METHOD FOR THE SELECTIVE INDUSTRIAL PRODUCTION OF 1,5,9 CYCLODODECATRIENE
    14.
    发明申请
    METHOD FOR THE SELECTIVE INDUSTRIAL PRODUCTION OF 1,5,9 CYCLODODECATRIENE 审中-公开
    方法选择性大规模生产1,5,9三烯的

    公开(公告)号:WO2009092683A3

    公开(公告)日:2009-09-24

    申请号:PCT/EP2009050543

    申请日:2009-01-19

    Abstract: The invention relates to a method for the trimerisation of butadiene to form cyclododecatriene by continuously feeding butadiene into a main reactor volume, for producing a reaction mixture in the main reactor volume which comprises non-converted butadiene and cyclododecatriene, and for providing isothermic conditions in the main reactor volume by tempering the reaction mixture. Said method also continuously the following steps: the reaction mixture produced in the main reactor volume is continuously guided into a post-reactor volume and converts at least one part of the non-converted butadiene in the post-reactor volume into cyclododecatriene. Said reaction mixture provided in the post reactor volume is essentially in adiabatic equilibrium. The invention also relates to a reactor arrangement for carrying out said method comprising a main reactor and a secondary reactor. Subsequently, in accordance with the inventive method, the temperature difference is detected for determining the butadiene concentration in the main reactor and for monitoring the operation or the method.

    Abstract translation: 本发明涉及一种用于丁二烯通过丁二烯的连续进料在主反应器体积以环十二碳三烯的三聚的过程中,形成在主反应器容积含有未反应的丁二烯和环十二碳三烯的反应混合物,和通过控制反应混合物的温度在主反应器体积提供的等温条件。 该方法还包括:连续传递在Nachreaktorvolumen主反应器体积中产生的反应混合物和至少一个在未反应Nachreaktorvolumen丁二烯部分环十二碳三烯反应。 在Nachreaktorvolumen反应混合物中提供的在绝热平衡基本上提供。 本发明还包括用于实施过程与初级和次级反应器的反应器布置。 最后,温度差的用于确定丁二烯的浓度在主反应器,并监测操作的检测,并且该方法是根据本发明的方法中使用。

    METHOD AND SYSTEM TO REDUCE POLYMERIZATION REACTOR FOULING
    15.
    发明申请
    METHOD AND SYSTEM TO REDUCE POLYMERIZATION REACTOR FOULING 审中-公开
    减少聚合反应器的方法和系统

    公开(公告)号:WO2006026224A3

    公开(公告)日:2009-07-02

    申请号:PCT/US2005029784

    申请日:2005-08-23

    Abstract: Techniques are provided for the prevention of reactor fouls in polymerization reactors. A technique is provided for limiting polymer particle size to prevent or limit the occurrence of reactor fouls associated with large polymer particles. A technique is also provided for measuring reactor temperature at one or more local hot spots of the reactor and for controlling the polymerization reaction based upon these temperature measurements. In particular, control of the reaction may be based on the hottest temperature, such that the hottest temperature in the reactor is maintained within the reactor fouling curve. A technique is also discussed for predicting reactor fouls by using statistical analyses, such as periodogram analysis, to identify leading indicators of impending fouls. Preventative measures may be performed upon identification of such a leading indicator. In addition, the statistical analyses may be used to identify catalysts having less propensity to foul.

    Abstract translation: 提供了防止聚合反应堆中反应堆犯规的技术。 提供了一种限制聚合物粒度以防止或限制与大聚合物颗粒相关的反应堆犯规的发生的技术。 还提供了用于测量反应器的一个或多个局部热点处的反应器温度并基于这些温度测量来控制聚合反应的技术。 特别地,反应的控制可以基于最热的温度,使得反应器中最热的温度保持在反应器结垢曲线内。 还讨论了一种通过使用统计分析(如周期图分析)来确定即将发生的犯规的领先指标来预测反应堆犯规的技术。 在确定此类领先指标时,可采取预防措施。 此外,统计学分析可用于鉴定具有较小的污染倾向的催化剂。

    TANDEM REACTOR SYSTEM HAVING AN INJECTIVELY-MIXED BACKMIXING REACTION CHAMBER, TUBULAR-REACTOR, AND AXIALLY MOVABLE INTERFACE
    17.
    发明申请
    TANDEM REACTOR SYSTEM HAVING AN INJECTIVELY-MIXED BACKMIXING REACTION CHAMBER, TUBULAR-REACTOR, AND AXIALLY MOVABLE INTERFACE 审中-公开
    具有混合的反射反应室,管状反应器和轴向可移动接口的TANDEM反应器系统

    公开(公告)号:WO2007133309A2

    公开(公告)日:2007-11-22

    申请号:PCT/US2007004185

    申请日:2007-02-19

    Abstract: A reactor system for gas phase reacting of at least two fluid feed streams, where the reactor system has an injectively-mixed backmixing reaction chamber in fluid communication with a tubular-flow reactor. The injectively-mixed backmixing reaction chamber has a bulkhead that slides during real-time operation to either diminish or expand the internal volume of the backmixing reaction chamber. In one embodiment, the effective passageway space through the bulkhead is also variably adjustable. In another embodiment, the tubular-flow reactor shares the bulkhead so that axial bulkhead movement commensurately expands one reaction space while diminishing the other reaction space. Input gas streams enter the backmixing reaction chamber with sufficient velocity to turbulently agitate the contents of the injectively-mixed backmixing reaction chamber by injective intermixing of the alkane-containing gas feed stream and the oxygen-containing gas feed stream. A focal application is for direct (partial) oxidative conversion of natural gas to alkyl oxygenates.

