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    ベータ型ゼオライト及びその製造方法
    1.
    发明申请
    ベータ型ゼオライト及びその製造方法 审中-公开
    β型沸石及其生产方法

    公开(公告)号：WO2017094196A1

    公开(公告)日：2017-06-08

    申请号：PCT/JP2015/084210

    申请日：2015-12-04

    申请人： ユニゼオ株式会社 ,  国立大学法人東京大学

    发明人： 伊與木　健太 ,  板橋　慶治 ,  大久保　達也

    IPC分类号： C01B39/48 ,  C01B39/00

    CPC分类号： C01B39/00 ,  C01B39/48

    摘要： 亜鉛を含み、かつ粒子径が小さなベータ型ゼオライトを提供すること。　本発明のベータ型ゼオライトは、ケイ素酸化物及び亜鉛酸化物を含み、走査型電子顕微鏡観察で測定された粒度分布における累積頻度５０％での平均粒子径が、５０ｎｍ以上１００ｎｍ以下である。

    摘要翻译： 为了提供含有锌并且具有小粒径的β型沸石。 本发明的β沸石是由氧化硅和氧化锌的，在用扫描型电子显微镜观察测得的颗粒大小分布的50％累积频率的平均粒径，为50nm或更100nm以下。

    CONTROLLER DEVICE COPROCESSOR ARCHITECTURE
    4.
    发明申请
    CONTROLLER DEVICE COPROCESSOR ARCHITECTURE 审中-公开
    控制器设备协处理器结构

    公开(公告)号：WO2011068614A2

    公开(公告)日：2011-06-09

    申请号：PCT/US2010/055022

    申请日：2010-11-01

    申请人： KULAKOWSKI, Robert

    发明人： KULAKOWSKI, Robert

    IPC分类号： G06F13/16 ,  G06F9/44

    CPC分类号： C07F3/003 ,  A61K31/166 ,  A61K47/6949 ,  B01J20/226 ,  B01J20/28066 ,  B01J20/28076 ,  B82Y5/00 ,  C01B37/00 ,  C01B39/00 ,  Y02C10/08

    摘要： Device controllers are enhanced with application processors or coprocessors and additional input/output interfaces are added to the device. Coprocessors running application code allowing the device to serve as application servers for data stored on the device. Coprocessors include an application processing framework allowing access to device storage and optionally include additional memory busses and additional memory chips to reduce bus contention allowing coprocessors to achieve high throughput rates for inputting or outputting or processing device data. Coprocessors include software to access and process stored data without processing support from the host system interfacing to the device. Access to stored data is managed to prevent simultaneous access corruption when the data is being changed.

    摘要翻译： 设备控制器采用应用处理器或协处理器进行增强，并将额外的输入/输出接口添加到设备中。 运行应用代码的协处理器允许设备充当存储在设备上的数据的应用服务器。 协处理器包括允许访问设备存储器的应用处理框架，并且可选地包括额外的存储器总线和额外的存储器芯片以减少总线争用，从而允许协处理器实现用于输入或输出或处理设备数据的高吞吐率。 协处理器包括访问和处理存储数据的软件，无需主机系统与设备接口的处理支持。 管理对存储数据的访问，以防止数据更改时同时发生访问损坏。

    MESOSTRUCTURED MATERIAL HAVING A HIGH ALUMINIUM CONTENT AND COMPOSED OF SPHERICAL PARTICLES OF SPECIFIC SIZE
    6.
    发明申请
    MESOSTRUCTURED MATERIAL HAVING A HIGH ALUMINIUM CONTENT AND COMPOSED OF SPHERICAL PARTICLES OF SPECIFIC SIZE 审中-公开
    具有高铝含量并由特定尺寸的球形颗粒组成的多晶结构材料

    公开(公告)号：WO2009122023A3

    公开(公告)日：2009-11-26

    申请号：PCT/FR2009000210

    申请日：2009-02-26

    申请人： INST FRANCAIS DU PETROLE ,  CHAUMONNOT ALEXANDRA ,  COUPE AURELIE ,  SANCHEZ CLEMENT ,  BOISSIERE CEDRIC ,  MARTIN MICHEL

    发明人： CHAUMONNOT ALEXANDRA ,  COUPE AURELIE ,  SANCHEZ CLEMENT ,  BOISSIERE CEDRIC ,  MARTIN MICHEL

    IPC分类号： C01B39/00 ,  C01B37/00 ,  C01B39/04

    CPC分类号： C01B39/04 ,  C01B37/00 ,  C01B39/00

    摘要： A mesostructured material is described that is composed of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminium oxide, said matrix having a pore diameter between 1.5 and 30 nm and an aluminium oxide content that represents more than 46% by weight relative to the weight of said matrix, which matrix has amorphous walls of thickness between 1 and 30 nm, said elementary spherical particles having a diameter D greater than 10 µm and less than or equal to 100 µm (10 100). Said mesostructured matrix may also contain silicon oxide. Each of the spherical particles of the mesostructured material may also contain zeolite nanocrystals so as to form a material having a mixed porosity of both mesostructured and zeolitic nature. The preparation of said material is also described.

