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公开(公告)号：WO1994014754A1
公开(公告)日：1994-07-07
申请号：PCT/JP1993001876
申请日：1993-12-24
IPC分类号： C07C211/64
CPC分类号： C07C229/18 , C07C211/64 , C07C215/16 , C07C217/28 , C07C219/06 , C07C219/12 , C07C225/06 , C07C255/24 , C07C2601/14
摘要： An anilinium salt compound represented by general formula (I) and a cationic polymerization initiator containing at least one said compound, wherein R1 represents hydrogen, alkyl, etc.; R2 represents alkyl, etc.; R3 represents alkyl substituted on the alpha -, beta - or UPSILON -carbon atom with respect to the nitrogen atom; R4 and R5 represents each hydrogen, halogen etc.; and X represents a non-nucleophilic counter anion residue. When the invention compound is used as a polymerization initiator, a cationically polymerizable compound can readily be polymerized under a mild temperature condition of near ordinary temperature up to 100 DEG C. When used as a curing catalyst, it can readily provide a cured article having high cross-linking density and glass transition point and excellent properties in the comparatively low temperature range of ordinary temperature to near 170 DEG C.
摘要翻译： 由通式（I）表示的苯胺鎓盐化合物和含有至少一种所述化合物的阳离子聚合引发剂，其中R1表示氢，烷基等; R2代表烷基等; R3表示相对于氮原子在α，β或UPSILON-碳原子上取代的烷基; R4和R5代表每个氢，卤素等; X表示非亲核抗衡阴离子残基。 当本发明化合物用作聚合引发剂时，阳离子聚合性化合物可以在接近常温至100℃的温和条件下容易地聚合。当用作固化催化剂时，可以容易地提供具有高 交联密度和玻璃化转变点，在常温至170℃的较低温度范围内具有优异的性能。
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公开(公告)号：WO1998025977A1
公开(公告)日：1998-06-18
申请号：PCT/JP1997004509
申请日：1997-12-09
申请人： NIPPON SODA CO., LTD. , MURAMOTO, Hiroo , YAMASE, Yukio , NOBUHARA, Yukikazu , MATSUMOTO, Hitoshi , SHIMIZU, Yutaka
IPC分类号： C08F220/12
CPC分类号： C08F297/026 , C08F220/04 , C08F220/12 , C08F220/18
摘要： Random or block copolymers of a (meth)acrylic ester, which comprise structural units represented by general formulae (I) and (II) and have a number-average molecular weight of 1,000 to 50,000, a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio, Mw/Mn, of 1.00 to 1.40, and a ratio of the repeating structural units represented by formula (I) to those represented by formula (II) of 1/9 to 9/1 (wherein R1 and R2 each independently represents hydrogen or methyl; R3 represents an optionally substituted C7-15 alicyclic group or an alkyl group having the alicyclic group; and R4 represents hydrogen, an optionally substituted C1-12 alkyl, optionally substituted C3-6 alicyclic or heterocyclic group, or substituted silyl group having a C1-8 alkyl and/or aryl group). The copolymers have each a unimodal narrow molecular weight distribution and an essential skeleton having at least one segment with a controlled structure comprising (meth)acrylic ester units each having an organic group containing a bulky alicyclic group.
