonane.
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公开(公告)号:US20230373892A1
公开(公告)日:2023-11-23
申请号:US18028280
申请日:2021-09-13
CPC分类号: C07C45/002 , C07C1/2076 , C07C7/005
摘要: The invention relates to a process for the dehydrogenation of a feedstock comprising ethanol, using at least one multitubular reactor advantageously comprising a plurality of tubes comprising at least one dehydrogenation catalyst, and a calender, said feedstock being introduced into the tubes in gas form, at an inlet temperature of greater than or equal to 240° C., a pressure between 0.1 and 1.0 MPa, and a WWH between 2 and 15 h−1, wherein a heat-transfer fluid circulates in said calender at a flow rate such that the weight ratio of said heat-transfer fluid relative to said feedstock is greater than or equal to 1.0, and such that said heat-transfer fluid is introduced into said calender in gas form at an inlet temperature of greater than or equal to 260° C. and at an inlet pressure of greater than or equal to 0.10 MPa, and less than or equal to 1.10 MPa, and leaves the calender at least partly in liquid form.
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公开(公告)号:US20230219867A1
公开(公告)日:2023-07-13
申请号:US18118674
申请日:2023-03-07
发明人: Ramin Abhari , H. Lynn Tomlinson , Vladimir Gruver
CPC分类号: C07C1/2078 , C09K5/063 , C10L1/04 , C07C9/14 , C07C9/22 , C07C9/15 , C07C1/22 , C07C2523/882 , C07C2525/02 , C07C2523/883 , C07C2521/04 , C07C2521/02 , C07C2523/888 , C07C2527/18 , C07C2525/00
摘要: Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.
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公开(公告)号:US20220184581A1
公开(公告)日:2022-06-16
申请号:US17431187
申请日:2020-02-12
申请人: SBI BioEnergy
发明人: Inder Pal SINGH , Shradha SINGH , Bharat MISTRY , Zhiyong LI
IPC分类号: B01J23/00 , B01J23/10 , B01J35/10 , B01J35/02 , B01J37/08 , B01J37/04 , C07C1/213 , C07C1/207
摘要: It is provided solid, heterogeneous catalysts for the deoxygenation of esters of free fatty acids and triglycerides, and for the production of hydrocarbons that can be used as biofuels. More particularly, the catalyst comprises at least one metal oxide, the catalyst having a formula AlaCubNicSidTieZnfZrgLahCeiWjSnkGalFemMOnMnoCOpOx, wherein a, b, c, d, g, h, i, j, k, l, m n, o, p and x are the molar ratios of the respective elements, wherein a, b, c, d, h, i, j, k, I, m, n, o and p are >0, e, f and g are >0 and x is such that the catalyst is electrically neutral.
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公开(公告)号:US11198942B2
公开(公告)日:2021-12-14
申请号:US15548618
申请日:2015-12-23
发明人: Ralf Krause , Christian Reller , Guenter Schmid , Elena Volkova
摘要: The present disclosure relates to electrolysis systems and methods. The teachings thereof may be embodied in methods and systems for the utilization of carbon dioxide and production of carbon monoxide. For example, a method may include: passing an electrolyte and carbon dioxide in front of a cathode through a cathode chamber; and removing electrolysis byproducts from an electrolyte/electrolysis product mixture using a catalytic filter system. The cathode may include material to reduce carbon dioxide. The process may generate a hydrocarbon compound or carbon monoxide as the electrolysis product and a formate as an electrolysis byproduct. The filter system may include a functionalized complex or a functionalized support material which catalyzes a cleavage reaction of formates (a) to hydrogen and carbon dioxide, or (b) to water and carbon monoxide.
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公开(公告)号:US20200299210A1
公开(公告)日:2020-09-24
申请号:US16896486
申请日:2020-06-09
发明人: Ramin Abhari , H. Lynn Tomlinson , Vladimir Gruver
摘要: Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.
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公开(公告)号:US20200283366A1
公开(公告)日:2020-09-10
申请号:US16639534
申请日:2018-08-17
IPC分类号: C07C51/377 , C07C67/08 , C07C1/207 , C25B3/04 , C25B11/04
摘要: The invention is directed to a method of electrochemically producing valeric acid.The method of the invention comprises contacting a solution of levulinic acid with an anode and a cathode in an electrochemical cell; and electrochemically reducing levulinic acid at the cathode to form valeric acid, wherein the cathode comprises one or more materials selected from the group consisting of cadmium, zinc, and indium.
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