나노금속과 탄소나노소재의 복합체 제조방법
    2.
    发明申请
    나노금속과 탄소나노소재의 복합체 제조방법 审中-公开
    制备纳米金属和碳纳米复合材料的方法

    公开(公告)号:WO2016052890A2

    公开(公告)日:2016-04-07

    申请号:PCT/KR2015/009789

    申请日:2015-09-17

    摘要: 본 발명은, 나노금속과 탄소나노소재의 복합체 제조방법에 있어서, 전도성 탄소나노소재에 관능기를 도입하기 위해 탄소나노소재의 표면을 개질시키는 단계와; 표면 개질된 상기 탄소나노소재에 이소시아네이트계 화합물과 피리미딘계 화합물을 혼합하여 반응시킴에 의해 금속 이온과 반응성이 있는 탄소나노소재 분산액을 형성하는 단계와; 상기 탄소나노소재 분산액에 금속염 전구체, 환원제 및 용매를 첨가하여 나노금속 입자를 제조하는 단계와; 상기 탄소나노소재가 포함된 상기 나노금속 입자를 분리하는 단계를 포함하는 것을 기술적 요지로 한다. 이에 의해 탄소나노소재에 이소시아네이트계 화합물 및 피리미딘계 화합물을 혼합하여 반응시킴에 의해 금속 이온과 반응성이 있는 탄소나노소재를 첨가제로 사용하여 3차원 미만의 저차원 형상을 보이는 나노금속을 얻을 수 있다. 또한, 탄소나노소재와의 복합화가 나노금속을 형성과 동시에 이루어지고, 이소시아네이트계 화합물과 피리미딘계 화합물을 혼합하여 반응시켜 형성된 관능기에 의해 용매 분산성이 확보되어 전도성 잉크 또는 페이스트의 제조가 매우 용이한 효과가 있다.

    摘要翻译: 本发明的主题是制备纳米金属和碳纳米材料的复合体的方法,包括以下步骤:改性碳纳米材料的表面以将官能团引入到导电碳纳米材料中; 通过将表面改性的碳纳米材料与异氰酸酯基化合物和嘧啶类化合物混合并与其反应,形成与金属离子反应的碳纳米材料分散溶液; 通过向碳纳米材料分散液中加入金属盐前体,还原剂和溶剂来制备金属纳米颗粒; 并分离含有碳纳米材料的金属纳米颗粒。 因此,通过将碳纳米材料与异氰酸酯基化合物和嘧啶类化合物混合并使其反应以使用碳纳米材料,可以获得显示小于三维的低维度形状的纳米金属,其中 与金属离子反应,作为添加剂。 此外,由于与纳米金属的形成同时进行与碳纳米材料的复合,因此具有极大地促进导电性墨水或糊料的制备的效果,并且通过混合和反应形成的官能团来确保溶剂分散性 异氰酸酯基化合物和嘧啶类化合物。

    金属錯体量子結晶及びそれを用いる生化学物質の表面増強ラマン散乱(SERS)分析法
    4.
    发明申请
    金属錯体量子結晶及びそれを用いる生化学物質の表面増強ラマン散乱(SERS)分析法 审中-公开
    金属复合量子晶体和表面增强拉曼散射(SERS)使用相同的生物化学物质的分析方法

    公开(公告)号:WO2013065747A1

    公开(公告)日:2013-05-10

    申请号:PCT/JP2012/078188

    申请日:2012-10-31

    摘要: 【課題】表面増強ラマン散乱を利用した生化学物質のSPR及びSERS分析用基板及びそれを用いる分析方法を提供する。 【解決手段】希薄プラズモン金属錯体溶液から金属基板上に析出させた金属錯体量子結晶からなる基板またはその基板上に抗体等の受容体を固定した受容体固相化基板であって、SPR又はSERS分析方法に適用される。それを用い、表面増強ラマン散乱を利用して、分析対象が含む生化学物質の存在または含量を検出すると、金属錯体量子結晶に固相化された抗体等の受容体に、分析対象物が結合され、形成された多数個のホットスポットより、表面増強ラマン散乱スペクトルを利用して生化学物質が検出される。

    摘要翻译: [问题]使用表面增强拉曼散射提供生物化学物质的SPR和SERS分析的基板以及使用其的分析方法。 [解决方案]包含从稀释的等离子体金属络合物溶液沉积在金属基底上的金属络合物量子晶体的底物或具有固定在上述基底上的抗体等受体的受体固相底物,所述底物 适用于SPR或SERS分析方法。 通过使用底物,通过使用表面增强拉曼散射来检测包含在待分析对象中的生化物质的存在或含量。 因此,待分析的对象与已经固定在金属络合物量子晶体上的受体(例如已经固定在金属络合物量子晶体上的抗体)结合,并且通过使用表面增强拉曼散射光谱从这样形成的多个热点检测生化物质 。

