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    Hot melt adhesive compositions
    2.
    发明授权
    Hot melt adhesive compositions 失效
    热熔胶组合物

    公开(公告)号：US4304697A

    公开(公告)日：1981-12-08

    申请号：US196209

    申请日：1980-10-14

    申请人： Pawan K. Agarwal ,  Robert D. Lundberg

    发明人： Pawan K. Agarwal ,  Robert D. Lundberg

    IPC分类号： C09J123/26 ,  C09J123/32 ,  C09J157/02 ,  C08L95/00

    CPC分类号： C09J123/32 ,  C09J157/02

    摘要： This invention relates to hot melt adhesive compositions which includes a neutralized sulfonated elastomeric polymer having about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated elastomeric polymer, and about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, aliphatic dienes and mono and diolefins, cyclic olefins of 5 or 6 carbon atoms and hydrogenated poly cyclics per 100 parts by weight of the neutralized sulfonated EPDM terpolymer.

    摘要翻译： 本发明涉及热熔粘合剂组合物，其包括具有约5至约50meq的中和磺化弹性体聚合物。 每100克中和的磺化弹性体聚合物中和磺酸盐基团，以及约25至约250重量份的石油或煤焦油馏出物，脂族二烯和单和二烯烃的烃树脂，5或6个碳原子的环烯烃 和每100重量份中和的磺化EPDM三元共聚物的氢化聚合物。

    High tensile strength elastomeric adhesive cements and laminates therefrom
    3.
    发明授权
    High tensile strength elastomeric adhesive cements and laminates therefrom 失效
    高抗拉强度弹性粘合剂水泥和层压材料

    公开(公告)号：US4072648A

    公开(公告)日：1978-02-07

    申请号：US505341

    申请日：1974-09-12

    申请人： Charles P. O'Farrell ,  John J. Higgins

    发明人： Charles P. O'Farrell ,  John J. Higgins

    IPC分类号： C09J123/32 ,  C08K5/01 ,  C08K5/05 ,  C08K5/15 ,  C08L9/00

    CPC分类号： C09J123/32 ,  Y10T428/3188 ,  Y10T442/3415

    摘要： Adhesive contact cements of sulfonated olefinically unsaturated elastomers (sulfobutyl rubber) containing from about 0.1 to about 5.0 mol % SO.sub.3 H neutralized, partially neutralized, or unneutralized, are admixed with tackifiers, i.e. phenolformaldehyde resins, polyisobutylene, alkylphenol formaldehyde resins, petroleum resins, etc. in an amount of between about 5 and about 90 phr in between about 10 and about 50 wt. % solids concentration in organic solvents. These cements are used for adhering porous or non-porous materials such as textiles, wood, cloth, sheets or strip of metals, plastics, etc. to each other. High green strength, high tensile strength, high resistance to peel, even at elevated temperatures, water impermeability, etc. characterize such adhesive layers in laminates. A preferred solvent, 90% toluene, 10% isopropyl alcohol is used in compounding the cement and preferably an organic amine, e.g. ethylamine, is used to partially or completely neutralize the sulfonated elastomer although inorganic bases may also be used for neutralization.

    摘要翻译： 将含有约0.1至约5.0mol％SO 3 H中和，部分中和或未中和的磺化烯属不饱和弹性体（磺丁基橡胶）的粘合剂接合剂与增粘剂即酚醛树脂，聚异丁烯，烷基酚甲醛树脂，石油树脂等混合。 其量为约5至约90phr，约10至约50wt。 有机溶剂中固体浓度％。 这些粘固剂用于将诸如纺织品，木材，布，金属，塑料等的多孔或无孔材料粘合到彼此上。 高的生坯强度，高拉伸强度，高耐剥离性，即使在升高的温度下，不透水性等也表征了层压板中的这种粘合剂层。 将优选的溶剂，90％甲苯，10％异丙醇用于配混水泥和优选有机胺，例如， 乙胺用于部分或完全中和磺化弹性体，尽管无机碱也可用于中和。

    Adhesive cements containing a sulfonated derivative of butyl rubber and laminates therefrom
    4.
    发明授权
    Adhesive cements containing a sulfonated derivative of butyl rubber and laminates therefrom 失效
    含有丁基橡胶的磺化衍生物和层压材料的胶粘剂粘合剂

    公开(公告)号：US3867247A

    公开(公告)日：1975-02-18

    申请号：US20941471

    申请日：1971-12-17

    申请人： EXXON RESEARCH ENGINEERING CO

    发明人： O'FARRELL CHARLES P ,  HIGGINS JOHN J

    IPC分类号： C09J123/32 ,  C08D9/16

    CPC分类号： B32B7/12 ,  B32B27/12 ,  B32B2305/026 ,  B32B2305/18 ,  B32B2311/24 ,  B32B2317/10 ,  B32B2323/10 ,  B32B2367/00 ,  C08L2666/02 ,  C09J123/32 ,  Y10T428/3188 ,  Y10T442/3415 ,  C08L23/32 ,  C08L101/00