    Abstract translation: 一种用于至少两种流体进料流的气相反应的反应器系统,其中反应器系统具有与管式流动反应器流体连通的注射混合的后混合反应室。 喷射混合后混合反应室具有在实时操作期间滑动的隔板,以减小或扩大回混反应室的内部体积。 在一个实施例中,穿过隔板的有效通道空间也是可变的。 在另一个实施例中,管状流动反应器共用舱壁,使得轴向隔板移动相应地扩展一个反应空间,同时减小另一个反应空间。 输入气流以足够的速度进入回混反应室,通过含烷烃气体进料流和含氧气体进料流的注入混合来湍动地搅拌喷射混合回混反应室的内容物。 焦点应用是将天然气直接(部分)氧化转化为烷基含氧化合物。

    PLUG FLOW REACTOR AND POLYMERS PREPARED THEREWITH
    18.
    发明申请
    PLUG FLOW REACTOR AND POLYMERS PREPARED THEREWITH 审中-公开
    PLUG流动反应器和制备的聚合物

    公开(公告)号:WO2006124297A3

    公开(公告)日:2007-10-18

    申请号:PCT/US2006017038

    申请日:2006-05-04

    Abstract: A plug flow reactor having an inner shell (27) surrounded by outer shell (21) and having at least one annular flow passage (35) therebetween can be used to prepare compositions, including polymers. The plug flow reactor also includes inlet port (36), an outlet port (37) and a plurality of exchanger tubes (26) wherein the exchanger tubes are in fluid communication to the at least one annular flow passage. Polystyrene and high impact polystyrene can be prepared using the reactor.

    Abstract translation: 具有由外壳(21)包围并且在其间具有至少一个环形流动通道(35)的内壳(27)的活塞式流动反应器可用于制备包括聚合物的组合物。 活塞流反应器还包括入口端口(36),出口端口(37)和多个交换器管(26),其中交换器管与至少一个环形流动通道流体连通。 可以使用反应器制备聚苯乙烯和高抗冲聚苯乙烯。

    PROCESS FOR THE PRODUCTION OF POLYMERS USING A LOOP REACTOR
    19.
    发明申请
    PROCESS FOR THE PRODUCTION OF POLYMERS USING A LOOP REACTOR 审中-公开
    使用环流反应器生产聚合物的方法

    公开(公告)号:WO2006052590A2

    公开(公告)日:2006-05-18

    申请号:PCT/US2005/039627

    申请日:2005-11-02

    Abstract: A polymer can be prepared using a loop reactor and process including feeding a process stream through the loop reactor and maintaining the loop reactor at a steady state by controlling a flow of coolant fluid to maintain a temperature in the loop reactor at a preset point. The temperature in the loop reactor may be maintained at a preset point by using a coolant fluid flow controller and valve unit having a substantially linear response over the normal operating range of the controller and valve unit. The normal operating range of the controller and valve unit may be sufficient to provide a flow range not limiting to the throughput of the loop reactor.

    Abstract translation: 聚合物可以使用环管反应器和方法制备,包括通过环管反应器进料工艺流,并通过控制冷却剂流体的流动将环管反应器维持在稳定状态,以将回路反应器中的温度保持在预设点。 通过使用在控制器和阀单元的正常工作范围内具有基本上线性响应的冷却剂流体流量控制器和阀单元,可以将回路反应器中的温度保持在预设点。 控制器和阀门单元的正常操作范围可能足以提供不限制回路反应器的通量的流量范围。

    METHOD AND SYSTEM TO REDUCE POLYMERIZATION REACTOR FOULING
    20.
    发明申请
    METHOD AND SYSTEM TO REDUCE POLYMERIZATION REACTOR FOULING 审中-公开
    降低聚合反应器的方法和系统

    公开(公告)号:WO2006026224A2

    公开(公告)日:2006-03-09

    申请号:PCT/US2005/029784

    申请日:2005-08-23

    Abstract: Techniques are provided for the prevention of reactor fouls in polymerization reactors. A technique is provided for limiting polymer particle size to prevent or limit the occurrence of reactor fouls associated with large polymer particles. A technique is also provided for measuring reactor temperature at one or more local hot spots of the reactor and for controlling the polymerization reaction based upon these temperature measurements. In particular, control of the reaction may be based on the hottest temperature, such that the hottest temperature in the reactor is maintained within the reactor fouling curve. A technique is also discussed for predicting reactor fouls by using statistical analyses, such as periodogram analysis, to identify leading indicators of impending fouls. Preventative measures may be performed upon identification of such a leading indicator. In addition, the statistical analyses may be used to identify catalysts having less propensity to foul.

    Abstract translation: 提供了防止聚合反应堆中反应堆犯规的技术。 提供了限制聚合物粒度以防止或限制与大聚合物颗粒相关的反应器瑕疵的发生的技术。 还提供了用于测量反应器的一个或多个局部热点处的反应器温度并基于这些温度测量来控制聚合反应的技术。 特别地,反应的控制可以基于最热的温度,使得反应器中最热的温度保持在反应器结垢曲线内。 还讨论了一种通过使用统计分析(如周期图分析)来确定即将发生的犯规的领先指标来预测反应堆犯规的技术。 在确定这样的领先指标时,可以采取预防措施。 此外,统计分析可以用于鉴定具有较小的污染倾向的催化剂。

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