摘要:
Crystalline molecular sieves and their synthesis using quaternary N-methyl-diisoalkylammonium cations as organic structure directing agents are disclosed. The structure directing agent has the following structure (1): in which R 1 is selected from hydrogen, a methyl group, an ethyl group, a propyl group, and a hydroxymethyl group; and R 2 , R 3 , R 4 and R 5 are independently selected from a methyl group, an ethyl group, and a propyl group.
摘要:
The present disclosure is directed to novel crystalline germanosilicate compositions and methods of producing the same. In particular, the crystalline germanosilicate compositions are extra-large-pore compositions, designated CIT-13 possessing 10- and 14- membered rings. The disclosure describes methods of preparing these compositions using substituted benzyl- imidazolium organic structure-directing agents (OSDAs). Also disclosed are methods of using these crystalline compositions.
摘要:
A method for forming a catalyst can comprise: heating a Ge-ZSM-5 zeolite powder at a temperature of 400 to 600C; ion-exchanging the heat-treated zeolite powder with an alkali metal and impregnating the heat-treated zeolite powder with noble metal; heating the ion-exchanged, impregnated zeolite powder to a temperature of 250 to 350C; mixing the second heat-treated zeolite powder with a solid silica binder and a colloidal silica binder to form a mixture, wherein if the solid silica has a purity of less than or equal to 66 wt% of silica oxide based on the total weight of the solid silica, then the mixture is free of an extrusion aide and the colloidal silica has a particle size of less than 20 nm as measured along a major axis; forming the mixture into a shaped body; and heating the shaped body to result in the catalyst.
摘要:
The present invention is directed to processes using new crystalline molecular sieve designated SSZ-79 synthesized using 1,8-dimethyl-1,4,8,11-tetraazacyclotetradecane or 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane as a structure directing agent.
摘要:
This invention relates to a process for the aromatization of C 6 to C 12 alkanes, such as hexane, heptane and octane, to aromatics, such as benzene, ethyl benzene, toluene and xylenes, with a germanium-containing zeolite catalyst. The catalyst is a non-acidic aluminum-silicon-germanium zeolite on which a noble metal, such as platinum, has been deposited. The zeolite structure may be of MFI, BEA, MOR, LTL or MTT. The zeolite is made non-acidic by being base-exchanged with an alkali metal or alkaline earth metal, such as cesium, potassium, sodium, rubidium, barium, calcium, magnesium and mixtures thereof, to reduce acidity. The catalyst is sulfur tolerant and may be pretreated with a sulfur compound, i.e., sulfided. The hydrocarbon feed may contain sulfur up to 1000 ppm. The present invention could be applicable to a feedstream which is predominantly parafflnic and/or low in naphthenes. Lowering the hydrogen to hydrocarbon ratio increases conversion and aromatics selectivity.
摘要翻译:本发明涉及将C 6 C 12 C 12 C 12 C 12烷烃如己烷,庚烷和辛烷芳构化成芳族化合物如苯,乙苯,甲苯的方法 和二甲苯,含有锗的沸石催化剂。 催化剂是沉积贵金属如铂的非酸性铝硅锗沸石。 沸石结构可以是MFI,BEA,MOR,LTL或MTT。 沸石通过与碱金属或碱土金属如铯,钾,钠,铷,钡,钙,镁及其混合物进行碱交换而制成非酸性,以降低酸度。 催化剂是耐硫的,并且可以用硫化合物预处理,即硫化。 烃进料可含有高达1000ppm的硫。 本发明可以应用于主要是parafflnic和/或低环烷烃的进料流。 降低氢气与烃的比例会提高转化率和芳烃选择性。
摘要:
The present invention relates to new methods of making crystalline materials, as well as to new crystalline materials obtainable by such methods, and their use in hydrocarbon conversion processes. In one of its aspects, the invention relates to a method for preparing a crystalline molecular sieve. comprising oxides of one or more tetravalent element(s), optionally one or more trivalent element(s), and optionally one or more pentavalent element(s), said method comprising submitting to crystallization conditions one or more sources of said oxides in the presence of at least one organic templating agent R of formula C 1 C 2 R 1 R 2 N + A - (I), in which C 1 and C 2 each independently represent a substituted or unsubstituted cyclohexyl or cyclopentyl group; R 1 and R 2 each independently represent a methyl group, an ethyl group or a propyl group, or R 1 and R 2 together with the nitrogen atom they are connected to form a ring containing 5 or 6 atoms; and A represents hydroxyl, fluorine, chlorine, bromine or iodine.
