公开(公告)号：WO2018117820A1

公开(公告)日：2018-06-28

申请号：PCT/NL2017/050845

申请日：2017-12-19

申请人： INOVACAT B.V.

发明人： FLETCHER, Raymond Paul

IPC分类号： C07C4/06 ,  C07C11/06 ,  C07C5/22 ,  C07C9/12 ,  C10G11/05

CPC分类号： C07C4/06 ,  C07C5/2702 ,  C07C2529/072 ,  C10G11/05 ,  C10G11/10 ,  C10G2300/1081 ,  C10G2400/20 ,  C07C11/06 ,  C07C9/16

摘要： The invention is directed to a process to prepare propylene from a hydrocarbon feed comprising pentane by contacting the hydrocarbon feed with a heterogeneous cracking catalyst as present in one or more fixed beds thereby obtaining a cracked effluent. The heterogeneous catalyst comprises a matrix component and a molecular sieve comprising framework alumina, framework silica and a framework metal selected from the group of Zn, Fe, Ce, La, Y, Ga and/or Zr. Propylene is isolated from the cracked effluent.

公开(公告)号：WO1993005000A1

公开(公告)日：1993-03-18

申请号：PCT/AU1992000457

申请日：1992-08-28

申请人： THE BROKEN HILL PROPRIETARY COMPANY LIMITED ,  BESSELL, Sandra ,  CHAFFEE, Alan, Loyd

发明人： THE BROKEN HILL PROPRIETARY COMPANY LIMITED

IPC分类号： C07C01/04

CPC分类号： C10G2/332 ,  B01J23/83 ,  B01J29/072 ,  C07C1/0435 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2521/12 ,  C07C2521/16 ,  C07C2523/10 ,  C07C2523/12 ,  C07C2523/34 ,  C07C2523/75 ,  C07C2523/83 ,  C07C2529/072 ,  C10G2/334

摘要： The specification describes a Fischer-Tropsch catalyst which comprises cobalt, scandium and a suitable support. The specification also describes a process for producing hydrocarbons by contacting synthesis gas with the Fischer-Tropsch catalyst. Suitable supports include silica, alumina, silica-alumina and kieselguhr if the product required is a wax or distillate. Alternatively the support may be an acidic molecular sieve material such as a zeolite if gasoline or distillate and gasoline is/are required.

摘要翻译： 该说明书描述了一种费 - 托催化剂，其包括钴，钪和合适的载体。 本说明书还描述了通过使合成气与费 - 托催化剂接触来生产烃的方法。 如果需要的产品是蜡或馏出物，合适的载体包括二氧化硅，氧化铝，二氧化硅 - 氧化铝和硅藻土。 或者，如果需要汽油或馏出物和汽油，则载体可以是酸性分子筛材料，例如沸石。

公开(公告)号：WO2018204025A1

公开(公告)日：2018-11-08

申请号：PCT/US2018/026665

申请日：2018-04-09

申请人： EXXONMOBIL CHEMICAL PATENTS INC.

发明人： BEDARD, Jeremy, W. ,  BAO, Xiaoying ,  IACCINO, Larry, L.

IPC分类号： B01J38/12 ,  B01J23/94 ,  B01J23/96 ,  B01J29/90

CPC分类号： B01J29/46 ,  B01J29/068 ,  B01J29/072 ,  B01J29/44 ,  B01J29/90 ,  B01J37/0009 ,  B01J38/10 ,  B01J38/12 ,  B01J38/42 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C01B39/40 ,  C07C5/373 ,  C07C2529/068 ,  C07C2529/072 ,  C07C2529/44 ,  C07C2529/46 ,  C07C2601/10 ,  C07C13/15

摘要： Disclosed are processes for rejuvenating catalysts comprising at least one Group 10 metal and a microporous crystalline metallosilicate, and hydrocarbon conversion processes including such rejuvenation processes. In an aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from 250°C to 375°C and a pressure of up to 100 bar. In a further aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal, at least one rare earth metal, and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from 250°C to 500°C and a pressure of up to 100 bar.

