公开(公告)号：WO2016096967A1

公开(公告)日：2016-06-23

申请号：PCT/EP2015/079966

申请日：2015-12-16

Applicant: BASF SE

Inventor： YAMATO, Hitoshi ,  TSUDA, Takuya ,  WU, Chao ,  WEITZ, Thomas ,  EUSTACHI, Michael ,  HEMGESBERG, Maximilian

IPC: C07D513/14

CPC classification number: H01L51/0071 ,  C07D513/14 ,  H01L51/0562

Abstract: The present invention provides compounds of formula (I) wherein X is O, S or NR 10 , wherein R 10 is H, C 1-30 -alkyl, substituted C 1-30 -alkyl, C 2-30 -alkenyl, substituted C 2-30 -alkenyl, C 2-30 -alkynyl, substituted C 2-30 -alkynyl or C(0)-OR 11 , R 1 and R 11 are independently from each other selected from the group consisting of C 1-30 -alkyl, substituted C 1-30 -alkyl, C 2-30 -alkenyl, substituted C 2-30 -alkenyl, C 2-30 -alkynyl, substituted C 2-30 -alkynyl, C 5-8 -cycloalkyl, substituted C 5-8 -cycloalkyl, C 5-8 -cycloalkenyl, and substituted C 5-8 -cycloalkenyl, and an electronic device comprising the compounds as semiconducting material.

Abstract translation: 本发明提供式（I）化合物，其中X为O，S或NR 10，其中R 10为H，C 1-30 - 烷基，取代的C 1-30 - 烷基，C 2-30 - 烯基，取代的C 2-30 - 烯基， C 2-30 - 炔基，取代的C 2-30 - 炔基或C（O）-OR 11，R 1和R 11彼此独立地选自C 1-30 - 烷基，取代的C 1-30 - 烷基，C 2-30 - 烯基，取代的C 2-30 - 烯基，C 2-30 - 炔基，取代的C 2-30 - 炔基，C 5-8 - 环烷基，取代的C 5-8 - 环烷基，C 5-8 - 环烯基和取代的C 5-8-环烯基， 以及包含化合物作为半导体材料的电子器件。

公开(公告)号：WO2016066494A1

公开(公告)日：2016-05-06

申请号：PCT/EP2015/074369

申请日：2015-10-21

Applicant: BASF SE

Inventor： NEKELSON, Fabien ,  YAMATO, Hitoshi ,  AGARI, Michaela ,  SEND, Robert

IPC: C07D333/20 ,  C07D409/14 ,  C07D495/04 ,  C07D495/14 ,  C07D495/22 ,  C09K11/06 ,  H01L51/00

CPC classification number: C07D495/04 ,  C07D333/20 ,  C07D409/14 ,  C07D495/14 ,  C07D495/22 ,  C09K11/06 ,  H01L51/0059 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/4226 ,  Y02E10/549

Abstract: The present invention relates to hole-transport materials in organic solar cells. In particular the present invention relates to a compound of general formula (I), wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 are independent of each other H, an alkyi group, an alkoxy group, an alkyi thiol group or an aryl group, X 1 , X 2 are independent of each other H, an alkyi group, an alkoxy group, an alkyi thiol group, or an aryl group, wherein X 1 , X 2 can form together a ring and wherein at least one of X 1 , X 2 is not H.

Abstract translation: 本发明涉及有机太阳能电池中的空穴传输材料。 特别地，本发明涉及通式（I）的化合物，其中R1，R2，R3，R4，R5，R6，R7，R8，R9彼此独立地为H，烷基，烷氧基， 烷基硫醇基或芳基，X1，X2彼此独立地为氢，烷基，烷氧基，烷硫基或芳基，其中X1，X2可以一起形成环，其中至少一个 的X1，X2不是H.

公开(公告)号：WO2015159192A1

公开(公告)日：2015-10-22

申请号：PCT/IB2015/052622

申请日：2015-04-10

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： ERK, Peter ,  BRUDER, Ingmar ,  DIETSCH, Herve ,  SCHWAB, Matthias Georg ,  CHA, Kitty Chih-Pei ,  NAKAMICHI, Shinji ,  YAMATO, Hitoshi ,  TAKAHASHI, Ryuichi

IPC: H01L51/42

CPC classification number: H01L51/0021 ,  H01G9/2022 ,  H01L51/0032 ,  H01L51/4226 ,  Y02E10/549 ,  Y02P70/521

Abstract: An electrically conductive inter layer is provided between hole transport layer and counter electrode in a solid dye-sensitized solar cell or a Perovskite solar cell and a process is provided for the production of said inter layer. This process can beneficially be integrated in a process for the production of printed solid dye-sensitized solar cells or Perovskite solar cells under ambient conditions.