    摘要： Adhesive contact cements of sulfonated olefinically unsaturated elastomers (sulfobutyl rubber) containing from about 0.1 to about 5.0 mol % SO3H neutralized, partially neutralized, or unneutralized are admixed with tackifiers, i.e. phenolformaldehyde resins, polyisobutylene, alkylphenol formaldehyde resins, petroleum resins, etc. in an amount of between about 5 and about 90 phr in between about 10 and about 50 wt. % solids concentration in organic solvents. These cements are used for adhering porous or non-porous materials such as textiles, wood, cloth, sheets or strip of metals, plastics, etc. to each other. High green strength, high tensile strength, high resistance to peel, even at elevated temperatures, water impermeability, etc. characterize such adhesive layers in laminates. A preferred solvent, 90% toluene, 10% isopropyl alcohol is used in compounding the cement and preferably an organic amine, e.g. ethylamine, is used to partially or completely neutralize the sulfonated elastomer although inorganic bases may also be used for neutralization.

    摘要翻译： 将含有约0.1至约5.0摩尔％SO 3 H中和，部分中和或未中和的磺化烯属不饱和弹性体（磺丁基橡胶）的粘合剂接合剂与增粘剂即酚醛树脂，聚异丁烯，烷基酚甲醛树脂，石油树脂等混合在一起 在约10至约50重量％之间的量为约5至约90phr。 有机溶剂中固体浓度％。 这些粘固剂用于将诸如纺织品，木材，布，金属，塑料等的多孔或无孔材料粘合到彼此上。 高的生坯强度，高拉伸强度，高耐剥离性，即使在升高的温度下，不透水性等也表征了层压板中的这种粘合剂层。 将优选的溶剂，90％甲苯，10％异丙醇用于配混水泥和优选有机胺，例如， 乙胺用于部分或完全中和磺化弹性体，尽管无机碱也可用于中和。

    Bitumen adhesive composition containing an ionomeric elastomer and waterproofing membranes comprising same
    5.
    发明授权
    Bitumen adhesive composition containing an ionomeric elastomer and waterproofing membranes comprising same 失效
    含有离聚物弹性体的沥青粘合剂组合物和包含其的防水膜

    公开(公告)号：US4595636A

    公开(公告)日：1986-06-17

    申请号：US724000

    申请日：1985-04-17

    申请人： Robert A. Wiercinski ,  Stephen J. Whicher

    发明人： Robert A. Wiercinski ,  Stephen J. Whicher

    IPC分类号： B32B11/04 ,  C09J123/32 ,  C09J195/00 ,  B32B11/00

    CPC分类号： C09J195/00 ,  B32B11/04 ,  C09J123/32 ,  Y10T428/31815 ,  Y10T428/31844 ,  Y10T428/31931

    摘要： Bitumen-based pressure sensitive adhesive compositions are provided which comprise bitumen, oil, and an ionomeric elastomer. The adhesive compositions are useful as self adherent waterproofing layers, particularly in roofing applications. The use of the ionomeric elastomer permits formulation of the adhesive to have improved tack at the lower temperatures encountered in such application while maintaining desired flexibility, shear strength, and flow resistance.Also provided are waterproofing membranes comprising the inventive adhesive compositions.

    摘要翻译： 提供了基于沥青的压敏粘合剂组合物，其包含沥青，油和离聚物弹性体。 粘合剂组合物可用作自粘防水层，特别是在屋顶应用中。 使用离聚物弹性体允许粘合剂的配制在这种应用中遇到的较低温度下具有改进的粘性，同时保持所需的柔韧性，剪切强度和流动阻力。 还提供了包含本发明的粘合剂组合物的防水膜。

    Contact adhesive and adhesive system for EPDM elastomers
    7.
    发明授权
    Contact adhesive and adhesive system for EPDM elastomers 失效
    接触EPDM弹性体的粘合剂和粘合剂系统