公开(公告)号：WO2018136218A1

公开(公告)日：2018-07-26

申请号：PCT/US2017/068882

申请日：2017-12-29

申请人： HIGHER COMMITTEE FOR EDUCATION DEVELOPMENT ,  KANSAS STATE UNIVERSITY RESEARCH FOUNDATION

发明人： ALAUDA, Zahraa ,  HOHN, Keith

IPC分类号： C07C1/207 ,  C07C11/08 ,  B01J23/72 ,  C12P7/16 ,  C07C45/52 ,  C07C49/10

CPC分类号： C07C1/22 ,  B01J23/72 ,  B01J29/072 ,  C07C45/52 ,  C07C2529/072 ,  C07C11/08 ,  C07C49/10

摘要： Catalysts and methods are provided for producing high yields of butene. The inventive catalysts are bifunctional catalysts having both hydrogenation and dehydration functionalities. Preferred catalysts generally comprise elemental copper or a copper-containing compound supported on a sodium-modified aluminosilicate zeolite. The catalysts are useful in methods of reacting methyl ethyl ketone and hydrogen to produce high yields of butene. The present invention provides a simplified, renewable route to butene, with a number of practical applications.

公开(公告)号：WO2014159490A1

公开(公告)日：2014-10-02

申请号：PCT/US2014/023905

申请日：2014-03-12

申请人： E. I. DU PONT DE NEMOURS AND COMPANY

发明人： KELKAR, Manish, S. ,  MURPHY, Joseph, E. ,  RITTER, Joachim, C. ,  SENGUPTA, Sourav, Kumar

IPC分类号： C07C1/24 ,  B01J27/188

CPC分类号： C07C1/20 ,  B01J23/002 ,  B01J23/30 ,  B01J23/78 ,  B01J23/8878 ,  B01J23/888 ,  B01J23/8892 ,  B01J27/188 ,  B01J29/072 ,  B01J29/076 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0201 ,  B01J37/035 ,  B01J37/04 ,  B01J37/30 ,  B01J2523/00 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/26 ,  C07C2523/72 ,  C07C2523/86 ,  C07C2523/888 ,  C07C2523/889 ,  C07C2527/188 ,  C07C2529/072 ,  C07C2529/076 ,  C10G3/44 ,  C10G3/50 ,  C10G2300/1014 ,  C07C9/15 ,  B01J2523/17 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/69 ,  B01J2523/72 ,  B01J2523/25 ,  B01J2523/67 ,  B01J2523/48

摘要： A hydrodeoxygenation process for producing a linear alkane from a feedstock comprising a saturated or unsaturated C 10-18 oxygenate that comprises an ester group, carboxylic acid group, carbonyl group and/or alcohoi group is disclosed. The process comprises contacting the feedstock with a catalyst composition comprising a metal catalyst and a heteropolyacid or heteropo!yacid salt, at a temperature between about 240 °C to 280 °C and a hydrogen gas pressure of at least 300 psi. The metal catalyst comprises copper in certain embodiments. By contacting the feedstock with the catalyst composition under these temperature and pressure conditions, the C 10-18 oxygenate is hydrodeoxygenated to a linear alkane that has the same carbon chain length as the C 10-18 oxygenate.

摘要翻译： 公开了用于从包含酯基，羧酸基，羰基和/或醇铝基的饱和或不饱和C 10-18含氧化合物的原料生产线性烷烃的加氢脱氧方法。 该方法包括使原料与包含金属催化剂和杂多酸或杂多酸盐的催化剂组合物在约240℃至280℃之间的温度和至少300psi的氢气压力下接触。 在某些实施方案中，金属催化剂包含铜。 通过在这些温度和压力条件下使原料与催化剂组合物接触，将C10-18含氧化合物加氢脱氧至具有与C10-18含氧化合物相同碳链长度的直链烷烃。

公开(公告)号：WO2012162526A3

公开(公告)日：2013-03-21

申请号：PCT/US2012039383

申请日：2012-05-24

申请人： SILURIA TECHNOLOGIES INC ,  CIZERON JOEL M ,  SCHER ERIK C ,  ZURCHER FABIO R ,  SCHAMMEL WAYNE P ,  NYCE GREG ,  RUMPLECKER ANJA ,  MCCORMICK JAROD ,  ALCID MARIAN ,  GAMORAS JOEL ,  ROSENBURG DANIEL ,  RAS ERIK-JAN

发明人： CIZERON JOEL M ,  SCHER ERIK C ,  ZURCHER FABIO R ,  SCHAMMEL WAYNE P ,  NYCE GREG ,  RUMPLECKER ANJA ,  MCCORMICK JAROD ,  ALCID MARIAN ,  GAMORAS JOEL ,  ROSENBURG DANIEL ,  RAS ERIK-JAN

