公开(公告)号：US20240336553A1

公开(公告)日：2024-10-10

申请号：US18576016

申请日：2022-05-26

申请人： Cataler Corporation

发明人： Yusuke SAITO ,  Tomohito MIZUKAMI ,  Yohei MAKI

IPC分类号： C07C209/36 ,  B01J8/06 ,  B01J10/00 ,  B01J19/24 ,  C07C45/00 ,  C07C45/37

CPC分类号： C07C209/36 ,  B01J8/065 ,  B01J10/007 ,  B01J19/2485 ,  C07C45/006 ,  C07C45/37 ,  B01J2219/2419 ,  C07C2601/14

摘要： A reaction method includes, in a gas-liquid reaction performed using a solid catalyst, alternately allowing a gaseous raw material that includes a first raw material and a liquid raw material that includes a second raw material to pass through a reaction field that holds the solid catalyst, and reacting the first and second raw materials on the solid catalyst.

公开(公告)号：US20240226858A1

公开(公告)日：2024-07-11

申请号：US18558408

申请日：2022-05-05

申请人： BASF SE

发明人： Thomas HEIDEMANN ,  Stephanie Sybille LINKE ,  Viktor ULRICH ,  Matthias HINRICHS ,  Michael FRIKO

IPC分类号： B01J23/89 ,  B01J21/06 ,  B01J21/08 ,  B01J23/889 ,  B01J35/30 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  B01J37/18 ,  C07C209/36

CPC分类号： B01J23/892 ,  B01J21/066 ,  B01J21/08 ,  B01J23/8896 ,  B01J35/394 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/088 ,  B01J37/18 ,  C07C209/36

摘要： The present invention relates to a catalytic material comprising Ni, one or more additional metals M, and an oxidic support material comprising Si and Zr, both in oxidic form, as well as a process for preparation thereof. In addition thereto, the present invention relates to a use of the inventive catalytic material as a catalyst or catalyst component, especially in a hydrogenation reaction.

公开(公告)号：US12024481B1

公开(公告)日：2024-07-02

申请号：US18103860

申请日：2023-01-31

申请人： Government of the United States, as represented by the Secretary of the Air Force

发明人： Loon-Seng Tan ,  Zhenning Yu

IPC分类号： C07C211/50 ,  C07C209/06 ,  C07C209/36

CPC分类号： C07C211/50 ,  C07C209/06 ,  C07C209/36

摘要： The invention relates to bis(aniline) compounds containing multiple arylethynyl, alkylethynyl, ethynyl groups or their combinations, processes of making such compounds and materials comprising such compounds. Such, bis(aniline) compounds preferably comprise multiple phenylethynyl (PE) groups, i.e. 2-4 PE moieties. Such compounds are useful monomers for the preparation of polyimides, polyamides and poly(amide-imides) whose post-fabrication crosslinking chemistry (i.e. reaction temperature) can be controlled by the number of PE per repeat unit as well as finding utility in thermosetting matrix resins, 3D printable resins, and as high-carbon-content precursors to carbon-carbon composites.

公开(公告)号：US20240157343A1

公开(公告)日：2024-05-16

申请号：US18546817

申请日：2022-02-28

申请人： Covestro Deutschland AG ,  Lanxess Deutschland GmbH

发明人： Bernd Pennemann ,  Lennart Sandbrink ,  Eberhard Zirngiebl ,  Thomas Kaese ,  Hans-Jürgen Quella ,  Paul Sprenger ,  Daniel Ullrich ,  Marc Williams

IPC分类号： B01J23/80 ,  B01J21/08 ,  B01J23/745 ,  B01J23/75 ,  B01J23/847 ,  B01J23/889 ,  B01J35/40 ,  B01J35/51 ,  B01J35/55 ,  B01J37/02 ,  B01J37/08 ,  C07C209/36