Abstract translation: 在固体染料敏化太阳能电池或钙钛矿太阳能电池中，在空穴传输层和对电极之间设置导电层间层，并且提供用于制造所述层间的工艺。 该方法可以有益地集成在环境条件下生产印刷的固体染料敏化太阳能电池或钙钛矿太阳能电池的工艺中。

公开(公告)号：WO2019101569A1

公开(公告)日：2019-05-31

申请号：PCT/EP2018/081011

申请日：2018-11-13

Applicant: BASF SE

Inventor： YAMATO, Hitoshi ,  TSUDA, Takuya ,  DOI, Iori ,  NEKELSON, Fabien

IPC: C07D495/04 ,  H01L29/772 ,  H01L51/00 ,  H01L51/30 ,  H01L51/46

CPC classification number: C07D495/04 ,  H01L29/772 ,  H01L51/0074 ,  H01L51/0558

Abstract: The present invention provides a process for manufacturing an electronic device comprising a semiconducting layer, which process comprises i) a step of applying a composition comprising at least a compound of formulae (1A)-(1B)-(1C) on a precursor of the electronic device in order to form a layer, and ii) a step of treating the layer of step i) with light in order to form a semiconducting layer, we well as a compound of formula 1A, 1B or 1C, compositions comprising at least one compound of formula 1A, 1B or 1C, and the use of at least one compound of formula 1A, 1B or 1C as photocleavable precursor for organic semiconducting materials.

公开(公告)号：WO2015011638A1

公开(公告)日：2015-01-29

申请号：PCT/IB2014/063298

申请日：2014-07-22

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： YAMATO, Hitoshi ,  NAKAMICHI, Shinji ,  TAKAHASHI, Ryuichi ,  YAMAMOTO, Hiroshi ,  SEND, Robert ,  WONNEBERGER, Henrike ,  BRUDER, Ingmar ,  GETAUTIS, Vytautas ,  KASPARAS, Rakstys ,  MALINAUSKAS, Tadas

IPC: C09B23/00 ,  H01L51/00 ,  H01G9/20

CPC classification number: H01G9/2059 ,  C09B23/0091 ,  C09B23/105 ,  C09B23/12 ,  C09B23/14 ,  C09B23/146 ,  C09B23/148 ,  C09B23/164 ,  C09B26/00 ,  C09B29/00 ,  C09B29/0832 ,  C09B57/00 ,  C09B57/001 ,  C09B57/007 ,  C09B57/008 ,  C09B69/02 ,  C09B69/04 ,  C09B69/045 ,  C09B69/06 ,  H01G9/2027 ,  H01G9/2031 ,  H01L51/0054 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0064 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0069 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549 ,  Y02P70/521

Abstract: The present invention relates to an electrode layer comprising a porous film made of oxide semiconductor fine particles sensitized with a methine dye having a counter anion capable of absorbing electromagnetic radiation having a wavelength in the range of from 400 nm to 1000 nm. Moreover the present invention relates to a photoelectric conversion device comprising said electrode layer, a dye sensitized solar cell comprising said photoelectric conversion device, an organic electronic device comprising said photoelectric conversion device and to novel methine dyes having a counter anion capable of absorbing electromagnetic radiation having a wavelength in the range of from 400 nm to 1000 nm.

Abstract translation: 本发明涉及一种电极层，其包括由具有能够吸收波长在400nm至1000nm范围内的电磁辐射的具有抗衡阴离子的次甲基染料敏化的氧化物半导体微粒制成的多孔膜。 此外，本发明涉及包括所述电极层的光电转换装置，包括所述光电转换装置的染料敏化太阳能电池，包括所述光电转换装置的有机电子装置和具有能够吸收电磁辐射的抗衡阴离子的新的次甲基染料， 在400nm至1000nm范围内的波长。