IPC分类号： B01J23/00 ,  B01J21/02 ,  B01J21/10 ,  B01J23/02 ,  B01J23/10 ,  B01J23/30 ,  B01J23/34 ,  B01J23/38 ,  B01J23/54 ,  B01J23/76 ,  C07C2/84

CPC分类号： C07C2/84 ,  B01J19/0046 ,  B01J21/066 ,  B01J21/08 ,  B01J23/002 ,  B01J23/10 ,  B01J23/34 ,  B01J23/54 ,  B01J23/63 ,  B01J23/76 ,  B01J23/83 ,  B01J23/8892 ,  B01J27/16 ,  B01J35/0006 ,  B01J37/031 ,  B01J37/035 ,  B01J2219/00527 ,  B01J2219/00536 ,  B01J2219/00702 ,  B01J2219/00747 ,  B01J2523/00 ,  C07C2521/10 ,  C07C2521/14 ,  C07C2523/10 ,  C07C2523/18 ,  C07C2523/34 ,  C07C2529/072 ,  C07C2529/076 ,  C07C2529/89 ,  Y02P20/52 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/3725 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/23 ,  B01J2523/11 ,  B01J2523/22 ,  B01J2523/305 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/12 ,  B01J2523/69 ,  C07C11/04

摘要： Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.

摘要翻译： 提供了包含各种掺杂剂的金属氧化物催化剂。 催化剂可用作各种催化反应中的异质催化剂，例如甲烷与C 2烃如乙烷和乙烯的氧化偶联。 还公开了相关的使用和制造方法。

公开(公告)号：WO2018071185A1

公开(公告)日：2018-04-19

申请号：PCT/US2017/053894

申请日：2017-09-28

申请人： EXXONMOBIL CHEMICAL PATENTS INC.

发明人： ELIA, Christine, N. ,  LAI, Wenyih, F. ,  NAIR, Hari ,  CUTLER, Joshua, I. ,  BAI, Chuansheng ,  ROLLMAN, Nicholas, S.

IPC分类号： B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/12 ,  B01J29/14 ,  B01J29/22 ,  B01J29/24 ,  B01J29/26 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J29/80 ,  B01J35/02 ,  B01J35/10 ,  B01J37/20 ,  C07C4/18 ,  B01J29/90 ,  B01J29/08

CPC分类号： B01J37/20 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/12 ,  B01J29/126 ,  B01J29/14 ,  B01J29/146 ,  B01J29/22 ,  B01J29/24 ,  B01J29/26 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/7415 ,  B01J29/7423 ,  B01J29/7438 ,  B01J29/7446 ,  B01J29/7453 ,  B01J29/7461 ,  B01J29/7469 ,  B01J29/7476 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7615 ,  B01J29/7623 ,  B01J29/7638 ,  B01J29/7646 ,  B01J29/7653 ,  B01J29/7661 ,  B01J29/7669 ,  B01J29/7676 ,  B01J29/7684 ,  B01J29/7692 ,  B01J29/7815 ,  B01J29/7823 ,  B01J29/783 ,  B01J29/7838 ,  B01J29/7846 ,  B01J29/7853 ,  B01J29/7861 ,  B01J29/7869 ,  B01J29/7876 ,  B01J29/7884 ,  B01J29/7892 ,  B01J29/80 ,  B01J29/90 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1061 ,  B01J38/12 ,  B01J2029/081 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C07C4/18 ,  C07C6/126 ,  C07C2521/04 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/88 ,  C07C2523/888 ,  C07C2529/072 ,  C07C2529/24 ,  C07C2529/76 ,  Y02P20/52 ,  Y02P20/584 ,  C07C15/08 ,  C07C15/04 ,  C07C15/06

摘要： Disclosed are processes for conversion of a feedstock comprising C 8 + aromatic hydrocarbons to lighter aromatic products in which the feedstock and optionally hydrogen are contacted in the presence of a first and a second catalyst composition under conversion conditions effective to produce said lighter aromatic products comprising benzene, toluene and xylene. In the process, the C 8 + aromatic hydrocarbons are dealkylated to form C 6 -C 7 aromatic hydrocarbon and the C 2 + olefins formed are saturated. The remaining C 8 + aromatic hydrocarbons are transalkylated with the C 6 -C 7 aromatic hydrocarbon. The first and second catalyst compositions each comprise a first or second zeolite respectively, a first metal, and a second metal, and are treated with a source of sulfur and/or a source of steam. The first zeolite is selected from ZSM-5, ZSM-11, ZSM-22, ZSM-23, ZSM-35, ZSM-48, ZSM-57, ZSM-58 or mixtures of two or more thereof. The second zeolite is selected from ZSM-4, ZSM-12, ZSM-20, ZSM-50, zeolite beta, mordenite, faujasite, an MCM-22 family material, MCM-68, and mixtures of two or more thereof. The first metal is at least one group 6 metal; the second metal at least one group 9 or 10 metal.

