OLEFIN OLIGOMERIZATION CATALYSTS AND METHODS OF USING SAME
    41.
    发明申请
    OLEFIN OLIGOMERIZATION CATALYSTS AND METHODS OF USING SAME 审中-公开
    烯烃低聚催化剂及其使用方法

    公开(公告)号:WO2008014139A2

    公开(公告)日:2008-01-31

    申请号:PCT/US2007/073606

    申请日:2007-07-16

    IPC分类号: C07F9/50 C07C2/36 C07F11/00

    摘要: A metal complex comprising a metal compound complexed to a heteroatomic ligand, the metal complex having Structure (X), wherein R 1 , R 2 , R 3 , and R 4 are each independently an alkyl group, a cycloalkyl group, a substituted cycloalkyl group, an aromatic group, or a substituted aromatic group, R 1c , R 2c , R 3c , R 4c , and R 5c are each independently hydrogen or an alkyl group, and MXp comprises a group IVB, VB, or VIB metal. A metal complex comprising a metal compound complexed to a diphosphino aminyl ligand comprising at least two diphosphino aminyl moieties and a linking group linking each aminyl nitrogen atom of the diphosphino aminyl moieties.

    摘要翻译: 包含与杂原子配体络合的金属化合物的金属络合物,所述金属络合物具有结构(X),其中R 1,R 2, ,R 3和R 4各自独立地为烷基,环烷基,取代的环烷基,芳族基团或取代的芳族基团,R

    PHOSPHORUS SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION
    44.
    发明申请
    PHOSPHORUS SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
    用于烯烃聚合的磷取代金属化合物

    公开(公告)号:WO2005108410A1

    公开(公告)日:2005-11-17

    申请号:PCT/US2005/008388

    申请日:2005-03-11

    IPC分类号: C07F17/00

    摘要: This invention relates to a metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is an indenyl ligand that is substituted with a PR2 group in the two position of the indenyl ligand, where each R is, independently a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl substituent, and additionally, E may be substituted with 0, 1, 2, 3, 4, 5 or 6 R ° where each R" is, independently, a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent, and optionally, two or more adjacent R ° substituents may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E or as X; each X is, independently, an univalent anionic ligand, cz both X are joined and bound to the metal atom to, form a metallocycle ring, or, both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.

    摘要翻译: 本发明涉及由下式表示的茂金属化合物:其中M是3,4,5或6族过渡金属原子,或镧系元素金属原子或锕系金属原子; E是在茚基配体的两个位置被PR 2基团取代的茚基配体,其中每个R独立地是烃基,取代的烃基,卤代烃基或取代的卤代烃基取代基,另外E可以被0, 1,2,3,4,5或6个R“,其中每个R”独立地是烃基,取代的烃基,卤代烃基,取代的卤代烃基,甲硅烷基,取代的甲硅烷基,锗烷基或取代的己基羰基取代基,以及任选的两个 或更多相邻的R 0取代基可以连接在一起以形成取代或未取代的,饱和的,部分不饱和的或芳族的环状或多环取代基; A是取代或未取代的环戊二烯基配体,取代或未取代的杂环戊二烯基配体,取代或未取代的 取代或未取代的杂茚基配体,取代或未取代的芴基配体,取代或未取代的杂环 芴基配体或其它单阴离子配体,或A可以独立地定义为E或X定义; 每个X独立地是一价阴离子配体,两个X连接并结合到金属原子上,形成金属环,或者两者X连接形成螯合配体,二烯配体或亚烷基配体。