Abstract:
The present invention relates to a process for the production of a transition metal containing zeolite comprising expanding a layered silicate with a swelling agent and introducing the transition metal into the interlayer expanded silicate prior to calcination thereof for obtaining the transition metal containing zeolite. The present invention further relates to a zeolite containing transition metal nanoparticles as obtainable or obtained according to the inventive process, as well as to a zeolite containing nanoparticles per se. Finally the present invention relates to the use of a zeolite containing transition metal nanoparticles as obtainable or obtained according to the inventive process, as well as to the use of a zeolite containing nanoparticles per se.
Abstract:
A process for preparing a zeolitic material comprising Ti, having framework type CHA and having a framework structure which comprises Si and O, said process comprising (i) preparing a pre-synthesis mixture comprising water, a CHA framework structure directing agent, and a zeolitic material comprising Ti, having framework type MFI and having a framework structure which comprises Si and O; (ii) removing water from the pre-synthesis mixture obtained from (i) by heating the pre-synthesis mixture to a temperature of less than 100°C at a pressure of less than 1 bar (abs); (iii) hydrothermally crystallizing the zeolitic material comprising Ti, having framework type CHA and having a framework structure which comprises Si and O.
Abstract:
The present invention relates to a process for the preparation of a catalyst for selective catalytic reduction comprising • (i) preparing a mixture comprising a metal-organic framework material comprising an ion of a metal or metalloid selected from groups 2-5, groups 7-9, and groups 11-14 of the Periodic Table of the Elements, and at least one at least monodentate organic compound, a zeolitic material containing a metal as a non-framework element, optionally a solvent system, and optionally a pasting agent, • (ii) calcining of the mixture obtained in (i); and further relates to a catalyst per se comprising a composite material containing an amorphous mesoporous metal and/or metalloid oxide and a zeolitic material, wherein the zeolitic material contains a metal as non-framework element, as well as to the use of said catalyst.
Abstract:
A zeolitic material having framework type CHA, comprising a transition metal M and an alkali metal A, and having a framework structure comprising a tetravalent element Y, a trivalent element X and O, wherein the transition metal M is a transition metal of groups 7 to 12 of the periodic table, A is one or more of K and Cs, Y is one or more of Si, Ge, Ti, Sn and Zr, and X is one or more of Al, B, Ga and In.A process for preparing such a zeolitic material. Use of such a zeolitic material.
Abstract:
The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO 2 and X 2 O 3 , wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO 2 , one or more sources for X 2 O 3 , one or more tetraalkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds, and one or more tetraalkylammonium cation R 5 R 6 R 7 R 8 N + -containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 independently from one another stand for alkyl, and wherein R 8 stands for cycloalkyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
Abstract:
The present invention relates to a process for the oxygen free conversion of methane to ethylene on zeolite catalysts and catalysts comprising a zeolite, a metal and a further component.
Abstract:
Verfahren zur Herstellung eines passivierten Katalysators, der einen Zeolith und mindestens ein aktives Metall enthält, dadurch gekennzeichnet, dass - der Katalysator in einer Wirbelschicht gehalten wird und - in der Wirbelschicht mit einer Siliciumverbindung passiviert wird.
Abstract:
The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a methanol active component and an acid component comprising a zeolitic material being crystallized by means of one or more alkenyltrialkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds as structure directing agent. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for the preparation of dimethyl ether from synthesis gas.
Abstract:
The present invention relates to a method for the preparation of a treated zeolitic material having a BEA framework structure comprising the steps of: (i) providing a zeolitic material having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, and wherein the zeolitic material having a BEA framework structure is obtainable and/or obtained from an organotemplate-free synthetic process; (ii) calcining the zeolitic material provided in step (i) at a temperature of 650°C or more; and (iii) treating the calcined zeolitic material obtained from step (ii) with an aqueous solution having a pH of 5 or less, as well as to zeolitic materials per se preferably obtainable according to the inventive method and to their use, and to a process for converting oxygenates to olefins employing the inventive zeolitic materials.
Abstract translation:本发明涉及一种制备具有BEA骨架结构的经处理的沸石材料的方法,包括以下步骤:(i)提供具有BEA骨架结构的沸石材料,其中BEA骨架结构包含YO 2和X 2 O 3,其中Y 是四价元素,X是三价元素,并且其中具有BEA骨架结构的沸石材料可以从有机无模板合成方法获得和/或获得; (ii)在650℃以上的温度下煅烧步骤(i)中提供的沸石材料; 和(iii)用pH为5以下的水溶液以及根据本发明方法可获得的沸石材料本身及其用途来处理由步骤(ii)获得的煅烧沸石材料及其用途 使用本发明的沸石材料将含氧物转化为烯烃的方法。
Abstract:
The present invention relates to a process for the preparation of a pillared silicate compound comprising a layered silicate structure and bridging silicon atoms located between adjacent silicate layers of the silicate structure, wherein said bridging silicon atoms form at least one covalent bond to each of the adjacent silicate layers, said process comprising (1) providing one or more layered silicates; (2) adding said one or more layered silicates to a solvent system, wherein the resulting mixture has a pH of 5 or less; and (3) subjecting the mixture obtained in step (2) to solvothermal conditions; wherein no silicon-containing compound according to formula (I) R4-mSi[-(SiR2)n-R]m (I) is used at any point of the process up to and including step (3), wherein m is 1, 2, 3, or 4, and n is an integer greater than or equal to 0, wherein when n is equal to 0, one or more residues R are leaving groups, and wherein none of the residues R contains Si, as well as to a pillared silicate compound per se, preferably as obtained and/or obtainable according to the inventive process as well as to the use of the inventive compounds.