    摘要翻译： 描述了由至少两个基本球形颗粒组成的介孔结构材料，每个所述颗粒包含基于氧化铝的介孔结构基质，所述基质具有1.5-30nm的孔直径和代表大于46的氧化铝含量 所述基质具有厚度在1和30nm之间的无定形壁，所述基本球形颗粒的直径D大于10μm并且小于或等于100μm（10 100）。 所述介孔结构化基质还可以含有氧化硅。 介孔结构材料的每个球形颗粒还可以含有沸石纳米晶体，从而形成具有介孔结构和沸石性质的混合孔隙率的材料。 还描述了所述材料的制备。

    ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES HAVING AN ORDERED STRUCTURE
    8.
    发明申请
    ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES HAVING AN ORDERED STRUCTURE 审中-公开
    有机无机杂化硅酸盐和具有有序结构的金属硅酸盐

    公开(公告)号：WO2008017513A3

    公开(公告)日：2008-03-27

    申请号：PCT/EP2007007132

    申请日：2007-08-03

    申请人： ENI SPA ,  BELLUSSI GIUSEPPE ,  CARATI ANGELA ,  RIZZO CATERINA ,  DIAZ MORALES URBANO ,  ZANARDI STEFANO ,  PARKER WALLACE O'NEIL ,  MILLINI ROBERTO

    发明人： BELLUSSI GIUSEPPE ,  CARATI ANGELA ,  RIZZO CATERINA ,  DIAZ MORALES URBANO ,  ZANARDI STEFANO ,  PARKER WALLACE O'NEIL ,  MILLINI ROBERTO

    IPC分类号： C01B37/00 ,  C01B33/44 ,  C01B37/02 ,  C09C1/30

    CPC分类号： C09C1/3081 ,  C01B33/44 ,  C01B37/00 ,  C01B39/00 ,  C01B39/02 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/86 ,  C01P2006/17 ,  C07F7/1836

    摘要： The present invention relates to new organic-inorganic hybrid silicates and metal-silicates called ECS, characterized by an X-ray powder diffraction pattern with reflections exclusively at angular values higher than 4.0° of 2T, preferably at angular values higher than 4.7°, and an ordered structure containing structural units having formula (a) wherein R is an organic group: Formula (a) and possibly containing one or more elements T selected from groups III B, IV B, V B and transition metals, with a Si/ (Si + T) molar ratio in said structure higher than 0.3 and lower than or equal to 1, wherein Si is the silicon contained in the structural unit (a). A process is also described, starting from disilanes, for the preparation of these materials, which does not include the use of templates or surfactants. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the field of nanotechnologies.

    摘要翻译： 本发明涉及称为ECS的新型有机 - 无机杂化硅酸盐和金属 - 硅酸盐，其特征在于X射线粉末衍射图案仅在高于4.0°2T的角度值下，优选在高于4.7°的角度值下反射，以及 包含具有式（a）的结构单元的有序结构，其中R为有机基团：式（a）并且可能含有一种或多种选自III B，IV B，VB和过渡金属的元素T，其中Si /（Si + T）摩尔比大于0.3且小于或等于1，其中Si是结构单元（a）中所含的硅。 还描述了一种从二硅烷开始制备这些材料的方法，其不包括使用模板或表面活性剂。 这些材料可用作分子筛，吸附剂，催化领域，电子领域，传感器领域，纳米技术领域。

    STRUCTURE MATERIAL OF THE ZEOLITE TYPE WITH ULTRALARGE PORES AND A LATTICE COMPRISED OF SILICONE AND TITANIUM OXIDES; ITS SYNTHESIS AND UTILIZATION FOR THE SELECTIVE OXIDATION OF ORGANIC PRODUCTS
    9.
    发明申请
    STRUCTURE MATERIAL OF THE ZEOLITE TYPE WITH ULTRALARGE PORES AND A LATTICE COMPRISED OF SILICONE AND TITANIUM OXIDES; ITS SYNTHESIS AND UTILIZATION FOR THE SELECTIVE OXIDATION OF ORGANIC PRODUCTS 审中-公开
    具有超细孔的沸石类型的结构材料和由硅氧烷和氧化钛组成的层压体; 其有机产品的选择性氧化的合成和利用

