公开(公告)号：WO2016079112A1

公开(公告)日：2016-05-26

申请号：PCT/EP2015/076809

申请日：2015-11-17

申请人： HALDOR TOPSØE A/S

发明人： KNUDSEN, Arne ,  MENJON, Ian

IPC分类号： C07C1/20 ,  C10G2/00 ,  C10L1/06 ,  C02F103/36

CPC分类号： C10G2/30 ,  C02F2103/365 ,  C10G2300/4081 ,  C10G2400/02 ,  C10L1/06

摘要： The present application relates to a plant and a hydrocarbon production process comprising the steps of (i) in a conversion step converting at least a feed stream thereby obtaining a conversion effluent stream comprising water, hydrocarbons such as raw gasoline, unreacted and/or partially reacted feed and/or inerts, (ii) In a separator separating the conversion effluent stream into at least a raw gasoline stream, a recycle stream and a process condensate stream comprising water and oxygenates, (iii) mixing the feed stream and the recycle stream upstream the conversion step, and (iv) adding at least part of the process condensate stream to the feed stream and/or the recycle stream and/or the mixed feed-recycle stream from step (iii).

摘要翻译： 本申请涉及植物和烃的生产方法，其包括以下步骤：（i）在转化步骤中，将至少一种进料流转化，从而获得包含水的转化流出物流，未加反应和/或部分反应的原油汽油 进料和/或惰性气体，（ii）在将转化流出物流分离成至少原始汽油流，再循环流和包含水和含氧化合物的工艺冷凝物流的分离器中，（iii）将进料流和再循环流混合在上游 转化步骤，和（iv）将至少一部分工艺冷凝物流加入到进料流和/或再循环流和/或来自步骤（iii）的混合进料 - 再循环料流中。

公开(公告)号：WO2016066813A1

公开(公告)日：2016-05-06

申请号：PCT/EP2015/075276

申请日：2015-10-30

申请人： HALDOR TOPSØE A/S

发明人： KNUDSEN, Arne ,  MENJON, Ian ,  NIELSEN, Jan Due

IPC分类号： C07C1/20 ,  C10G3/00

CPC分类号： C10G3/49 ,  C10G3/42 ,  C10G2300/1011 ,  C10G2300/202 ,  C10G2400/02 ,  C10G2400/04 ,  Y02P30/20

摘要： The invention relates to a processes comprising the steps of: in an evaporator forming a gas phase methanol rich stream from a feed stream; withdrawing a liquid purge stream from the evaporator, said liquid purge stream comprising oxygenates and water; providing the gas phase methanol rich stream to a conversion step; and adding at least part of said liquid purge stream upstream the conversion step.

摘要翻译： 本发明涉及一种方法，包括以下步骤：在蒸发器中形成来自进料流的富甲烷气流; 从蒸发器抽出液体吹扫流，所述液体吹扫流包含含氧化合物和水; 将气相富含甲醇的流提供至转化步骤; 以及在转化步骤上游加入至少部分所述液体清洗流。

公开(公告)号：WO2018007484A1

公开(公告)日：2018-01-11

申请号：PCT/EP2017/066863

申请日：2017-07-06

申请人： HALDOR TOPSØE A/S

发明人： MENTZEL, Uffe Vie ,  MENJON, Ian ,  JOENSEN, Finn ,  AASBERG-PETERSEN, Kim

IPC分类号： C10G3/00 ,  C07C1/20

CPC分类号： C10G3/44 ,  C07C1/20 ,  C10G3/49 ,  C10G2300/4081 ,  C10G2400/02 ,  C10L1/06 ,  Y02P30/20 ,  C07C9/14

摘要： Process for producing a gasoline type reformate from a main feed comprising alcohols and/or ethers such as methanol and/or dimethyl ether, said process comprising the steps of - reacting a reaction feed over a zeolite or zeolite-containing catalyst thereby obtaining a reaction effluent comprising C1 -C10 hydrocarbons, - In a first separation, separating the reaction effluent into an aqueous phase, a first gas phase and a first liquid hydrocarbon phase, - separating the first liquid hydrocarbon phase into at least an incondensable gas phase, one or more intermediate liquid phases and a gasoline product phase, - recycling at least part of the one or more intermediate phases, where the reaction feed comprises the main feed and the at least part of the one or more intermediate phase recycle.

