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公开(公告)号：WO2013077457A2
公开(公告)日：2013-05-30
申请号：PCT/JP2012/080799
申请日：2012-11-21
Applicant: HENKEL JAPAN LTD.
Inventor： ITO, Shoko
IPC: C08G18/63
CPC classification number: C09J175/14 , C08G18/6229 , C08G18/6254 , C08G18/6262 , C09J175/04 , H01L31/0481 , H01L31/049 , Y02E10/50
Abstract: An object of the present invention is to provide a urethane adhesive for solar battery back sheets, which has satisfactory initial adhesion to a film in the production of a solar battery back sheet, satisfactory initial adhesive property after curing and high adhesive property at high temperature, and also has a sufficient hydrolysis resistance over the long term and is excellent in overall balance; a solar battery back sheet which is obtainable by using the adhesive; and a solar battery module. Disclosed is an adhesive for solar battery back sheets, including a urethane resin obtainable by the reaction of an acrylic polyol with an isocyanate compound, wherein the acrylic polyol is obtainable by polymerizing polymerizable monomers, the polymerizable monomers include a monomer having a hydroxyl group and other monomers, the monomer having a hydroxyl group includes a hydroxyalkyl (meth)acrylate, and the other monomers include acrylonitrile and (meth)acrylic ester(s).
Abstract translation: 本发明的目的是提供一种用于太阳能电池背板的聚氨酯粘合剂，其在太阳能电池背板的制造中对膜具有令人满意的初始粘合性，固化后的初始粘合性令人满意 并且在高温下具有高粘合性，并且长期具有足够的耐水解性，并且总体平衡优异; 太阳能电池背板，其可通过使用粘合剂获得; 和太阳能电池模块。 本发明公开了一种太阳能电池背板用粘合剂，其包含通过丙烯酸类多元醇与异氰酸酯化合物的反应获得的聚氨酯树脂，其中丙烯酸类多元醇可通过聚合可聚合单体获得，所述可聚合单体包括具有羟基的单体和其它 单体时，具有羟基的单体包括（甲基）丙烯酸羟烷基酯，其他单体包括丙烯腈和（甲基）丙烯酸酯。
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公开(公告)号：WO2011043345A1
公开(公告)日：2011-04-14
申请号：PCT/JP2010/067470
申请日：2010-10-05
IPC: C08G18/40 , A47C27/14 , C08G101/00
CPC classification number: C08G18/6547 , C08G18/36 , C08G18/4063 , C08G18/4858 , C08G18/6262 , C08G18/7607 , C08G18/7621 , C08G18/7664 , C08G2101/0008 , C08G2101/0083
Abstract: 高分子量ポリオキシアルキレンポリオールを使用してもポリオール含有混合物が低粘度であり、かつ軟質ポリウレタンフォームのバイオマス度を高くしながら、反発弾性率が高くて良好なクッション性を有し、スキン部にセル荒れのない軟質ポリウレタンフォームを製造できるようにする。 有機配位子を有する複合金属シアン化物錯体触媒（ａ１）の存在下で、開始剤にプロピレンオキシド（ｂ１）を開環付加重合させた後、アルカリ金属触媒（ａ２）の存在下でエチレンオキシド（ｂ２）を開環付加重合させて得られる、水酸基価が５～３０ｍｇＫＯＨ／ｇのポリオキシアルキレンポリオール（ポリオール（Ａ１））、および天然油脂由来ポリオール（Ａ２）を含むポリオール（Ａ）と、不飽和結合を有する天然油脂に酸化剤を作用させてエポキシ化して得られるエポキシ化天然油脂（Ｘ）を用いる。
Abstract translation: 可以制备软质聚氨酯泡沫塑料，其具有高的软质聚氨酯泡沫生物质量，同时具有高的回弹弹性模量，因此使用含有低聚碳酸酯的含多元醇的混合物具有良好的缓冲性能，但是皮肤部分没有细胞粗糙度 即使使用高分子量聚氧化烯多元醇也是粘度。 软质聚氨酯泡沫体的制造方法使用通过使用氧化剂对具有不饱和键的天然油进行环氧化而得到的环氧化天然油（X）和多元醇（A），所述多元醇（A）包括：具有羟基值的聚氧化烯多元醇 在具有有机物的复合金属氰化物配位催化剂（a1）的存在下，通过用引发剂对环氧丙烷（b1）进行开环加成聚合而获得的5〜30mg KOH / g（多元醇（A1） 配体，然后在碱金属催化剂（a2）的存在下使环氧乙烷（b2）进行开环加成聚合; 和天然油衍生的多元醇（A2）。
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公开(公告)号：WO2016098288A1
公开(公告)日：2016-06-23
申请号：PCT/JP2015/005865
申请日：2015-11-26
Applicant: HENKEL AG & CO. KGAA
Inventor： KAMAI, Noriyoshi , ITO, Shoko , YAMADA, Yasushi , IKEDA, Hitoshi
IPC: C08G18/62 , C08G18/79 , C08G18/76 , C09J175/14 , C08G18/69 , H01L31/049
CPC classification number: C09J175/14 , B32B7/12 , B32B2457/10 , C08G18/6262 , C08G18/69 , C08G18/73 , C08G18/7642 , C08G18/792 , H01L31/049
Abstract: An object of the present invention is to provide an adhesive for laminated sheets, which is excellent in adhesive strength to a film after curing and long-term hydrolysis resistance at high temperature and high humidity when a laminated sheet is produced, and is also excellent in adhesive property at low temperature. Disclosed is an adhesive for laminated sheets, which comprises a urethane resin obtainable by mixing an acrylic polyol with an isocyanate compound, and also has a chemical structure derived from a diene polymer, wherein the diene polymer has a glass transition temperature of -40°C or lower. The adhesive for laminated sheets is excellent in adhesive strength to a film after curing and long-term hydrolysis resistance at high temperature and high humidity when a laminated sheet is produced, and is also excellent in adhesive property at low temperature.