摘要翻译： 公开了将包含C 8+芳香族烃的原料转化为更轻质的芳族产物的方法，其中原料和任选的氢在第一和第二芳族烃存在下接触 第二催化剂组合物在有效生成包含苯，甲苯和二甲苯的所述较轻芳族产物的转化条件下进行。 在该过程中，C 8+芳族烃脱烷基化形成C≡C7 -C 7芳族烃，并且C≡C2 - 所形成的烯烃饱和。 剩余的C 8+芳族烃用C 6 -C 7芳族烃进行烷基转移。 第一和第二催化剂组合物各自分别包含第一或第二沸石，第一金属和第二金属，并用硫源和/或蒸汽源处理。 第一沸石选自ZSM-5，ZSM-11，ZSM-22，ZSM-23，ZSM-35，ZSM-48，ZSM-57，ZSM-58或其两种或更多种的混合物。 第二沸石选自ZSM-4，ZSM-12，ZSM-20，ZSM-50，沸石β，丝光沸石，八面沸石，MCM-22家族材料，MCM-68及其两种或更多种的混合物。 第一种金属是至少一种第6族金属; 第二种金属至少有一组9或10种金属。

公开(公告)号：WO2018071184A1

公开(公告)日：2018-04-19

申请号：PCT/US2017/053889

申请日：2017-09-28

申请人： EXXONMOBIL CHEMICAL PATENTS INC.

发明人： ELIA, Christine, N. ,  LAI, Wenyih, F. ,  NAIR, Hari ,  CUTLER, Joshua, I. ,  BAI, Chuansheng ,  ROLLMAN, Nicholas, S.

IPC分类号： B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/12 ,  B01J29/14 ,  B01J29/22 ,  B01J29/24 ,  B01J29/26 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J29/80

CPC分类号： B01J37/20 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/26 ,  B01J29/48 ,  B01J29/7669 ,  B01J29/7869 ,  B01J29/80 ,  B01J29/90 ,  B01J35/023 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108 ,  B01J2029/081 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C07C4/18 ,  C07C6/126 ,  C07C2521/04 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/88 ,  C07C2523/888 ,  C07C2529/072 ,  C07C2529/24 ,  C07C2529/76 ,  C10G35/085 ,  C10G35/09 ,  C10G35/095 ,  C10G2300/1096 ,  C10G2400/30 ,  Y02P20/52 ,  Y02P20/584 ,  C07C15/04 ,  C07C15/08 ,  C07C15/06

摘要： Disclosed are processes for conversion of a feedstock comprising Cs+ aromatic hydrocarbons to lighter aromatic products in which the feedstock and optionally hydrogen are contacted in the presence of the catalyst composition under conversion conditions effective to dealkylate and transalkylate said C 8 + aromatic hydrocarbons to produce said lighter aromatic products comprising benzene, toluene and xylene. The catalyst composition comprises a zeolite selected from zeolite beta, ZSM-4, ZSM-5, ZSM-11, ZSM-12, ZSM-20, ZSM-22, ZSM-23, ZSM-35, ZSM-48, ZSM-50, ZSM-57, ZSM-58, MCM-68, faujasite zeolite, mordenite zeolite or a MCM-22 family material, a first metal of group 6 in an amount of 0.001 wt% to 20.0 wt%, and a second metal of group 9 or 10 in an amount of 0.001 wt% to 20.0 wt %, and is treated with a source of sulfur and/or a source of steam.