    POLYAMIDE COMPOSITIONS WITH IMPROVED THERMO-OXIDATIVE, ANTI-BACTERIAL, LIGHT- OR ENERGY ACTIVE PROPERTIES AND METHOD FOR PRODUCING SAME
    6.
    发明申请
    POLYAMIDE COMPOSITIONS WITH IMPROVED THERMO-OXIDATIVE, ANTI-BACTERIAL, LIGHT- OR ENERGY ACTIVE PROPERTIES AND METHOD FOR PRODUCING SAME 审中-公开
    具有改进的热氧化,抗菌,电灯和电力资产,生产装置的和方法聚酰胺组合物

    公开(公告)号:WO2012066051A3

    公开(公告)日:2012-09-27

    申请号:PCT/EP2011070279

    申请日:2011-11-16

    摘要: The invention discloses stabilized and/or functionalized polyamide compositions containing at least one stabilizing and/or functionalizing metallic salt and organoligand complex compound as a polymer additive. Said compositions contain a complex compound consisting of a combination of a copper salt and a 2-oxazoline derivative. The invention also discloses a method for producing a stabilized polyamide composition in which at least one polyamide and a metallic salt and organoligand complex compound are blended. The invention further discloses nitrato-[2,2'-meta-phenylene-bis-(4,5-dihydro-oxazole)]-argentate, nitrato-bis-(2-heneicosyl-4,5-dihydro-oxazole)-argentate, chloro-[2,2'-para-phenylene-bis-(4,5-dihydro-oxazole)]-cuprate und dichloro-[2,2'-para-phenylene-bis-(4,5-dihydro-oxazole)]-cuprate.

    摘要翻译: 本发明公开了含有至少一种稳定剂和/或官能化的金属盐Organoligand络合物用作聚合物添加剂稳定化和/或官能化的聚酰胺组合物。 它们优选含有铜盐的组合与2-恶唑啉的配位化合物。 对于其中至少一种聚酰胺和金属盐Organoligand络合物偏离本发明公开了混合的稳定的聚酰胺组合物的制备方法。 进一步公开的是硝酸根[2,2'-间 - 亚苯基双(4,5-二氢恶唑)] - 的Argentat,硝酸基 - 双(2-二十一烷基-4,5-二氢 - 恶唑)-argentat, 氯 - [2,2'-对亚苯基 - 双 - (4,5-二氢 - 唑)] - 铜氧化物和二氯[2,2'-对亚苯基 - 双 - (4,5-二氢恶唑) ]铜氧化物。

    METHOD TO PRODUCE NANOPARTICLES OF METAL-OXYGEN SYSTEM OF THE SPECIFIED COMPOSITION BY ELECTRON BEAM EVAPORATION AND CONDENSATION IN VACUUM
    8.
    发明申请
    METHOD TO PRODUCE NANOPARTICLES OF METAL-OXYGEN SYSTEM OF THE SPECIFIED COMPOSITION BY ELECTRON BEAM EVAPORATION AND CONDENSATION IN VACUUM 审中-公开
    通过电子束蒸发和真空蒸发法制备指定组合物的金属氧化物体系的纳米颗粒的方法