摘要翻译:本发明涉及制备结晶材料的新方法以及可通过这些方法获得的新结晶材料及其在烃转化方法中的用途。 在其一个方面,本发明涉及一种制备结晶分子筛的方法。 包括一种或多种四价元素的氧化物,任选的一种或多种三价元素,以及任选的一种或多种五价元素,所述方法包括在存在的情况下使所述氧化物的一种或多种来源结晶 的至少一种式C的至少一种有机模板剂R 1 C 1 H 2 O 2 R 2 其中C 1至C 2和C 2各自独立地表示取代或未取代的环己基或环戊基 ; R 1和R 2各自独立地表示甲基,乙基或丙基,或R 1和R 2 与它们连接的氮原子一起形成含有5或6个原子的环; A表示羟基,氟,氯,溴或碘。
摘要:
A process for synthesizing the porous crystalline material ITQ- 12 is disclosed and employs an organic directing agent having the formula: where n is an integer from 1 to 3 and Q" is an anion. The resultant ITQ- 12 is useful in as a catalyst in chemical conversion reactions and as an adsorbent for gas separation.
摘要:
The present invention relates to new methods of making crystalline materials isostructural to ITQ-21, as well as to new crystalline materials obtainable by such methods, and their use in hydrocarbon conversion processes. In one of its aspects, the invention relates to a method of making a crystalline material iso-structural to ITQ-21, the method comprising: (a) providing a synthesis mixture comprising water, at least one source of germanium, at least one source of a tetravalent element X other than germanium, at least one structure directing agent R, optionally at least one source of trivalent element Y and optionally at least one source of fluoride, wherein the structure directing agent R is a compound of formula C 1 C 2 R 1 R 2 N + A - (I), in which C 1 and C 2 each independently represent a substituted or unsubstituted cyclohexyl or cyclopentyl group, R 1 and R 2 each independently represent a methyl group, an ethyl group or a propyl group, or R 1 and R 2 together with the nitrogen atom they are connected to form a ring containing 5 or 6 atoms, and A represents hydroxyl, fluorine, chlorine, bromine or iodine, (b) forming said crystalline material from the synthesis mixture; (c) recovering said crystalline material.
摘要翻译:本发明涉及制造与ITQ-21同构的结晶材料的新方法,以及通过这种方法可获得的新的结晶材料及其在烃转化过程中的用途。 在其一个方面中,本发明涉及制备与ITQ-21异结构的结晶材料的方法,所述方法包括:(a)提供合成混合物,其包含水,至少一种锗源,至少一种来源 的除锗之外的四价元素X,至少一种结构导向剂R,任选的至少一种三价元素Y的源和任选的至少一种氟化物源,其中所述结构导向剂R为式C的化合物, 1 2 R 1 1 R 2 N N + A - - - - - - - - - - - - - - - (I)的化合物,其中C 1和C 2各自独立地表示取代或未取代的环己基或环戊基,R 1和R sup 各自独立地代表甲基,乙基或丙基,或R 1和R 2与它们连接的氮原子一起形成 形成含有5或6个原子的环,并且A表示羟基,氟,氯 (b)由合成混合物形成所述结晶材料; (c)回收所述结晶物质。 p>
摘要:
The present disclosure is related to silica-based Lewis acid catalysts, being essentially devoid of strong Bronsted acid character, and their ability to effect the [4+2] cycloaddition and dehydrative aromatization of dienes and dienophiles containing oxygenated substituents to form substituted benzene products. In some embodiments, the processes comprise contacting biomass-derived substrates with ethylene to form terephthalic acid and its derivatives.