公开(公告)号：WO2009150074A1

公开(公告)日：2009-12-17

申请号：PCT/EP2009/056703

申请日：2009-06-02

Applicant: BASF SE ,  NISHIMAE, Yuichi ,  ASAKURA, Toshikage ,  YAMATO, Hitoshi

Inventor： NISHIMAE, Yuichi ,  ASAKURA, Toshikage ,  YAMATO, Hitoshi

IPC: C07D327/08 ,  C07D339/08 ,  G03F7/00

CPC classification number: C07D339/08 ,  C07D327/08

Abstract: Compounds of the formula (I), wherein R 1 , R 2 and R 3 for example are hydrogen, halogen, CN, C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, (CO)R 8 , (CO)OR 4 , or (CO)NR 5 R 6 ; Y is O, S or CO; D 2 , D 3 and D 4 for example are a direct bond, O, S, NR 7 , CO, O(CO), (CO)O, S(CO), (CO)S, NR 7 (CO), (CO)NR 7 , SO, SO 2 , or OSO 2 , C 1 -C 18 alkylene, C 3 -C 30 cycloalkylene, C 2 -C 12 alkenylene, C 4 -C 30 cycloalkenylene, Ar 1 ; Ar 1 , Ar 2 and Ar 3 are for example phenylene, R 4 , R 5 , R 6 , R 7 and R 8 are for example hydrogen, C 3 -C 30 cycloalkyl, C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, C 2 -C 12 alkenyl, C 4 -C 30 cycloalkenyl, phenyl-C 1 C 3 -alkyl; X - is Formulae (IA), (IB) or (IC); R 10 is for example C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, camphoryl, phenyl-C 1 -C 3 alkyl, C 3 -C 30 cycloalkyl; and R 11 , R 12 , R 13 , R 14 and R 15 are for example C 1 -C 10 haloalkyl; are useful as polymerizable photolatent acids.

Abstract translation: 式（I）化合物，其中R1，R2和R3例如是氢，卤素，CN，C1-C18烷基，C1-C10卤代烷基，（CO）R8，（CO）OR4或（CO）NR5R6; Y为O，S或CO; D2，D3和D4例如是直接键合，O，S，NR7，CO，O（CO），（CO）O，S（CO），（CO）S，NR7（CO） SO，SO 2或OSO 2，C 1 -C 18亚烷基，C 3 -C 30亚环烷基，C 2 -C 12亚烯基，C 4 -C 30环亚烯基，Ar 1; Ar 1，Ar 2和Ar 3是例如亚苯基，R 4，R 5，R 6，R 7和R 8是例如氢，C 3 -C 30环烷基，C 1 -C 18烷基，C 1 -C 10卤代烷基，C 2 -C 12烯基，C 4 -C 30环烯基，苯基-C 1 -C 3烷基; X-是式（IA），（IB）或（IC）; R 10例如为C 1 -C 18烷基，C 1 -C 10卤代烷基，樟脑基，苯基-C 1 -C 3烷基，C 3 -C 30环烷基; R 11，R 12，R 13，R 14和R 15例如为C 1 -C 10卤代烷基; 可用作可聚合的光潜酸。

公开(公告)号：WO2013144177A1

公开(公告)日：2013-10-03

申请号：PCT/EP2013/056461

申请日：2013-03-27

Applicant: BASF SE ,  BASF SCHWEIZ AG

Inventor： SEND, Robert ,  BRUDER, Ingmar ,  ERK, Peter ,  SENS, Rüdiger ,  YAMAMOTO, Hiroshi ,  YAMATO, Hitoshi ,  NAKAMICHI, Shinji ,  TAKAHASHI, Ryuichi

IPC: C09B23/10 ,  C09B69/06 ,  H01G9/20 ,  H01L51/00 ,  C09B23/00 ,  C09B23/14 ,  C09B57/00 ,  C09B23/01

CPC classification number: H01L51/0072 ,  C09B23/0091 ,  C09B23/105 ,  C09B23/148 ,  C09B57/008 ,  C09B69/06 ,  C09K11/06 ,  C09K2211/1014 ,  C09K2211/1018 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0059 ,  H01L51/0064 ,  Y02E10/542 ,  Y02E10/549

Abstract: The present invention relates to an electrode layer comprising a porous film made of oxide semiconductor fine particles sensitized with a quinolinium dye having a fluorinated counteranion. Moreover the present invention relatesto a photoelectric conversion device comprising said electrode layer, a dye sensitized solar cell comprising said photoelectric conversion device and to novel quinolinium dyes having a fluorinated counteranion.

