公开(公告)号：WO2013188052A1

公开(公告)日：2013-12-19

申请号：PCT/US2013/041567

申请日：2013-05-17

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： LAKROUT, Hamed ,  MARKS, Maurice, J. ,  VALETTE, Ludovic

IPC: C08J3/00 ,  C04B35/524 ,  C04B35/83 ,  C08L63/00

CPC classification number: C04B35/524 ,  C04B35/83 ,  C04B2235/48 ,  C08G59/40 ,  C08G59/68 ,  C08G59/687 ,  C08J3/00

Abstract: A liquid carbon precursor composition including (a) at least one aromatic epoxy resin; and (b)(i) at least one aromatic co-reactive curing agent or (b)(ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; wherein the liquid composition prior to adding optional components and curing, has a neat viscosity of less than 10,000 mPa-s, at 25 °C; and wherein the liquid precursor composition has a neat viscosity of less than 10,000 mPa-s at 25 °C prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid precursor composition being cured has a carbon yield of at least 35 weight percent as measured in the absence of optional components; a cured liquid carbon precursor composition; a carbonized material made from the above liquid carbon precursor composition; and processes for producing the above compositions.

Abstract translation: 一种液体碳前体组合物，其包含（a）至少一种芳族环氧树脂; 和（b）（i）至少一种芳族共反应性固化剂或（b）（ii）至少一种催化固化剂，或（b）（iii）它们的混合物; 其中在添加任选组分和固化之前，液体组合物在25℃时具有小于10,000mPa·s的纯粘度; 并且其中所述液体前体组合物在25℃下具有小于10,000mPa·s的洁净粘度，然后在固化之前和在碳化之前加入任选组分。 并且其中固化的液体前体组合物具有至少35重量％的碳收率，在不存在任选组分的情况下测量; 固化液体碳前体组合物; 由上述液态碳前体组合物制成的碳化材料; 以及制备上述组合物的方法。

公开(公告)号：WO2013048784A1

公开(公告)日：2013-04-04

申请号：PCT/US2012/055483

申请日：2012-09-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  LAUFER, Caroline, H. ,  FU, Lin ,  LIN, Thomas, S. ,  BISHOP, Matthew, T. ,  LAKROUT, Hamed

Inventor： LAUFER, Caroline, H. ,  FU, Lin ,  LIN, Thomas, S. ,  BISHOP, Matthew, T. ,  LAKROUT, Hamed

IPC: C08L23/12 ,  H01B3/44 ,  H01B7/295

CPC classification number: H01B3/441 ,  C08K3/28 ,  C08K3/32 ,  C08K5/5205 ,  C08K5/5399 ,  C08L23/12 ,  C08L2201/02 ,  H01B7/295 ,  C08L23/0815

Abstract: The present disclosure is directed to a halogen-free composition and conductors coated with the halogen-free composition. The halogen-free composition includes (A) from 70 wt % to 85 wt % of a polymeric component and (B) from 30 wt % to 15 wt % of a halogen- free flame retardant. The polymeric component (A) includes (i) a propylene homopolymer or a mini- random copolymer with greater than 40% crystallinity and (ii) an ethylene/a-olefin copolymer. The halogen-free composition has a density less than 1.15 g/cc. The halogen-free composition also has a scrape abrasion resistance of greater than or equal to 350 cycles as measured in accordance with ISO 6722.

Abstract translation: 本公开涉及无卤素组合物和涂覆有无卤素组合物的导体。 无卤素组合物包含（A）70重量％至85重量％的聚合物组分和（B）30重量％至15重量％的无卤阻燃剂。 聚合物组分（A）包括（i）丙烯均聚物或具有大于40％结晶度的微小共聚物和（ii）乙烯/α-烯烃共聚物。 无卤素组合物的密度小于1.15g / cc。 无卤组合物还具有根据ISO 6722测量的大于或等于350个循环的刮擦耐磨性。