    公开(公告)号：US4657958A

    公开(公告)日：1987-04-14

    申请号：US827456

    申请日：1986-02-11

    申请人： John W. Fieldhouse ,  Mark L. Stayer

    发明人： John W. Fieldhouse ,  Mark L. Stayer

    IPC分类号： C09J123/32 ,  C08K5/01 ,  C08K3/36 ,  C08K5/17 ,  C08K5/05

    CPC分类号： C09J123/32

    摘要： Adhesive compositions for bonding EPDM elastomers comprise (a) a neutralized sulfonated EPDM elastomeric terpolymer; (b) an organic hydrocarbon solvent; (c) an ionic plasticizer or mixture of ionic plasticiziers; (d) a phenolic hydrocarbon resin or mixture of phenolic hydrocarbon resins and (e) a material selected from mineral oils, petroleum oils, polybutenes, polyisobutylenes and ethylene/propylene copolymers. Such adhesive compositions are particularly suitable for bonding sheets of black EPDM, especially sheets of cured black EPDM, elastomeric membranes together and may also be utilized to bond sheets of cured black EPDM to other uncured elastomers and to non-elastomeric substrates as well.The adhesive compositions to proper selection of the component (e) material and the addition of a color pigment or dye thereto may also be used to bond colored EPDM elastomers such as white, blue, yellow, green, etc.An adhesive composition for bonding sheets of EPDM elastomeric roofing membrane in cases where the membrane is to be anchored to the roof surface by mechanical systems will further contain a hydrophobic silica.

    摘要翻译： 用于粘合EPDM弹性体的粘合剂组合物包含（a）中和的磺化EPDM弹性体三元共聚物; （b）有机烃溶剂; （c）离子增塑剂或离子塑化剂的混合物; （d）酚醛树脂或酚醛树脂的混合物和（e）选自矿物油，石油，聚丁烯，聚异丁烯和乙烯/丙烯共聚物的材料。 这种粘合剂组合物特别适合于将黑色EPDM的片材，特别是固化的黑色EPDM片材，弹性体膜粘合在一起，并且还可以用于将固化的黑色EPDM的片材与其它未固化的弹性体和非弹性体基材结合。 用于适当选择组分（e）材料和向其中添加着色颜料或染料的粘合剂组合物也可以用于粘合着色的EPDM弹性体如白色，蓝色，黄色，绿色等。用于粘合片材的粘合剂组合物 在通过机械系统将膜锚定到屋顶表面的情况下，EPDM弹性体屋顶膜将进一步含有疏水性二氧化硅。

    Bitumen adhesive and waterproofing membranes containing same
    8.
    发明授权
    Bitumen adhesive and waterproofing membranes containing same 失效
    含沥青粘合剂和防水膜含有

    公开(公告)号：US4600635A

    公开(公告)日：1986-07-15

    申请号：US723995

    申请日：1985-04-17

    申请人： Robert A. Wiercinski ,  Stephen J. Whicher

    发明人： Robert A. Wiercinski ,  Stephen J. Whicher

    IPC分类号： B32B11/04 ,  C09J123/32 ,  C09J195/00 ,  B32B7/00

    CPC分类号： C09J195/00 ,  B32B11/04 ,  C09J123/32 ,  Y10T428/31815 ,  Y10T428/31844 ,  Y10T428/31931

    摘要： Pressure sensitive bitumen-based adhesive compositions are provided which comprise bitumen, oil, an ionomeric elastomer, and gilsonite. The adhesives are particularly useful as self adherent waterproofing layers in roofing. The presence of gilsonite can result in substantial increases in the shear strength of these adhesives at the relatively high temperatures encountered in roofing applications.Also provided are waterproofing membranes comprising the inventive adhesive compositions.

    摘要翻译： 提供了压敏沥青基粘合剂组合物，其包含沥青，油，离聚物弹性体和高锰酸盐。 粘合剂作为屋顶的自粘防水层特别有用。 在屋顶应用中遇到的相对较高的温度下，长寿石的存在可导致这些粘合剂的剪切强度的显着增加。 还提供了包含本发明的粘合剂组合物的防水膜。

    Hot melt adhesive compositions
    9.
    发明授权
    Hot melt adhesive compositions 失效
    热熔胶组合物

    公开(公告)号：US4362828A

    公开(公告)日：1982-12-07

    申请号：US323420

    申请日：1981-11-20

    申请人： Pawan K. Agarwal ,  Warren A. Thaler

    发明人： Pawan K. Agarwal ,  Warren A. Thaler

    IPC分类号： C08C19/20 ,  C09J123/32 ,  C08L95/00

    CPC分类号： C08C19/20 ,  C09J123/32

    摘要： This invention relates to hot melt adhesive compositions which include a neutralized EPDM terpolymer which has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated elastomeric EPDM terpolymer, a neutralized sulfonated 1,2-syndiotactic polybutadiene resin which has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated polybutadiene, and about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate having about 5 to about 6 carbon atoms the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated EPDM terpolymer.

    摘要翻译： 本发明涉及热熔粘合剂组合物，其包括具有约5至约50meq的中和的EPDM三元共聚物。 每100克中和的磺化弹性体EPDM三元共聚物中和磺化基团，中和的磺化1,2-间同立构聚丁二烯树脂，其具有约5至约50meq。 每100克中和的磺化聚丁二烯中和磺酸盐基团，以及约25至约250重量份具有约5至约6个碳原子的石油或煤焦油馏出物的烃树脂，烃树脂由脂族二烯组成， 单烯烃/ 100重量份中和的磺化EPDM三元共聚物。