Abstract translation: 本发明涉及一种电极层，其包括由具有氟化抗衡阴离子的喹啉染料敏化的氧化物半导体微粒制成的多孔膜。 此外，本发明涉及包括所述电极层，包含所述光电转换装置的染料敏化太阳能电池和具有氟化抗衡阴离子的新型喹啉染料的光电转换装置。

公开(公告)号：WO2011120908A1

公开(公告)日：2011-10-06

申请号：PCT/EP2011/054704

申请日：2011-03-28

Applicant: BASF SE ,  YAMAMOTO, Hiroshi ,  NAKAMICHI, Shinji ,  TANABE, Junichi ,  TAKAHASHI, Ryuichi ,  YAMATO, Hitoshi

Inventor： YAMAMOTO, Hiroshi ,  NAKAMICHI, Shinji ,  TANABE, Junichi ,  TAKAHASHI, Ryuichi ,  YAMATO, Hitoshi

IPC: H01G9/20 ,  C09B23/14

CPC classification number: H01G9/2059 ,  C09B23/0008 ,  C09B23/107 ,  C09B23/145 ,  H01G9/2031 ,  H01G9/2063 ,  H01L51/0064 ,  H01L51/0072 ,  H01L51/4206 ,  Y02E10/542 ,  Y02E10/549

Abstract: The present invention pertains to an electrode layer comprising a porous film made of oxide semiconductor fine particles sensitized with certain methin dyes. Moreover the present invention pertains to a photoelectric conversion device comprising said electrode layer, a dye sensitized solar cell comprising said photoelectric conversion device and to novel methin dyes.

Abstract translation: 本发明涉及包含由用某些次甲基染料敏化的氧化物半导体微粒制成的多孔膜的电极层。 此外，本发明涉及一种包含所述电极层的光电转换装置，包含所述光电转换装置的染料敏化太阳能电池以及新颖次甲基染料。

公开(公告)号：WO2011104127A1

公开(公告)日：2011-09-01

申请号：PCT/EP2011/051995

申请日：2011-02-10

Applicant: BASF SE ,  YAMATO, Hitoshi ,  ASAKURA, Toshikage ,  MATSUMOTO, Akira ,  TANAKA, Keita ,  NISHIMAE, Yuichi

Inventor： YAMATO, Hitoshi ,  ASAKURA, Toshikage ,  MATSUMOTO, Akira ,  TANAKA, Keita ,  NISHIMAE, Yuichi

IPC: C07C309/08 ,  C07C309/12 ,  C07C311/53 ,  C07C333/06 ,  C07C381/12 ,  C07C25/18 ,  G03F7/004 ,  G03F7/039 ,  C07D209/00 ,  C07D241/00 ,  C07D265/00 ,  C07D311/00 ,  C07D235/00

CPC classification number: C07C381/12 ,  C07C25/18 ,  C07C309/08 ,  C07C309/12 ,  C07C311/53 ,  C07C333/06 ,  C07C2601/14 ,  C07C2602/42 ,  C07C2603/74 ,  C07D207/28 ,  C07D233/38 ,  C07D241/08 ,  C07D295/205 ,  C07D295/215 ,  C07D493/08 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/0382 ,  G03F7/0392

Abstract: The invention pertains to a compound generating an acid of the formula (I) or (II), for instance corresponding sulfonium and iodonium salts, as well as corresponding sulfonyloximes, Formula (I) and Formula (II), wherein X is CH 2 or CO; Y is O, NR 4 , S, O(CO), O(CO)O, O(CO)NR 4 , OSO 2 , O(CS), or O(CS)NR 4 ; R 1 is for example C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, C 2 -C 12 alkenyl, C 4 -C 30 cycloalkenyl, phenyl-C 1 -C 3 -alkyl, C 3 -C 30 cycloalkyl, C 3 -C 30 cycloalkyl-C 1 -C 18 alkyl, interrupted C 2 -C 18 alkyl, interrupted C 3 -C 30 cycloalkyl, interrupted C 3 -C 30 cycloalkyl-C 1 -C 18 alkyl, interrupted C 4 -C 30 cycloalkenyl, phenyl, naphthyl, anthracyl, phenanthryl, biphenylyl, fluorenyl or heteroaryl, all unsubstituted or are substituted; or R 1 is NR 12 R 13 ; R 2 and R 3 are for example C 3 -C 30 cycloalkylene, C 3 -C 30 cycloalkyl-C 1 -C 18 alkylene, C 1 -C 18 alkylene, C 1 -C 10 haloalkylene, C 2 -C 12 alkenylene, C 4 -C 30 cycloalkenylene, phenylene, naphthylene, anthracylene, phenanthrylene, biphenylene or heteroarylene; all unsubstituted or substituted; R 4 is for example C 3 -C 30 cycloalkyl, C 3 -C 30 cycloalkyl-C 1 -C 18 alkyl, C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, C 2 -C 12 alkenyl, C 4 -C 30 cycloalkenyl, phenyl-C 1 -C 3 -alkyl; R 12 and R 13 are for example C 3 -C 30 cycloalkyl, C 3 -C 30 cycloalkyl-C 1 -C 18 alkyl, C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, C 2 -C 12 alkenyl, C 4 -C 30 cycloalkenyl, phenyl-C 1 -C 3 -alkyl, Ar, (CO)R 15 , (CO)OR 15 or SO 2 R 15 ; and Ar is phenyl, biphenylyl, fluorenyl, naphthyl, anthracyl, phenanthryl or heteroaryl, all unsubstituted or substituted.