Abstract translation: 本发明的目的是提供一种层叠片材用粘合剂，其在制造层压片材时，对于固化后的膜的粘合强度优异，在高温高湿下具有长期耐水解性，并且也优异 低温粘合性能。 公开了一种层压片用粘合剂，其包含通过将丙烯酸多元醇与异氰酸酯化合物混合而获得的聚氨酯树脂，并且还具有衍生自二烯聚合物的化学结构，其中所述二烯聚合物的玻璃化转变温度为-40℃ 或更低。 层压片用粘合剂在制造层叠片材时，对于固化后的膜的粘合强度以及高温高湿的长期耐水解性优异，并且在低温下的粘合性也优异。
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公开(公告)号：WO2013180301A1
公开(公告)日：2013-12-05
申请号：PCT/JP2013/065303
申请日：2013-05-28
Applicant: HENKEL JAPAN LTD.
Inventor： YAMADA, Yasushi , KAMAI, Noriyoshi , ITO, Shoko , IKEDA, Hitoshi
IPC: C08G18/62 , B32B7/12 , B32B27/36 , C09J175/04 , H01L31/048 , C08G18/00
CPC classification number: B32B7/12 , B32B27/08 , B32B27/28 , B32B27/308 , B32B27/36 , B32B2255/10 , B32B2255/28 , B32B2307/306 , B32B2457/12 , C08G18/6229 , C08G18/6262 , C08K5/5435 , C09J175/04 , H01L31/049 , Y02E10/50
Abstract: An object of the present invention is to provide an adhesive for laminated sheets, which is excellent in initial adhesion to a plastic film and is also excellent in long-term hydrolysis resistance at high temperature in the production of a laminate using the plastic film; a laminated sheet obtainable by using the adhesive; and an outdoor material obtainable by using the laminated sheet. Disclosed is an adhesive for laminated sheets, said adhesive comprising: a urethane resin obtainable by mixing an acrylic polyol with an isocyanate compound; and a silane compound, wherein the silane compound contains an epoxy based silane compound, and wherein the acrylic polyol is obtainable by polymerizing a polymerizable monomer; the polymerizable monomer contains a monomer having a hydroxyl group and the other monomer; and the other monomer contains acrylonitrile. The adhesive is excellent in initial adhesion to a film and is also excellent in long-term hydrolysis resistance at high temperature. The adhesive for laminated sheets is preferably used for an outdoor material, and is particularly useful as an adhesive for solar battery back-sheets.
Abstract translation: 本发明的目的是提供一种层叠片材用粘合剂，其在与塑料膜的初始粘合性方面优异，并且在使用该塑料膜的层叠体的制造中，在高温下的长期耐水解性也优异。 可通过使用粘合剂获得的层压片; 以及通过使用层压片材可获得的室外材料。 公开了一种用于层压片材的粘合剂，所述粘合剂包括：通过将丙烯酸多元醇与异氰酸酯化合物混合而获得的聚氨酯树脂; 和硅烷化合物，其中所述硅烷化合物含有环氧基硅烷化合物，并且其中所述丙烯酸多元醇可通过聚合可聚合单体获得; 可聚合单体含有具有羟基的单体和其它单体; 而其他单体含有丙烯腈。 该粘合剂在初始粘合性方面优异，并且在高温下长期耐水解性也优异。 用于层叠片的粘合剂优选用于户外材料，并且特别可用作太阳能电池底片的粘合剂。
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5.发明申请PREFORMED STABILIZERS USEFUL FOR THE PRODUCTION OF POLYMER POLYOLS AND POLYMER POLYOLS PRODUCED THEREFROM 审中-公开用于生产聚合物多元醇和聚合物多元醇的预制稳定剂
公开(公告)号：WO2013158471A1
公开(公告)日：2013-10-24
申请号：PCT/US2013/036276
申请日：2013-04-12
Applicant: BAYER MATERIALSCIENCE LLC , ENGLAND, Jiong , ADKINS, Rick, L. , NEAL, Brian, L. , GILL, William, A.