公开(公告)号：WO2013188048A1

公开(公告)日：2013-12-19

申请号：PCT/US2013/041558

申请日：2013-05-17

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： LAKROUT, Hamed ,  MARKS, Maurice, J. ,  VALETTE, Ludovic

IPC: C08J3/00 ,  C04B35/524 ,  C04B35/83 ,  C08L63/00

CPC classification number: C09D5/24 ,  B82Y10/00 ,  C03C17/22 ,  C03C2217/28 ,  C04B35/524 ,  C04B35/6269 ,  C04B35/63452 ,  C04B2235/9653 ,  C08J3/00 ,  C08L63/00 ,  H01B1/04 ,  H01B1/24 ,  H01L51/0045 ,  H01L51/442 ,  Y10T428/265

Abstract: A process for preparing a conductive carbonized layered article including the steps of: (I) providing a liquid carbon precursor formulation comprising (a) at least one aromatic epoxy resin; and (b)(i) at least one aromatic co-reactive curing agent, (b)(ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; wherein the liquid precursor composition has a neat viscosity of less than 10,000 mPa-s at 25 °C prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid precursor composition being cured has a carbon yield of at least 35 weight percent disregarding the weight of the substrate and any optional components present in the composition; (II) applying the liquid formulation of step (I) as a thin coating layer onto at least a portion of the surface of a substrate; (III) curing the liquid formulation of step (II) to form a cured product, wherein the cured product has a carbon yield of at least 35 weight percent disregarding the weight of the substrate and any optional components present in the composition; and (IV) carbonizing the cured product of step (III) to form a conductive carbonized layered article; and a conductive carbonized layered article such as a carbon optical transparent electrode (COTE) prepared by the above process.

Abstract translation: 一种制备导电碳化层状制品的方法，包括以下步骤：（I）提供液体碳前体制剂，其包含（a）至少一种芳族环氧树脂; 和（b）（i）至少一种芳族共反应性固化剂，（b）（ii）至少一种催化固化剂，或（b）（iii）它们的混合物; 其中所述液体前体组合物在25℃下具有小于10,000mPa·s的纯粘度，然后在固化之前和在碳化之前加入任选组分。 并且其中固化的液体前体组合物具有至少35重量％的碳收率，而不考虑底物的重量和组合物中存在的任何任选组分; （II）将作为薄涂层的步骤（I）的液体制剂施用到基材表面的至少一部分上; （III）固化步骤（II）的液体制剂以形成固化产物，其中固化产物具有至少35重量％的碳产率，而不考虑基质和组合物中存在的任何任选组分的重量; 和（IV）将步骤（III）的固化产物碳化以形成导电性碳化层压制品; 以及通过上述方法制备的碳光透明电极（COTE）等导电性炭化层叠体。

公开(公告)号：WO2013048754A1

公开(公告)日：2013-04-04

申请号：PCT/US2012/055084

申请日：2012-09-13

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  FU, Lin ,  LAUFER, Caroline, H. ,  LIN, Thomas, S. ,  BISHOP, Matthew, T. ,  LAKROUT, Hamed ,  HARRIS, William, J.

Inventor： FU, Lin ,  LAUFER, Caroline, H. ,  LIN, Thomas, S. ,  BISHOP, Matthew, T. ,  LAKROUT, Hamed ,  HARRIS, William, J.

IPC: C08L69/00 ,  H01B3/42 ,  H01B7/295 ,  C08L23/10 ,  C08K5/521

CPC classification number: H01B3/426 ,  C08K5/521 ,  C08L23/10 ,  C08L51/06 ,  C08L69/00 ,  C08L2201/02 ,  C08L2203/202 ,  C08L2205/03 ,  C08L2205/08 ,  H01B3/421 ,  H01B7/295 ,  Y10T428/2933

Abstract: A composition comprising (A) at least one bisphenol-A polycarbonate resin, (B) at least one polypropylene, preferably a high crystallinity polypropylene, (C) at least one compatibilizer comprising an amine functionalized elastomeric polymer, (D) at least one organic phosphate flame retardant, preferably an organic phosphate that is liquid at room temperature, and, optionally, (E) one or more additives. These compositions are useful in the manufacture of wire insulation coatings of less than 0.2 mm with good scrape abrasion resistance.