Abstract translation: 本发明涉及产生式（I）或（II）的酸的化合物，例如相应的锍盐和碘鎓盐，以及相应的磺酰肟，式（I）和式（II），其中X是CH 2或CO ; Y是O，NR4，S，O（CO），O（CO）O，O（CO）NR4，OSO2，O（CS）或O（CS）NR4; R 1是例如C 1 -C 18烷基，C 1 -C 10卤代烷基，C 2 -C 12烯基，C 4 -C 30环烯基，苯基-C 1 -C 3烷基，C 3 -C 30环烷基，C 3 -C 30环烷基-C 1 -C 18烷基，间断的C 2 -C 18烷基，间断的C 3 -C 30环烷基， 间断的C 3 -C 30环烷基-C 1 -C 18烷基，间断的C 4 -C 30环烯基，苯基，萘基，蒽基，菲基，联苯基，芴基或杂芳基，全部未取代或被取代; 或R1是NR12R13; R2和R3是例如C 3 -C 30亚环烷基，C 3 -C 30环烷基-C 1 -C 18亚烷基，C 1 -C 18亚烷基，C 1 -C 10卤代亚烷基，C 2 -C 12亚烯基，C 4 -C 30环亚烯基，亚苯基，亚萘基，亚蒽基，亚菲基，亚联苯基或亚杂芳基。 全部未取代或取代; R4是例如C 3 -C 30环烷基，C 3 -C 30环烷基-C 1 -C 18烷基，C 1 -C 18烷基，C 1 -C 10卤代烷基，C 2 -C 12链烯基，C 4 -C 30环烯基，苯基-C 1 -C 3烷基; R 12和R 13例如为C 3 -C 30环烷基，C 3 -C 30环烷基-C 1 -C 18烷基，C 1 -C 18烷基，C 1 -C 10卤代烷基，C 2 -C 12烯基，C 4 -C 30环烯基，苯基-C 1 -C 3烷基，Ar，（CO）R 15 CO）OR15或SO2R15; 并且Ar是苯基，联苯基，芴基，萘基，蒽基，菲基或杂芳基，全部是未取代或取代的。

公开(公告)号：WO2010046240A1

公开(公告)日：2010-04-29

申请号：PCT/EP2009/063095

申请日：2009-10-08

Applicant: BASF SE ,  YAMATO, Hitoshi ,  ASAKURA, Toshikage ,  NISHIMAE, Yuichi

Inventor： YAMATO, Hitoshi ,  ASAKURA, Toshikage ,  NISHIMAE, Yuichi

IPC: C07C381/12 ,  G03F7/00

CPC classification number: C07C381/12 ,  C07C317/04 ,  G03F7/0007 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/038 ,  G03F7/0382 ,  G03F7/0392 ,  Y10S430/122 ,  Y10S430/123 ,  Y10S430/124 ,  Y10S430/125 ,  Y10S430/126

Abstract: Compounds of the formula (I), wherein Ar 1 is for example phenylene or biphenylene both unsubstituted or substituted; Ar 2 and Ar 3 are for example independently of each other phenyl, naphthyl, biphenylylyl or heteroaryl, all optionally substituted; or Ar 1 and Ar 2 for example together with a direct bond, O, S or (CO), form a fused ring system; R is for example hydrogen, C 3 -C 30 cycloalkyl or C 1 -C 18 alkyl; and R 1 , R 2 and R 3 independently of each other are for example C 1 -C 10 haloalkyl; are effective photoacid generators (PAG).

Abstract translation: 式（I）的化合物，其中Ar1为未取代或取代的亚苯基或亚联苯; Ar2和Ar3例如彼此独立地为苯基，萘基，联苯基或杂芳基，全部为取代基; 或Ar1和Ar2与直接键O，S或（CO）一起形成稠环体系; R是例如氢，C 3 -C 30环烷基或C 1 -C 18烷基; 并且R 1，R 2和R 3彼此独立地是例如C 1 -C 10卤代烷基; 是有效的光酸产生剂（PAG）。