摘要:
The present invention relates to a method for manufacturing a conductive metal thin film, including: preparing a conductive metal coating solution by adding carboxylic acid to a dispersion including a conductive metal particle having a core/shell structure; coating the conductive metal coating solution on a top portion of a substrate, heat-treating it, and removing an metal oxide layer of the surface of the conductive metal particle having the core/shell structure; and forming a thin film of the conductive metal particle from which the metal oxide layer is removed.
摘要:
Abstract An electroless palladium plating solution includes a polar solvent, at least one palladium salt, at least one non-nitrogenated complexing agent, an alkaline adjusting agent that adjusts the plating solution to a pH of at least 8.0, and a reducing agent. The plating solution, which is used for forming a layer of palladium on a surface of a substrate, yields a substantially pure palladium deposit on the substrate. Precipitation of reduced palladium in the plating solution is substantially prevented.
摘要:
Processes for making multinary bulk and thin film alloys with nanometer-scale grains are disclosed. An electroless process includes contacting a substrate with a bath within a sealed pressure vessel; and heating the sealed pressure vessel for a time and at a temperature under an autogeneous pressure effective for plating a film of an alloy with nanometer-scale grains onto a contacted portion of the substrate; wherein the bath is formed from one or more salts comprising each constituent element of the alloy, an organic medium, and a reducing agent. The bulk and thin film alloys may be useful in applications requiring high surface area materials or protection from corrosion such as for catalysts and battery cathodes.
摘要:
The present invention provides an improved aqueous alkaline zincate solution comprising hydroxide ions, zinc ions, nickel ions and/or cobalt iron ions, copper ions, and at least one inhibitor containing one or more nitrogen atoms, sulfur atoms, or both nitrogen and sulfur atoms provided said nitrogen atoms are not present in an aliphatic amine or hydroxylamine. The present invention also relates to methods for depositing zincate coatings on aluminum and aluminum alloys comprising applying an immersion zincate coating on an aluminum or aluminum alloy substrates, optionally followed by plating the zincate coated aluminum or aluminum alloy substrate using an electroless or electrolytic metal plating solution.
摘要:
Methods and apparatus are provided for forming a metal or metal silicide layer by an electroless deposition technique. In one aspect, a method is provided for processing a substrate including depositing an initiation layer on a substrate surface, cleaning the substrate surface, and depositing a conductive material on the initiation layer by exposing the initiation layer to an electroless solution. The method may further comprise etching the substrate surface with an acidic solution and cleaning the substrate of the acidic solution prior to depositing the initiation layer. The initiation layer may be formed by exposing the substrate surface to a noble metal electroless solution or a borane-containing solution. The conductive material may be deposited with a borane-containing reducing agent. The conductive material may be used as a passivation layer, a barrier layer, a seed layer, or for use in forming a metal silicide layer.
摘要:
There is provided a semiconductor device having such a protective film that selectively covers the surface of embedded interconnects and can effectively prevent both of the oxidation and the thermal diffusion of the interconnects. A method for manufacturing such a semiconductor device is also provided. The semiconductor device includes: a semiconductor substrate having an embedded interconnect structure in which the embedded interconnects have an exposed surface; and a protective film composed of a multi-layer laminated film formed selectively on the exposed surface of interconnects. The multi-layer laminated film preferably includes an oxidation-preventing layer, composed of e.g. a Ni or Ni alloy layer, for preventing oxidation of the interconnects, and a thermal diffusion-preventing layer, composed of e.g. a Co or Co alloy layer, for preventing thermal diffusion of the interconnects.
摘要:
The invention relates to a method for surface-coating apparatuses and parts of apparatuses for the construction of chemical installations, for example apparatus, container and reactor walls, discharging devices, fittings, pumps, filters, compressors, centrifuges, columns, heat exchangers, dryers, reducing machines, built-in parts, packing and mixing mechanisms. The method is characterised in that bumps with an average height of 100 nm to 50 mu m are produced on the surface to be coated, at average intervals of 100 nm to 100 mu m, before the surface is coated by currentlessly depositing a layer of metal or a layer of a metal-polymer-dispersion using a galvanisation bath containing a metal electrolyte, a reduction agent and optionally, a polymer or polymer mixture to be deposited, in dispersed form.