摘要翻译： 由包含醇和/或醚如甲醇和/或二甲醚的主进料生产汽油型重整产物的方法，所述方法包括以下步骤： - 使反应进料经沸石或沸石 从而获得包含C1-C10烃的反应流出物。在第一次分离中，将反应流出物分离成水相，第一气相和第一液态烃相， - 将第一液态烃相至少分离成 不可冷凝气相，一个或多个中间液相和汽油产物相， - 循环至少一部分所述一个或多个中间相，其中所述反应进料包含主进料和所述一个或多个中间相的至少一部分 再循环。

公开(公告)号：WO2016174145A1

公开(公告)日：2016-11-03

申请号：PCT/EP2016/059503

申请日：2016-04-28

申请人： HALDOR TOPSØE A/S

发明人： KNUDSEN, Arne ,  NIELSEN, Jan Due ,  MENJON, Ian

IPC分类号： C10G7/00 ,  C10G45/02 ,  C10G45/58 ,  C10G47/00

CPC分类号： C10G7/00 ,  C10G45/02 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/104 ,  C10G2300/1044

摘要： The present relates to a plant and a process for treating raw gasoline, said process comprising the steps of (1) In a first splitter separating a raw gasoline stream into at least a first light fraction, a first durene rich fraction and a heavy gasoline fraction, and (2) In a second splitter separating the first durene rich fraction into a second light fraction and a second durene rich fraction.

摘要翻译： 本发明涉及一种用于处理原料汽油的设备和方法，所述方法包括以下步骤：（1）将原始汽油流分离成至少第一轻馏分，第一富含富含馏分和重汽油馏分的第一分离器 ，和（2）在将第一富含富烯馏分分离成第二轻馏分和富含第二富含富烯馏分的第二分离器中。

公开(公告)号：WO2018007488A1

公开(公告)日：2018-01-11

申请号：PCT/EP2017/066867

申请日：2017-07-06

申请人： HALDOR TOPSØE A/S

发明人： MENTZEL, Uffe Vie ,  MENJON, Ian ,  JOENSEN, Finn ,  AASBERG-PETERSEN, Kim

IPC分类号： C10G3/00 ,  C07C1/20

CPC分类号： C10G3/44 ,  C01B3/50 ,  C01B2203/0405 ,  C01B2203/044 ,  C01B2203/045 ,  C01B2203/061 ,  C07C1/20 ,  C10G3/42 ,  C10G3/49 ,  C10G2300/4081 ,  C10G2400/30 ,  Y02P20/128 ,  Y02P30/20 ,  C07C15/00

摘要： The present application relates to a process for conversion of methanol to hydrocarbons comprising aromatics (MTA), said process comprising the steps of - reacting a reactor feed comprising methanol over a bifunctional catalyst thereby obtaining a reaction efflu-ent, - separating the reaction effluent into at least an aqueous condensate stream, a liquid hydrocarbon stream and a gas stream, - obtaining a first recycle stream from the gas stream - obtaining a first side stream from the gas stream, - passing the first side stream through at least one hydrogen (H2) removal step thereby obtaining a hydrogen depleted stream, and - mixing the first recycle stream and the hydrogen depleted stream with a first feed stream comprising methanol to obtain the reactor feed.

摘要翻译： 本申请涉及将甲醇转化成包含芳族化合物（MTA）的烃的方法，所述方法包括以下步骤： - 使包含甲醇的反应器进料在双功能催化剂上反应，从而获得反应流出物 - - 将反应流出物分离成至少含水冷凝物流，液态烃流和气流， - 从气流获得第一循环流 - - 从气流获得第一侧流， - 通过第一侧 通过至少一个氢气（H 2）去除步骤，从而获得贫氢气流，以及 - 将第一循环物流和贫氢物流与包含甲醇的第一进料物流混合以获得反应器进料。

公开(公告)号：WO2016116612A1

公开(公告)日：2016-07-28

申请号：PCT/EP2016/051367

申请日：2016-01-22

申请人： HALDOR TOPSØE A/S

发明人： JOENSEN, Finn ,  MENTZEL, Uffe Vie ,  MENJON, Ian

IPC分类号： C10G3/00 ,  C07C1/20

CPC分类号： C07C29/141 ,  B01J29/405 ,  C07C1/20 ,  C07C9/08 ,  C07C9/10 ,  C07C31/04 ,  C07C2529/40 ,  C10G3/42 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G3/54 ,  C10G2300/4081 ,  C10G2300/805 ,  C10G2400/02 ,  Y02P20/52 ,  Y02P30/20

摘要： The present application relates to a process for production of hydrocarbons comprising the steps of - converting a feed stream comprising alcohols, ethers or mixtures hereof over a metal-containing zeolite based catalyst, active in dehydrogenation of hydrocarbons, in a conversion step thereby obtaining a conversion effluent, - separating said effluent to obtain an aqueous process condensate stream, a liquid hydrocarbon stream and a gaseous stream, - removing part of the hydrogen formed in the conversion step, and recycling at least part of the gaseous and/or liquid hydro- carbon stream to the conversion step.