Inventor： ENGLAND, Jiong , ADKINS, Rick, L. , NEAL, Brian, L. , GILL, William, A.
IPC: C08F265/04 , C08F20/10 , C08F2/38 , C08G63/00 , C08G65/00
CPC classification number: C08F2/38 , C08F8/30 , C08F10/00 , C08F14/06 , C08F36/04 , C08F220/18 , C08F222/30 , C08F283/008 , C08F283/06 , C08F290/147 , C08G18/227 , C08G18/3275 , C08G18/4072 , C08G18/4841 , C08G18/6262 , C08G18/638 , C08G18/6688 , C08G18/7621 , C08G18/7671 , C08G18/8108 , C08G2101/0083 , C08L33/066 , C08L33/20 , C08L63/00
Abstract: Preformed stabilizers useful for the production of low viscosity, high solids polymer polyols are produced by free-radical polymerization of: (a) at least one ethylenically unsaturated macromolecule or macromer with (b) at least three different ethylenically unsaturated monomers in the presence of (c) at least one free-radical polymerization initiator, and, optionally, (d) a liquid diluent, and, optionally, (e) a chain transfer agent.
Abstract translation: 用于生产低粘度，高固含量聚合物多元醇的预成型稳定剂是通过以下方式的自由基聚合制备的：（a）至少一种烯键式不饱和大分子或大分子单体与（b）至少三种不同的烯属不饱和单体在（ c）至少一种自由基聚合引发剂，和任选的（d）液体稀释剂，和任选的（e）链转移剂。
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Patent Agency Ranking6.发明申请SUSPENSION SYSTEM FOR AIRCRAFT AUXILIARY POWER UNIT WITH ELASTOMERIC MEMBER 审中-公开具有弹性构件的飞机辅助动力装置悬架系统
公开(公告)号：WO2009054926A3
公开(公告)日：2009-10-22
申请号：PCT/US2008011936
申请日：2008-10-20
Applicant: LORD CORP , OLSEN KIRK W , KRAKOWSKI FRANK J
Inventor： OLSEN KIRK W , KRAKOWSKI FRANK J
CPC classification number: B64D27/26 , B23P11/00 , B64D41/00 , B64D2041/002 , C08G18/6262 , C08G18/718 , C08G18/73 , C08G18/7671 , C09D175/04 , F16F1/3835 , Y02T50/44 , Y10T29/49885 , Y10T29/49982
Abstract: The present invention broadly comprises an aircraft motion control auxiliary- power unit suspension system device, the aircraft motion control auxiliary power unit suspension system device comprising a first motion control nonelastomeric member (36) and a second motion control nonelastomeric member (38), a first motion control elastomer member (40) disposed to operatively interconnect the first motion control nonelastomeric member and the second motion control nonelastomeric member. The first motion control elastomer member includes an exterior surface coating formed from an elastomeric polymer dissolved in an organic solvent and the elastomeric polymer dissolved in the solvent is applied to an exterior surface of the first motion control elastomer member, the solvent evaporates, and the elastomeric polymer crosslinks.
Abstract translation: 本发明广泛地包括飞机运动控制辅助动力单元悬挂系统装置，飞行器运动控制辅助动力单元悬架系统装置包括第一运动控制非弹性构件（36）和第二运动控制非弹性构件（38），第一运动控制非弹性构件 运动控制弹性体构件（40）设置成可操作地互连第一运动控制非弹性构件和第二运动控制非弹性构件。 第一运动控制弹性体构件包括由溶解在有机溶剂中的弹性体聚合物形成的外表面涂层，并且溶解在溶剂中的弹性体聚合物施加到第一运动控制弹性体构件的外表面，溶剂蒸发，并且弹性体 聚合物交联。
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公开(公告)号：WO2015038827A1
公开(公告)日：2015-03-19
申请号：PCT/US2014/055264
申请日：2014-09-11
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： COOKSON, Paul, A. , AMICI-KROUTILOVA, Irena , LORA LAMIA, Alberto , CASATI, Francois
CPC classification number: C08J9/0061 , C08G18/0876 , C08G18/14 , C08G18/165 , C08G18/1808 , C08G18/222 , C08G18/244 , C08G18/3281 , C08G18/409 , C08G18/4829 , C08G18/6262 , C08G18/7621 , C08G18/7806 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08J9/0004 , C08J9/145 , C08J2375/04 , C08J2475/04 , C08K5/0066 , C08L75/04
Abstract: A process for forming a conventional flexible polyurethane foam includes providing a polyol component including a PIPA polyol that is a dispersion having a solids content from 10% to 75 wt%, based on a total weight of the PIPA polyol, providing an isocyanate component that includes at least one polyisocyanate, providing an additive component that includes a catalyst, and forming a reaction mixture including the polyol component, the isocyanate component, and the additive component to form a flexible polyurethane foam with a resiliency value below 45%. The reaction mixture has an isocyanate index from 90 to 150. The PIPA polyol is a reaction product of a mixture including at least a low equivalent weight polyol having a number average hydroxyl equivalent weight of less than 80, a polyisocyanate compound having a number average isocyanate equivalent weight that is less than 225, and a liquid base poly ether polyol having a number average hydroxyl equivalent weight from 200 to 1500 and at least 80 % of secondary hydroxyl groups based on a total amount of hydroxyl groups in the liquid base polyether polyol.