摘要翻译： 公开了将包含Cs +芳族烃的原料转化为更轻芳烃产物的方法，其中原料和任选的氢在催化剂组合物存在下在有效使所述C脱烷基化和转烷基化的转化条件下 以产生包含苯，甲苯和二甲苯的所述较轻芳族产物。 催化剂组合物包含选自沸石β，ZSM-4，ZSM-5，ZSM-11，ZSM-12，ZSM-20，ZSM-22，ZSM-23，ZSM-35，ZSM-48，ZSM-50 ，ZSM-57，ZSM-58，MCM-68，八面沸石，丝光沸石或MCM-22家族材料，含量为0.001重量％至20.0重量％的第6族第一金属和第二族金属 9或10，其量为0.001重量％至20.0重量％，并用硫源和/或蒸汽源处理。

公开(公告)号：WO2013122797A1

公开(公告)日：2013-08-22

申请号：PCT/US2013024953

申请日：2013-02-06

申请人： CHEVRON USA INC

发明人： KIBBY CHARLES LEONARD ,  SAXTON ROBERT JAMES JR ,  JOTHIMURUGESAN KANDASWAMY ,  DAS TAPAN KUMAR ,  LACHEEN HOWARD STEVEN ,  BARTZ MICAHEL ,  HASS ALFRED

IPC分类号： B01J37/02 ,  B01J23/89 ,  B01J29/06 ,  B01J29/064 ,  B01J29/068 ,  B01J29/072 ,  B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J35/04 ,  C07C1/04 ,  C10G2/00

CPC分类号： B01J29/7669 ,  B01J23/8986 ,  B01J29/061 ,  B01J29/064 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/7469 ,  B01J29/7869 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0203 ,  B01J37/0225 ,  B01J37/0228 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/0248 ,  B01J2229/186 ,  B01J2229/42 ,  B01J2229/60 ,  C07C1/0435 ,  C07C2529/072 ,  C10G2/33 ,  Y10T428/31678

摘要： Disclosed are hybrid synthesis gas conversion catalysts containing at least one Fischer-Tropsch component and at least one acidic component deposited on a monolith catalyst support for use in synthesis gas conversion processes and methods for preparing the catalysts. Also disclosed are synthesis gas conversion processes in which the hybrid synthesis gas conversion catalysts are contacted with synthesis gas to produce a hydrocarbon product containing at least 50 wt % C5+ hydrocarbons. Also disclosed are synthesis gas conversion processes in which at least one layer of Fischer-Tropsch component deposited onto a monolith support is alternated with at least one layer of acidic component in a fixed bed reactor.

摘要翻译： 公开了含有至少一种费 - 托组分和沉积在整体催化剂载体上的至少一种酸性组分的混合合成气转化催化剂，用于合成气转化方法和制备催化剂的方法。 还公开了合成气转化方法，其中混合合成气转化催化剂与合成气体接触以产生含有至少50重量％的C 5+烃的烃产物。 还公开了合成气转化方法，其中沉积在整料载体上的至少一层费 ​​- 托成分与固定床反应器中的至少一层酸性组分交替。

公开(公告)号：WO2009148909A3

公开(公告)日：2010-03-18

申请号：PCT/US2009045404

申请日：2009-05-28

申请人： SYNTROLEUM CORP ,  ABHARI RAMIN ,  TOMLINSON H LYNN ,  ROTH GARY

发明人： ABHARI RAMIN ,  TOMLINSON H LYNN ,  ROTH GARY

IPC分类号： C10G3/00 ,  C10G65/12

CPC分类号： C07C4/06 ,  C07C1/2078 ,  C07C5/22 ,  C07C2523/84 ,  C07C2529/072 ,  C10G3/46 ,  C10G3/50 ,  C10G3/54 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/301 ,  C10G2300/308 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/18 ,  C10L1/06 ,  Y02P30/20

摘要： The present invention generally relates to a method for producing a naphtha product from a renewable feedstock. The method includes hydrotreating the renewable feedstock to produce a hydrotreating unit heavy fraction that includes n-paraffins, and hydrocracking the hydrotreating unit heavy fraction to produce a hydrocracking unit product that includes the naphtha product. The method also includes separating the naphtha fraction and optionally recycling the hydrocracking unit heavy fraction through the hydrocracking unit. The present invention also relates to a biorenewable naphtha product suitable for use as feed stock for steam crackers and catalytic reforming units, and for use as fuel, or fuel blend stock.

摘要翻译： 本发明一般涉及从可再生原料生产石脑油产品的方法。 该方法包括加氢处理可再生原料以产生包含正链烷烃的加氢处理单元重馏分，以及加氢处理单元重馏分加氢裂化以产生包含石脑油产物的加氢裂化装置产品。 该方法还包括分离石脑油馏分并任选地通过加氢裂化装置再循环加氢裂化装置重馏分。 本发明还涉及一种适用于蒸汽裂化器和催化重整单元的原料的生物可再生石脑油产品，并且用作燃料或燃料混合原料。