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1.发明申请BUBBLING BED CATALYTIC HYDROPYROLYSIS PROCESS UTILIZING LARGER CATALYST PARTICLES AND SMALLER BIOMASS PARTICLES FEATURING AN ANTI-SLUGGING REACTOR 审中-公开使用催化剂水解微生物催化剂的方法使用较大的催化剂颗粒和小型生物质颗粒特种抗反应剂
公开(公告)号：WO2012145123A1
公开(公告)日：2012-10-26
申请号：PCT/US2012/030386
申请日：2012-03-23
申请人： GAS TECHNOLOGY INSTITUTE , MARKER, Terry, L. , FELIX, Larry, G. , LINCK, Martin, B. , ROBERTS, Michael, J.
CPC分类号： C10G1/06 , B01J8/1809 , B01J8/34 , B01J23/755 , B01J23/882 , B01J2208/00061 , B01J2208/00115 , B01J2208/00548 , B01J2208/0084 , B01J2219/00252 , C10G1/002 , C10G1/086 , C10G1/10 , C10G3/45 , C10G3/46 , C10G3/50 , C10G3/57 , C10G2300/1003 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L2200/0469 , C10L2290/02 , Y02E50/14 , Y02E50/32 , Y02P30/20
摘要： This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.
摘要翻译： 本发明涉及将生物质或其它含氧原料热化学变换成高质量液体烃燃料的方法。 特别地，使用含有流化催化剂颗粒的深层的催化加氢热解反应器来接受显着小于流化床中的催化剂颗粒的生物质或其它含氧原料的颗粒。 反应器具有设置在反应器容器内的插入物或其它结构，其抑制床的压块，从而使催化剂的磨损最小化。 在床内，生物质原料转化为含有烃分子和其他工艺蒸气的气相产物，以及夹带的固体焦炭产物，其在蒸气流已经从蒸汽流的顶部排出之后与蒸气流分离 反应堆。 当产物蒸气流被冷却到环境温度时，产物蒸气流中的相当大比例的烃可作为疏水性烃的液体流回收，其特性与汽油，煤油和柴油燃料的性质一致。 也可以通过每种类型的燃料的选择性冷凝，或通过以后的组合烃液体的蒸馏来获得单独的汽油，煤油和柴油燃料。
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公开(公告)号：WO2016003892A1
公开(公告)日：2016-01-07
申请号：PCT/US2015/038297
申请日：2015-06-29
CPC分类号： C10G1/002 , C01B3/34 , C01B2203/0233 , C01B2203/0405 , C01B2203/043 , C01B2203/062 , C01B2203/1235 , C01B2203/1264 , C01B2203/148 , C10G1/06 , C10G3/42 , C10G3/46 , C10G3/50 , C10G3/52 , C10G2300/1003 , C10K1/32 , Y02P30/20
摘要： Various techniques are disclosed for pretreating municipal solid waste (MSW) and other biomass-containing feedstocks that may be of a poorer quality and consequently more difficult, or even impossible, to convert to higher value liquid products (e.g., transportation fuels) using conventional processes. Such conventional processes may otherwise be satisfactory for the conversion of the biomass portion of the feedstock alone. The pretreatment of biomass-containing feedstocks may generally include steps carried out prior to a hydropyrolysis step and optionally further steps, in order to change one or more characteristics of the feedstock, rendering it more easily upgradable.
摘要翻译： 公开了各种技术用于预处理城市固体废物（MSW）和其他可能具有较差质量的生物质原料，因此更难或甚至不可能使用常规方法转化为更高价值的液体产品（例如运输燃料） 。 否则这种常规方法可能对于单独的原料的生物质部分的转化是令人满意的。 含生物质的原料的预处理通常可以包括在加氢热解步骤之前进行的步骤和任选的进一步的步骤，以改变原料的一种或多种特性，使其更容易升级。
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3.发明申请REMOVAL OF HYDROGEN SULFIDE AS AMMONIUM SULFATE FROM HYDROPYROLYSIS PRODUCT VAPORS 审中-公开从水解产物蒸气中除去硫化氢作为硫酸铵
公开(公告)号：WO2013019558A1
公开(公告)日：2013-02-07
申请号：PCT/US2012/048345
申请日：2012-07-26
申请人： GAS TECHNOLOGY INSTITUTE , MARKER, Terry, L. , FELIX, Larry, G. , LINCK, Martin, B. , ROBERTS, Michael, J.
CPC分类号： C10G1/002 , B01D53/52 , B01D53/75 , B01D2255/705 , B01D2257/304 , C01B3/38 , C01B2203/0233 , C01C1/022 , C01C1/026 , C01C1/247 , C05C3/00 , C10G1/06 , C10G3/50 , C10G2300/1011 , C10G2300/207 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10J2300/0966 , C10K1/004 , C10L1/04 , C10L2200/0469 , Y02E50/32 , Y02E50/343 , Y02P20/145 , Y02P20/52 , Y02P30/20 , Y02W30/47
摘要： A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H 2 , CH 4 , CO, C0 2 , ammonia and hydrogen sulfide.
摘要翻译： 一种用于将生物质加工成烃燃料的系统和方法，其包括在加氢热解反应器中加工生物质，产生烃燃料和工艺蒸汽流，并将工艺蒸汽流冷却至导致含水流的冷凝温度。 将水流送入催化反应器，在其中将其进行氧化，得到含有氨和硫酸铵的产物流。 所得到的冷却产物蒸汽流包括不可冷凝的工艺蒸气，其包含H 2，CH 4，CO，CO 2，氨和硫化氢。
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