    公开(公告)号：WO1994029022A1

    公开(公告)日：1994-12-22

    申请号：PCT/ES1994000059

    申请日：1994-06-10

    申请人： CONSEJO SUPERIOR INVESTIGACIONES CIENTIFICAS ,  UNIVERSIDAD POLITECNICA DE VALENCIA ,  CORMA CANOS, Avelino ,  NAVARRO VILLALBA, Mª Teresa ,  PEREZ PARIENTE, Joaquín

    发明人： CONSEJO SUPERIOR INVESTIGACIONES CIENTIFICAS ,  UNIVERSIDAD POLITECNICA DE VALENCIA

    IPC分类号： B01J29/04

    CPC分类号： C01B39/00 ,  B01J29/89 ,  C07D301/12

    摘要： The invention relates to a material comprised of silicotitanates having a crystalline structure similar to MCM-41 zeolites, said material being characterized in that it contains in its lattice atoms of titanium and channels in its porous structure whose average sizes exceed 10 ANGSTROM , making possible its utilization in catalytic reactions wherein are involved large organic molecules, such as the oxidation of olefins to epoxides and glycols, alcohols to cetones, thio-ethers to sulfoxides and sulfones, and phenol to catechol and hydroquinone, and if Al is introduced into the structure it is then possible to prepair bifunctional catalysts "oxidant-acid/base". In order to obtain such product, an aqueous solution is used which contains the ion NR1R2R3R4 as well as another aqueous solution which contains tetramethyl amonium hydroxide and a silica source (e.g. aerosil3). After homogenization, more silica is added, as is the Ti source [e.g. Ti(C2OH5)4]. The resultant gel is heated in an autoclave at a temperature between 80 and 200 DEG C. The obtained gel is activated by roasting between 350 and 800 DEG C. It is used for catalytic oxidation.

    摘要翻译： 本发明涉及由具有类似于MCM-41沸石的结晶结构的硅钛酸盐组成的材料，所述材料的特征在于其在其晶格原子中含有钛和其多孔结构的通道，其平均尺寸超过10 ANGSTROM，使其成为可能 在催化反应中的应用，其中涉及大的有机分子，例如将烯烃氧化成环氧化物和二醇，醇类，酮类，硫代醚类，亚砜类和砜类，以及苯酚类，以及邻苯二酚和对苯二酚。 然后可以制备双功能催化剂“氧化剂 - 酸/碱”。 为了获得这样的产物，使用含有离子NR1R2R3R4 +的水溶液以及含有四甲基氢氧化铵和二氧化硅源（例如aerosil3）的另一种水溶液。 均化后，加入更多的二氧化硅，如Ti源[例如]。 的Ti（C2OH5）4]。 所得凝胶在高压釜中在80至200℃的温度下加热。所得凝胶通过在350和800℃之间的焙烧而活化。用于催化氧化。

    ZINC PHOSPHOROUS OXIDE AND ZINC ARSENIC OXIDE COMPOSITIONS
    10.
    发明申请
    ZINC PHOSPHOROUS OXIDE AND ZINC ARSENIC OXIDE COMPOSITIONS 审中-公开
    ZINC氧化磷和氧化锌氧化物组合物

    公开(公告)号：WO1992020444A1

    公开(公告)日：1992-11-26

    申请号：PCT/US1992003692

    申请日：1992-05-05

    申请人： EXXON RESEARCH AND ENGINEERING COMPANY

    发明人： EXXON RESEARCH AND ENGINEERING COMPANY ,  CORCORAN, Edward, William, Jr. ,  BHALLA-CHAWLA, Meena

    IPC分类号： B01J23/02

    CPC分类号： C01G28/02 ,  B01J23/18 ,  B01J27/1808 ,  B01J29/04 ,  B01J37/10 ,  C01B37/002 ,  C01B39/00 ,  C01B39/54

    摘要： Briefly stated, this present invention passes a new class of microporous zinc phosphorous oxide and zinc arsenic oxide compositions and method of preparation. The novel compositions have an oxide framework containing zinc and an oxide selected from the group consisting of phosphorous oxides, arsenic oxides and mixtures thereof as the sole lattice constituents; specifically the compositions have the formula: [Ma(R4X)b]{[ZnpOq][(TO4-e)(OH)e]yLf}.gH¿2O (I) where M is selected from the group consisting of H, Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, and mixtures thereof; R is selected from the group consisting of H, alky groups having about 1 to about 8 carbon atoms, preferably about 1 to about 4 carbon atoms, and mixtures thereof; X is selected from the group consisting of N, P, As, and mixtures thereof; T is selected from the group consisting of P, As, and mixtures thereof; L is a halogen, and mixtures thereof; a, b, g, q, f are numerical values of from 0 to 200; p and y are numerical values greater than 0 up to about 200; and e is any numerical value from 0 to 4; provided that, when M is K and y is 2, e is not 1/2.