摘要翻译： （甲基）丙烯酸酯的无规或嵌段共聚物，其包含由通式（I）和（II）表示的结构单元，数均分子量为1,000至50,000，重均分子量（Mw）至 数均分子量（Mn）比，Mw / Mn为1.00〜1.40，由式（I）表示的重复结构单元与式（II）表示的重复结构单元的比例为1/9〜9/1 其中R 1和R 2各自独立地表示氢或甲基; R 3表示任选取代的C 7-15脂环基或具有脂环基的烷基; R 4表示氢，任选取代的C 1-12烷基，任选取代的C 3-6脂环族或 杂环基或具有C1-8烷基和/或芳基的取代甲硅烷基）。 共聚物各自具有单峰窄分子量分布和具有至少一个具有受控结构的链段的必需骨架，其包含各自具有含有大体积脂环族基团的有机基团的（甲基）丙烯酸酯单元。
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公开(公告)号：WO1995024387A1
公开(公告)日：1995-09-14
申请号：PCT/JP1995000364
申请日：1995-03-07
IPC分类号： C07C381/12
CPC分类号： C08G59/687 , C07C381/12 , C08F2/50
摘要： A sulfonium salt compound represented by general formula (I) and a curable composition containing the compound, wherein R1 represents C1-C18 alkyl, hydroxy, C1-C18 alkoxy, C1-C18 alkylcarbonyloxy or halogen, and n represents 0, 1, 2 or 3, provided when n represents 2 or 3, R1's may be different from each other; R2 represents C1-C6 alkyl; R3 and R4 represent each hydrogen or C1-C6 alkyl; R5 and R6 represent each hydrogen, C1-C6 alkyl, hydroxy, C1-C6 alkoxy, C1-C18 alkylcarbonyloxy or aromatic carbonyloxy; R7 represents C4-C20 alkyl or a group represented by general formula (II), wherein R8 represents C1-C18 alkyl, hydroxy, C1-C18 alkoxy, C1-C18 alkylcarbonyloxy, aromatic carbonyloxy or halogen, and m represents 0, 1, 2 or 3, provided when m represents 2 or 3, R8's may be different from each other; and X represents a nonnucleophilic anion residue. As a curable composition particularly comprising a sulfonium salt compound of formula (I), a sensitizer, and a cationically polymerizable compound is cured by heat or light in a short time, it is suitably usable as coating material, adhesive and photoresist.
摘要翻译： 由通式（I）表示的锍盐化合物和含有该化合物的可固化组合物，其中R1表示C1-C18烷基，羟基，C1-C18烷氧基，C1-C18烷基羰氧基或卤素，n表示0,1,2或 3，当n表示2或3时，R1可以彼此不同; R2代表C1-C6烷基; R3和R4代表每个氢或C1-C6烷基; R5和R6代表每个氢，C1-C6烷基，羟基，C1-C6烷氧基，C1-C18烷基羰氧基或芳香羰氧基; R7表示C4-C20烷基或由通式（II）表示的基团，其中R8表示C1-C18烷基，羟基，C1-C18烷氧基，C1-C18烷基羰基氧基，芳香族羰基氧基或卤素，m表示0,1,2 或3，当m表示2或3时，R8可以彼此不同; X表示非亲核阴离子残基。 作为特别是包含式（I）的锍盐化合物的可固化组合物，敏化剂和阳离子聚合性化合物在短时间内通过热或光固化，因此适合用作涂料，粘合剂和光致抗蚀剂。
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公开(公告)号：WO1992021712A1
公开(公告)日：1992-12-10
申请号：PCT/JP1992000686
申请日：1992-05-27
IPC分类号： C08G77/10
CPC分类号： C08G77/42 , C08G77/442
摘要： A modified polysiloxane compound having a phenol skeleton controlled in molecular weight and molecular structure. It can be produced by conducting the anionic homopolymerization of a compound represented by general formula (I) wherein the phenolic hydroxyl group is protected with a saturated aliphatic protective group or the anionic copolymerization thereof with a compound copolymerizable therewith, adding a cyclic siloxane compound to the formed polymer to effect copolymerization, and removing the protective group (a) wherein R represents hydrogen or methyl.