CPC分类号： B01J23/80 ,  B01J21/08 ,  B01J23/745 ,  B01J23/75 ,  B01J23/8472 ,  B01J23/8892 ,  B01J35/40 ,  B01J35/51 ,  B01J35/55 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0236 ,  B01J37/086 ,  B01J37/088 ,  C07C209/36

摘要： The present invention relates (i) to a method for producing a doped copper-tetraammine-salt-based hydrogenation catalyst suitable for the hydrogenation of an aromatic nitro compound such that an aromatic amine is obtained, the hydrogenation catalyst comprising copper in metal form or in oxidic form and a doping metal selected from iron, cobalt, manganese, vanadium, zinc or a mixture of two or more thereof in metal form or in oxidic form on a carrier, the carrier comprising silicon dioxide shaped bodies and/or silicon carbide shaped bodies, (ii) to a doped copper-tetraammine-salt-based hydrogenation catalyst obtainable using the aforementioned method according to the invention, and (iii) to a method for producing an aromatic amine, comprising the hydrogenation of an aromatic nitro compound in the presence of a doped copper-tetraammine-salt-based hydrogenation catalyst comprising copper in metal form or in oxidic form and comprising a doping metal in metal form or in oxidic form on a carrier as hydrogenation catalyst, the carrier comprising silicon dioxide shaped bodies and/or silicon carbide shaped bodies, and the hydrogenation catalyst being, more particularly, the aforementioned hydrogenation catalyst according to the invention.

公开(公告)号：US20230277998A1

公开(公告)日：2023-09-07

申请号：US18101376

申请日：2023-01-25

申请人： W. L. Gore & Associates, Inc.

发明人： Gary P. Harp ,  Jeffrey A. Knopf, JR. ,  William J. Napier, III

IPC分类号： B01J19/18 ,  B01J10/00 ,  B01J19/00 ,  B01J31/06 ,  B01J35/06 ,  C07C209/36 ,  B01J8/22

CPC分类号： B01J19/1893 ,  B01J8/222 ,  B01J10/007 ,  B01J19/0066 ,  B01J19/1868 ,  B01J31/06 ,  B01J35/065 ,  C07C209/36 ,  B01J2231/641 ,  B01J2531/002

摘要： A catalytic membrane composite that includes porous supported catalyst particles durably enmeshed in a porous fibrillated polymer membrane is provided. The porous fibrillated polymer membrane may be manipulated to take the form of a tube, disc, or diced tape and used in multiphase reaction systems. The supported catalyst particles are composed of at least one finely divided metal catalyst dispersed on a porous support substrate. High catalytic activity is gained by the effective fine dispersion of the finely divided metal catalyst such that the metal catalyst covers the support substrate and/or is interspersed in the pores of the support substrate. In some embodiments, the catalytic membrane composite may be introduced to a stirred tank autoclave reactor system, a continuous flow reactor system, or a Parr Shaker reaction system and used to effect the catalytic reaction.

公开(公告)号：US20230182120A1

公开(公告)日：2023-06-15

申请号：US17921384

申请日：2021-04-29

申请人： BASF SE

发明人： Thomas HEIDEMANN ,  Inna SCHWABAUER ,  Barbara WUCHER ,  Marie Katrin SCHROETER ,  Claudia OEZKOZANOGLU ,  Michael FRIKO ,  Jim BRANDTS

IPC分类号： B01J23/755 ,  B01J21/08 ,  B01J35/00 ,  B01J35/02 ,  B01J37/04 ,  B01J37/03 ,  B01J37/02 ,  B01J37/08 ,  C07C209/36

CPC分类号： B01J23/755 ,  B01J21/08 ,  B01J35/0066 ,  B01J35/026 ,  B01J37/04 ,  B01J37/035 ,  B01J37/0236 ,  B01J37/088 ,  C07C209/36

摘要： A catalytic material comprising Ni supported on an oxidic support comprising Zr in oxidic form and Si in oxidic form, wherein the catalytic material comprises equal to or greater than 65 weight-% of Ni, calculated as elemental Ni, wherein the catalytic material exhibits a Ni:Zr atomic ratio in the range of from 8.5 to 50.0.