Abstract translation: 一种组合物，其包含（A）至少一种双酚A聚碳酸酯树脂，（B）至少一种聚丙烯，优选高结晶度聚丙烯，（C）至少一种增容剂，其包含胺官能化弹性体聚合物，（D）至少一种有机 磷酸盐阻燃剂，优选在室温下为液体的有机磷酸盐，和任选地（E）一种或多种添加剂。 这些组合物可用于制造小于0.2mm的电线绝缘涂层，具有良好的刮擦耐磨性。

公开(公告)号：WO2013188051A1

公开(公告)日：2013-12-19

申请号：PCT/US2013/041564

申请日：2013-05-17

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： LAKROUT, Hamed ,  MARKS, Maurice, J. ,  VALETTE, Ludovic

IPC: C01B31/02 ,  C04B35/524

CPC classification number: C01B31/02 ,  C01B32/05 ,  C04B35/524 ,  C04B35/6269 ,  C04B35/63452 ,  C04B2235/602 ,  C04B2235/6022 ,  C04B2235/6025 ,  C04B2235/6027 ,  C04B2235/6562 ,  C04B2235/658 ,  C04B2235/662 ,  C08G59/687

Abstract: A process for preparing a vitreous carbon including the steps of: (I) providing a curable low viscosity liquid carbon precursor formulation comprising (a) at least one aromatic epoxy resin; and (b)(i) at least one aromatic co-reactive curing agent, (b)(ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; wherein the liquid precursor composition has a neat viscosity of less than 10,000 mPa-s at 25 °C prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid precursor composition being cured has a carbon yield of at least 35 weight percent as measured in the absence of optional components; (II) curing the liquid formulation from step (I) to form a cured product wherein the cured product has a carbon yield of at least 35 weight percent as measured in the absence of optional components; (III) carbonizing the cured product from step (II) to form a carbonized composition; and (IV) purifying the carbonized product from step (III) to form a vitreous carbon composition; and a vitreous carbon prepared by the above process.

Abstract translation: 一种制备玻璃碳的方法，包括以下步骤：（I）提供可固化的低粘度液体碳前体制剂，其包含（a）至少一种芳族环氧树脂; 和（b）（i）至少一种芳族共反应性固化剂，（b）（ii）至少一种催化固化剂，或（b）（iii）它们的混合物; 其中所述液体前体组合物在25℃下具有小于10,000mPa·s的纯粘度，然后在固化之前和在碳化之前加入任选组分。 并且其中固化的液体前体组合物具有至少35重量％的碳收率，在不存在任选组分的情况下测量; （II）固化来自步骤（I）的液体制剂以形成固化产物，其中固化产物的碳收率为至少35重量％，在不存在任选组分的情况下测量; （III）将来自步骤（II）的固化产物碳化以形成碳化组合物; 和（IV）从步骤（III）中纯化碳化产物以形成玻璃碳组合物; 和通过上述方法制备的玻璃碳。

公开(公告)号：WO2013188050A1

公开(公告)日：2013-12-19

申请号：PCT/US2013/041561

申请日：2013-05-17

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： LAKROUT, Hamed ,  MARKS, Maurice, J. ,  VALETTE, Ludovic ,  LATHAM, Dwight, D.