摘要翻译： 具有分子量和分子结构控制的酚骨架的改性聚硅氧烷化合物。 可以通过对通式（I）表示的化合物进行阴离子均聚反应来制备，其中酚羟基被饱和脂族保护基保护，或者与可与其共聚的化合物进行阴离子共聚，向环状硅氧烷化合物加入环状硅氧烷化合物 形成的聚合物进行共聚，除去保护基（a），其中R 1表示氢或甲基。
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公开(公告)号：WO1986006085A1
公开(公告)日：1986-10-23
申请号：PCT/JP1986000173
申请日：1986-04-09
申请人： MITSUBISHI GAS CHEMICAL COMPANY, INC. , NIPPON SODA CO., LTD. , GAKU, Morio , KIMBARA, Hidenori , MURAMOTO, Hiroo , HIGASHIDA, Shiro , SATO, Fumio
IPC分类号： C08L09/06
CPC分类号： H05K1/0353 , C08G59/12 , C08G59/4014 , C08L19/006 , C08L63/00 , C08L63/10 , C08L79/06 , Y10T428/31525 , Y10T428/31529 , Y10T428/31645 , Y10T428/31692 , C08L2666/14 , C08L2666/20
摘要： Thermosetting resin composition comprising a thermosetting cyanate ester resin composition (A) and a butadiene based copolymer (B) (i) or an epoxy resin-modified butadiene based copolymer (B) (ii), in which said component (B) (i) or (B) (ii) are used for modifying said component (A), component (A) and (B) being as follows; (A) a cyanate ester thermosetting resin composition comprising a cyanate ester compound selected from the group consisting of, (i) a polyfunctional cyanate ester having at least two cyanate group in its molecule, (ii) prepolymer of the cyanate ester of (i), (iii) coprepolymer of the cyanate ester of (i) and an amine, and (iv) mixtures thereof, and optionally adding another thermosetting resin, (B) (i) a butadiene based copolymer comprising a butadiene-aromatic vinyl monomer copolymer having 0.5 or more functional groups selected from a group consisting of carboxyl radical, hydroxyl radical, acid anhydride radical, mercapto radical, epoxy radical and amino radical, and a melting point of 10 C or more, in which 1,2-type content in butadiene structure of copolymer chain is 50% or more, (ii) an epoxy resin-modified butadiene based copolymer comprising said butadiene based copolymer (B) (i) having a carboxy radical modified with polyfunctional epoxy resin, and having a melting point of 10 C or more and an epoxy equivalent of 300-8,000.
摘要翻译： 包含热固性氰酸酯树脂组合物（A）和丁二烯共聚物（B）（i）或环氧树脂改性丁二烯共聚物（B）（ii））的热固性树脂组合物，其中所述组分（B）（i） 或（B）（ii）用于改性所述组分（A），组分（A）和（B）如下： （A）氰酸酯热固性树脂组合物，其包含氰酸酯化合物，所述氰酸酯化合物选自：（i）分子中具有至少两个氰酸酯基的多官能氰酸酯，（ii）（i）的氰酸酯的预聚物， ，（iii）（i）的氰酸酯与胺的共聚物，和（iv）其混合物，和任选地加入另外的热固性树脂，（B）（i）包含丁二烯 - 芳族乙烯基单体共聚物的丁二烯基共聚物，其具有 0.5个以上选自羧基，羟基，酸酐基，巯基，环氧基和氨基的官能团，熔点为10℃以上，其中1,2-型 共聚物链的丁二烯结构中的含量为50％以上，（ii）包含用多官能环氧树脂改性的羧基的所述丁二烯类共聚物（B）（i）的环氧树脂改性丁二烯类共聚物，其熔点 的10 环氧当量为300-8,000。
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公开(公告)号：WO1994029271A1
公开(公告)日：1994-12-22
申请号：PCT/JP1994000953
申请日：1994-06-14
IPC分类号： C07C381/12
CPC分类号： C08F4/00 , C07C381/12 , C08G59/687
摘要： A sulfonium salt compound represented by general formula (I), useful as a cationic polymerization initiator, wherein R1 represents benzyl, phenyl, etc.; R2, R3 and R4 represent each hydrogen, alkyl, etc.; R5 represents hydrogen, alkyl, phenyl, etc.; R6 represents -(CH2)m- R11, wherein R11 represents COR12, COOR13, OR14, cyano, OCOR15 or SOR16 (wherein R12, R13, R14, R15 and R16 represent each hydrogen, alkyl or phenyl) and m represents O or 1; and X represents SbF6, AsF6, PF6 or BF4.
摘要翻译： 由通式（I）表示的锍盐化合物，可用作阳离子聚合引发剂，其中R1表示苄基，苯基等; R2，R3和R4代表氢，烷基等; R5代表氢，烷基，苯基等; R6表示 - （CH2）m -R11，其中R11表示COR12，COOR13，OR14，氰基，OCOR15或SOR16（其中R12，R13，R14，R15和R16各自表示氢，烷基或苯基），m表示0或1; X表示SbF 6，AsF 6，PF 6或BF 4。
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