    公开(公告)号:WO2010144070A2

    公开(公告)日:2010-12-16

    申请号:PCT/UA2010/000027

    申请日:2010-05-18

    IPC分类号: C01B13/20

    摘要: The invention pertains to synthesis of new nanomaterials in vacuum. A method to produce nanoparticles of metal-oxygen system by electron beam evaporation and condensation in vacuum is proposed, which includes simultaneous heating and evaporation of solid initial material and solid carrier material from at least two separate vessels in the vacuum chamber, mixing of vapour flows of initial material and carrier, deposition of mixed vapour flow on the substrate in the condensation zone with fixing of initial material nanoparticles on the substrate by carrier material which solidifies, and formation of nanoparticle condensate in the carrier, in which the initial material is selected from a group, which includes metals and their alloys (Me), micro- and nanosized porous structure of carrier material on the substrate is created by setting and maintaining substrate temperature in the range of formation of micro- and nanosized porous structure of carrier material and below 0.5 of carrier material melting, temperature, which results in production of condensate of nanoparticles with an open surface in micro- and nanosized porous structure of carrier material, dosed feed of oxygen / oxygen-containing gases, vapours and their mixtures into the vacuum chamber /condensation zone is performed after the process or during the process of condensate deposition on the substrate, chemical composition of initial material nanoparticles fixed in the micro- and nanosized porous structure of carrier material is changed due to physico- chemical interaction of open surface of nanoparticles with oxygen / oxygen- containing gases, vapours and their mixtures, which are fed into the vacuum chamber/ condensation zone, and metal-oxygen nanoparticles of the specified composition are produced. Used as the carrier material fixing the nanoparticles is a solid, soluble in liquid and evaporable in vacuum without decomposition simple or complex inorganic material selected from a group which includes chlorides of sodium, potassium, calcium, magnesium, boron oxide, sodium metaborate and their mixtures. In one of the embodiments of the method, the produced condensate of nanoparticles is subjected to further heat treatment in oxygen / oxygen- containing gases, vapours and their mixtures for modifying the composition, structure and dimensions of nanoparticles, which are located in carrier pores, dissolved in at least one liquid and a heterogeneous (colloid) system of the specified composition, size and structure is produced.

    摘要翻译: 本发明涉及真空中新纳米材料的合成。 提出了一种通过真空中电子束蒸发和冷凝来生产金属 - 氧气体纳米颗粒的方法,其中包括从真空室中的至少两个分开的容器同时加热和蒸发固体初始材料和固体载体材料,混合蒸气流 的初始材料和载体,在冷凝区中在衬底上沉积混合的蒸气流,其中固定初始材料纳米颗粒在载体材料上固化并在载体中形成纳米颗粒冷凝物,其中初始材料选自 包括金属及其合金(Me)的基团,载体材料的微米和纳米多孔结构在基底上通过在衬底的微孔和纳米多孔结构形成范围内设置和维持基板温度而产生,并在下面 0.5载体材料熔化,温度高,从而导致冷凝液生产 在载体材料的微米和纳米多孔结构中具有开放表面的纳米颗粒,在冷凝物沉积过程中或在冷凝沉积过程中进行氧/含氧气体,蒸气及其混合物的配料进料到真空室/冷凝区中 固定在载体材料的微米和纳米多孔结构中的初始材料纳米颗粒的化学组成由于纳米颗粒的开放表面与含氧/含氧气体,蒸汽及其混合物的物理化学相互作用而改变, 进入真空室/冷凝区,制备具有规定组成的金属 - 氧化纳米颗粒。 用作固定纳米颗粒的载体材料是固体,可溶于液体并在真空中可蒸发而不分解简单或复杂的无机材料,其选自钠,钾,钙,镁,氧化硼,偏硼酸钠及其混合物的组合 。 在该方法的一个实施方案中,将所制备的纳米颗粒的缩合物在含氧/含氧气体,蒸气及其混合物中进行进一步的热处理,以改变位于载体孔中的纳米颗粒的组成,结构和尺寸, 溶解在至少一种液体中,并且产生具有特定组成的大小和结构的非均相(胶体)体系。

    PRODUCTION OF SILVER SULFATE GRAINS
    9.
    发明申请
    PRODUCTION OF SILVER SULFATE GRAINS 审中-公开
    生产银硫酸盐颗粒

    公开(公告)号:WO2009126326A1

    公开(公告)日:2009-10-15

    申请号:PCT/US2009/002275

    申请日:2009-04-10

    摘要: An aqueous precipitation process for the preparation of particles comprising primarily silver sulfate, comprising reacting an aqueous soluble silver salt and an aqueous soluble source of inorganic sulfate ion in an agitated precipitation reactor vessel and precipitating particles comprising primarily silver sulfate, wherein the reaction and precipitation are performed in the presence of an aqueous soluble carboxylic acid additive or salt thereof, the amount of additive being a minor molar percentage, relative to the molar amount of silver sulfate precipitated, and effective to result in precipitation of particles comprising primarily silver sulfate having a mean grain-size of less than 70 micrometers.

    摘要翻译: 一种用于制备主要包含硫酸银的颗粒的水性沉淀方法,包括将水溶性银盐和无机硫酸根离子的水溶性来源在搅拌的沉淀反应器容器中反应并沉淀出主要包含硫酸银的颗粒,其中反应和沉淀是 在水溶性羧酸添加剂或其盐存在下进行,相对于沉淀的硫酸银的摩尔量,添加剂的量相对于少量摩尔百分数,并且有效地导致主要包含具有平均值的硫酸银的颗粒的沉淀 粒度小于70微米。