摘要翻译： 本申请涉及一种生产烃的方法，包括以下步骤：在转化步骤中将包含醇，醚或其混合物的进料流转化为在烃的脱氢中活化的含金属的沸石基催化剂，从而获得转化率 流出物， - 分离所述流出物以获得水性工艺冷凝物流，液态烃流和气态物流， - 去除在转化步骤中形成的部分氢气，并再循环至少部分气态和/或液态碳氢化合物 流转换步骤。

公开(公告)号：WO2021204621A1

公开(公告)日：2021-10-14

申请号：PCT/EP2021/058423

申请日：2021-03-31

申请人： HALDOR TOPSØE A/S

发明人： HIDALGO VIVAS, Angelica ,  RASMUSSEN, Henrik Wolthers ,  MENJON, Ian ,  ALKILDE, Ole Frej ,  KNUDSEN, Arne

IPC分类号： C10G3/00 ,  C10G45/64 ,  C10G47/02 ,  C10G65/14

摘要： The present disclosure relates to a production plant and a method for production of a synthetized gasoline product from a synthetic hydrocarbon mixture produced from a mixture of reactive oxygenates comprising the steps ofa. separating the synthetic hydrocarbon mixture in at least a light hydrocarbon frac-tion, and a higher boiling hydrocarbon fraction, wherein the higher boiling fraction comprises at least 70% of the molecules comprising 10 or more carbon atoms pre-sent in the hydrocarbon mixture and less than 20% of the molecules comprising ex-actly 9 carbon atoms present in the synthetic hydrocarbon mixture,b. directing at least an amount of said higher boiling hydrocarbon fraction as a hy-drocracking feedstock to contact a material catalytically active in hydrocracking un-der effective hydrocracking conditions providing a hydrocracked hydrocarbon stream,wherein at least an amount of said hydrocracked hydrocarbon stream, optionally after further hydroprocessing, is combined with at least an amount of said light hydrocarbon fraction, to provide said synthetized gasoline product having a T90 according to ASTM D86 being below T90 according to ASTM D86 of said synthetic hydrocarbon mixture, such as 10°C or 20°C below, with the associated benefit of such a process reducing the upper boiling point of the synthetized gasoline product, by hydrocracking C10 and C11 hydrocarbons, especially two-ring aromatics, while minimizing the yield loss of gasoline product.

公开(公告)号：WO2018007487A1

公开(公告)日：2018-01-11

申请号：PCT/EP2017/066866

申请日：2017-07-06

申请人： HALDOR TOPSØE A/S

发明人： MENTZEL, Uffe Vie ,  MENJON, Ian ,  JOENSEN, Finn ,  AASBERG-PETERSEN, Kim

IPC分类号： C10G3/00 ,  C07C1/20 ,  C07C15/02

CPC分类号： C10G3/49 ,  C07C1/20 ,  C07C7/005 ,  C07C7/04 ,  C07C7/09 ,  C07C2529/40 ,  C10G2400/30 ,  Y02P20/582 ,  Y02P30/20 ,  C07C15/04

摘要： Process for producing an aromatic rich hydrocarbon product from a main feed comprising methanol and/or DME, said process comprising the steps of - reacting a reaction feed over a bifunctional catalyst thereby obtaining a reaction effluent comprising aromatics, - In a first separation, separating the reaction effluent into an aqueous phase, a first gas phase and a liquid hydrocarbon phase, - separating the liquid hydrocarbon phase into at least an incondensable gas phase, one or more intermediate phases and an aromatic product phase, - recycling at least part of the one or more intermediate phases, and wherein - the reaction feed comprises the main feed and the intermediate phase recycle.