公开(公告)号：US11642667B2

公开(公告)日：2023-05-09

申请号：US17044702

申请日：2020-05-14

申请人： Institute of Coal Chemistry, Chinese Academy of Sciences

发明人： Yong Qin ,  Bin Zhang ,  Huibin Wu ,  Haojie Liang

IPC分类号： B01J35/06 ,  B01J23/89 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  B01J37/34 ,  C01B3/04 ,  C07C209/36

CPC分类号： B01J35/06 ,  B01J23/892 ,  B01J37/0018 ,  B01J37/0215 ,  B01J37/082 ,  B01J37/18 ,  B01J37/348 ,  C01B3/04 ,  C07C209/36 ,  C01B2203/0277 ,  C01B2203/107

摘要： The present disclosure relates to a multi-sandwich composite catalyst and a preparation method and application thereof. The present disclosure provides a preparation method of a multi-sandwich composite catalyst, comprises the following steps: sequentially depositing a first layer oxide, a first active metal, an oxide interlayer, a second active metal and a surface oxide on a template, and sequentially performing calcination and reduction, thereby obtaining a multi-sandwich composite catalyst; wherein the first active metal and the second active metal are different kinds of active metals. In the present disclosure, a multi-sandwich structure is formed by depositing the oxides and active metals alternately, so that the position and spacing distance of the active centers can be precisely controlled. The multi-sandwich composite catalyst prepared by the method provided described herein has a higher conversion than that of a catalyst without an interlayer when used for the catalytic reaction.

公开(公告)号：US11512006B2

公开(公告)日：2022-11-29

申请号：US17603005

申请日：2020-11-20

申请人： HEBEI CAIKE CHEMICAL CO., LTD.

发明人： Weidong Duan ,  Guofu Zhang ,  Yu Wei

IPC分类号： C01G49/06 ,  C09C1/24 ,  C07C303/22 ,  C07C209/36

摘要： A method for simultaneously preparing an iron oxide red pigment and an aromatic amine is provided. In the method, an aromatic nitro compound and ferrous iron are first used to prepare an iron oxide red seed crystal under the action of a catalyst, and then iron powder is used to reduce the aromatic nitro compound and generate iron oxide in situ which grows into iron oxide red with pigment performance on the seed crystal. The method provides a clean and economical way for the reduction of an aromatic nitro compound (especially those in which there are other easily-reduced substituents on an aromatic ring) to prepare an aromatic amine.

公开(公告)号：US20220098141A1

公开(公告)日：2022-03-31

申请号：US17545250

申请日：2021-12-08

申请人： Monsanto Technology LLC

发明人： John H. Ahn ,  Kam-To Wan

IPC分类号： C07C209/36 ,  B01J21/18 ,  B01J23/42 ,  B01J23/89 ,  C07C37/045 ,  B01J35/00 ,  C07C245/20 ,  C07C231/02

摘要： The present invention generally relates to processes for the catalytic hydrogenation of halonitroaromatics. In particular, the present invention includes processes for the catalytic hydrogenation of halonitroaromatics such as 2,5-dicloronitrobenzene to 2,5-dichloroaniline over a platinum-containing catalyst. The present invention also relates to processes for producing 3,6-dichloro-2-methoxybenzoic acid.

公开(公告)号：US11040336B2

公开(公告)日：2021-06-22

申请号：US16901029

申请日：2020-06-15

申请人： Xiangtan University

发明人： Jicheng Zhou ,  Yanji Zhang ,  Fei Wang

IPC分类号： C07C209/36 ,  C07C211/52 ,  B01J29/03 ,  B01J37/02 ,  B01J37/08 ,  B01J37/34

摘要： A catalyst including platinum (Pt) and a composite support. The composite support includes ZrO2/mesoporous silica sieve SBA-15. The platinum accounts for 0.01-0.3 wt. % of the catalyst. ZrO2 accounts for 5-20 wt. % of the composite support.