IPC: C01B31/00 ,  C04B35/52 ,  C04B38/00 ,  C08J5/24 ,  C04B35/524

CPC classification number: C01B31/02 ,  C01B32/00 ,  C01B32/05 ,  C04B35/524 ,  C04B35/6269 ,  C04B35/63452 ,  C04B38/0032 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2111/00836 ,  C04B2111/00844 ,  C04B2111/00853 ,  C04B2235/6562 ,  C08J9/122 ,  C08J9/127 ,  C08J9/141 ,  C08J9/143 ,  C08J9/149 ,  C08J9/32 ,  C08J9/36 ,  C08J2203/06 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2203/182 ,  C08J2363/00 ,  F16L59/028 ,  C04B35/52 ,  C04B38/02 ,  C04B38/0615 ,  C04B38/08 ,  C04B38/10

Abstract: A curable liquid carbon precursor formulation for preparing a porous carbon composition including (a) at least one aromatic epoxy resin; (b)(i) at least one aromatic co-reactive curing agent, or (b)(ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; and (c) at least one porogen; wherein the liquid composition has a neat viscosity of less than 10,000 mPa-s, at 25 °C prior to adding porogen, prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid composition being cured has a carbon yield of at least 35 weight percent disregarding the weight of the porogen and any optional components present in the composition; a process for preparing the porous carbon composition from the above formulation including the steps of curing the formulation, and carbonizing the cured product resulting from curing the formulation such that a porous carbon composition is produced; and a porous carbon composition made by the above process.

Abstract translation: 一种用于制备多孔碳组合物的可固化液体碳前体制剂，其包含（a）至少一种芳族环氧树脂; （b）（i）至少一种芳族共反应性固化剂，或（b）（ii）至少一种催化固化剂，或（b）（iii）其混合物; 和（c）至少一种致孔剂; 其中所述液体组合物在添加致孔剂之前，在25℃下，在加入任选组分之前，在固化之前和在碳化之前，其粘度小于10,000mPa·s。 并且其中固化的液体组合物具有至少35重量％的碳产率，而不考虑致孔剂和组合物中存在的任何任选组分的重量; 从上述制剂制备多孔碳组合物的方法，包括固化该制剂的步骤，以及将固化该制剂得到的固化产物碳化，从而制得多孔碳组合物; 和通过上述方法制备的多孔碳组合物。

公开(公告)号：WO2013188049A1

公开(公告)日：2013-12-19

申请号：PCT/US2013/041560

申请日：2013-05-17

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： LAKROUT, Hamed ,  MARKS, Maurice, J. ,  VALETTE, Ludovic

IPC: C01B31/02 ,  C04B35/52 ,  C04B35/83 ,  C08J5/24 ,  F16D69/02

CPC classification number: C01B31/02 ,  C01B32/05 ,  C04B35/521 ,  C04B35/522 ,  C04B35/6269 ,  C04B35/632 ,  C04B35/63452 ,  C04B35/83 ,  C04B2235/5256 ,  C04B2235/612 ,  C04B2235/616 ,  C04B2235/6562 ,  C04B2235/77 ,  C08G59/687 ,  C09K5/14 ,  F16D69/023

Abstract: A process for preparing a carbon-carbon composite including the steps of: (a) providing a curable low viscosity aromatic epoxy resin liquid formulation, wherein the formulation has a neat viscosity of less than 10,000 mPa-s at 25 °C prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the formulation being cured has a carbon yield of at least 35 wt % disregarding the weight of the carbon matrix and any optional components present in the composition; (b) contacting a carbon matrix with the formulation of step (a); (c) curing the contacted carbon matrix of step (b); and (d) carbonizing the cured carbon matrix of step (c) to form a carbon-carbon composite; and a carbon-carbon composite made by the process.

Abstract translation: 一种制备碳 - 碳复合材料的方法，包括以下步骤：（a）提供可固化的低粘度芳族环氧树脂液体制剂，其中所述制剂在25℃下具有小于10,000mPa·s的纯粘度，然后加入任选的 组分，固化前和碳化前; 并且其中固化的制剂具有至少35重量％的碳收率，不考虑碳基质和组合物中存在的任何任选的组分的重量; （b）使碳基质与步骤（a）的制剂接触; （c）固化步骤（b）的接触碳基质; 和（d）将步骤（c）的固化碳基质碳化以形成碳 - 碳复合材料; 和通过该方法制备的碳 - 碳复合材料。