摘要翻译： 由包含甲醇和/或DME的主进料生产富含芳烃的烃产物的方法，所述方法包括以下步骤： - 使反应进料在双功能催化剂上反应，从而获得包含芳族化合物的反应流出物， - 在第一次分离中，将反应流出物分离成水相，第一气相和液态烃相， - 将液态烃相分离成至少不可冷凝的气相，一个或多个中间相和芳族产物相， - 循环至少部分所述一个或多个中间相，并且其中 - 所述反应进料包括所述主进料和所述中间相循环。

公开(公告)号：WO2016116611A1

公开(公告)日：2016-07-28

申请号：PCT/EP2016/051366

申请日：2016-01-22

申请人： HALDOR TOPSØE A/S

发明人： JOENSEN, Finn ,  MENTZEL, Uffe Vie ,  MENJON, Ian

IPC分类号： C10G3/00 ,  C07C1/20

CPC分类号： C07C29/141 ,  B01J29/405 ,  C07C1/20 ,  C07C9/08 ,  C07C9/10 ,  C07C31/04 ,  C07C2529/40 ,  C10G3/42 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G3/54 ,  C10G2300/4081 ,  C10G2300/805 ,  C10G2400/02 ,  Y02P20/52 ,  Y02P30/20

摘要： The present application relates to a process for production of hydrocarbons comprising the steps of - converting a feed stream comprising alcohols, ethers or mixtures hereof over a metal-containing zeolite based catalyst, active in dehydrogenation of hydrocarbons, in a conversion step thereby obtaining a conversion effluent, - separating said effluent to obtain an aqueous process condensate stream, a liquid hydrocarbon stream and a gaseous stream, - removing part of the hydrogen formed in the conversion step, and recycling at least part of the gaseous and/or liquid hydrocarbon stream to the conversion step.

摘要翻译： 本申请涉及一种生产烃的方法，包括以下步骤：在转化步骤中，将包含醇，醚或其混合物的进料流转化为在烃的脱氢中活化的含金属的沸石基催化剂，从而获得转化率 流出物， - 分离所述流出物以获得水性工艺冷凝物流，液态烃流和气态物流， - 去除在转化步骤中形成的部分氢，并将至少部分气态和/或液态烃流再循环至 转换步骤。

公开(公告)号：WO2015169940A2

公开(公告)日：2015-11-12

申请号：PCT/EP2015/060159

申请日：2015-05-08

申请人： HALDOR TOPSØE A/S

发明人： WEINEISEN, Henrik Franz ,  MENJON, Ian ,  BRODAHL OLLING, Casper ,  LUNDSTED POULSEN, Jonas ,  JENSEN, Kresten, Juul, Nikolaj ,  ROSTRUP-NIELSEN, Thomas

IPC分类号： H01M8/06

CPC分类号： H01M8/0625 ,  H01M8/04037 ,  H01M8/04052 ,  H01M8/04067 ,  H01M8/04268 ,  H01M8/2425 ,  H01M8/2475 ,  H01M8/249

摘要： A core unit in the shape of an integrated module for fuel cell based power generation consists of (1) an inlet or more inlets for fuel cell suitable fuels, said fuels comprising hydrogen, hydrocarbon-based fuels, steam reformed fuels (such as hydrocarbons, alcohols and ethers) and ammonia, (2) one or more inlets for air, (3) one or more off-gas outlets, (4) heat exchangers, and (5) a fuel cell assembly, all mounted in an insulated housing or in several separate insulated housings connected by relevant piping. The unit is an SOFC sub-system, preferably in the 1.5 kW (DC) power range, designed to provide a simple interface to natural gas based SOFC technology. The system features tight integration of the SOFC stack(s) or stack module(s) and all hot balance of plant components. Since the system is designed for anode off-gas recycling, the unit requires no external water supply once in operation. Anode gas recycling results in high overall fuel utilization and in high electrical efficiency.

摘要翻译： 用于基于燃料电池的发电的集成模块形状的核心单元包括（1）用于燃料电池合适燃料的入口或更多入口，所述燃料包括氢气，烃类燃料，蒸汽重整燃料（例如烃， 醇和醚）和氨，（2）用于空气的一个或多个入口，（3）一个或多个废气出口，（4）热交换器和（5）燃料电池组件，其全部安装在绝缘壳体或 在几个单独的绝缘外壳通过相关管道连接。 该单元是SOFC子系统，优选在1.5 kW（DC）功率范围内，旨在为基于天然气的SOFC技术提供简单的接口。 该系统具有SOFC堆栈或堆栈模块的紧密集成以及工厂组件的所有热平衡。 由于系统设计用于阳极废气回收，因此该设备一旦运行就不需要外部供水。 阳极气体循环利用导致燃料利用率高，电效率高。