Abstract translation: 用于形成常规柔性聚氨酯泡沫的方法包括提供包含PIPA多元醇的多元醇组分，所述PIPA多元醇是基于PIPA多元醇总重量的固体含量为10％至75重量％的分散体，提供包含 至少一种多异氰酸酯，提供包括催化剂的添加剂组分，以及形成包含多元醇组分，异氰酸酯组分和添加剂组分的反应混合物以形成弹性值低于45％的柔性聚氨酯泡沫。 该反应混合物的异氰酸酯指数为90至150.PIPA多元醇是包含至少数均羟值当量小于80的低当量多元醇的混合物的反应产物，具有数均异氰酸酯的多异氰酸酯化合物 小于225的当量，以及基于液体基聚醚多元醇中的羟基总量的数均羟基当量为200至1500和至少80％仲羟基的液体基醚多元醇。
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公开(公告)号：WO2013161972A1
公开(公告)日：2013-10-31
申请号：PCT/JP2013/062304
申请日：2013-04-19
Applicant: HENKEL AG & CO. KGAA
Inventor： YAMADA, Yasushi , KAMAI, Noriyoshi , ITO, Shoko , MATSUKI, Yuichi
IPC: C08G18/62 , B32B7/12 , B32B27/36 , C08G18/72 , C09J175/04 , H01L31/048
CPC classification number: C09J175/12 , B32B7/12 , B32B15/04 , B32B27/08 , B32B27/32 , B32B27/36 , B32B2250/02 , B32B2250/24 , B32B2255/06 , B32B2255/10 , B32B2255/205 , B32B2255/26 , B32B2307/712 , B32B2323/00 , B32B2367/00 , B32B2457/12 , B32B2571/00 , C08F220/18 , C08F2220/1825 , C08G18/6229 , C08G18/6262 , C08G18/724 , C09J133/08 , C09J133/12 , C09J175/04 , H01L31/048 , H01L31/049 , Y02E10/50 , Y10T428/31565 , Y10T428/31605
Abstract: An object of the present invention is to provide an adhesive for laminated sheets, which is excellent in curing rate and initial adhesion to a film after aging in producing a laminated sheet, and is also excellent in hydrolysis resistance over a long term at high temperature. Disclosed is an adhesive for laminated sheets, comprising a urethane resin obtainable by mixing an acrylic polyol with an isocyanate compound, wherein the acrylic polyol is a polyol having a glass transition temperature of from -20 to 20°C, which polyol is obtainable by polymerizing a polymerizable monomer; the polymerizable monomer includes a monomer having a hydroxyl group and the other monomer, and the other monomer includes acrylonitrile; and the isocyanate compound includes both an isocyanate compound having no aromatic ring and an isocyanate compound having an aromatic ring. The adhesive is excellent in initial adhesion to a film after aging, and in its curing rate in the case of producing a laminated sheet, and is also excellent in hydrolysis resistance over a long term at high temperature.
Abstract translation: 本发明的目的是提供一种层合片材用粘合剂，其在制备层压片材时的老化后的固化速度和初始粘合性优异，并且在高温下长期耐水解性也优异。 公开了一种层压片用粘合剂，其包含通过将丙烯酸类多元醇与异氰酸酯化合物混合而获得的聚氨酯树脂，其中所述丙烯酸多元醇为玻璃化转变温度为-20〜20℃的多元醇，所述多元醇可通过聚合 可聚合单体; 可聚合单体包括具有羟基的单体和其它单体，其它单体包括丙烯腈; 并且异氰酸酯化合物包括无芳环的异氰酸酯化合物和具有芳环的异氰酸酯化合物。 粘合剂在老化后的初始粘合性优异，并且在制造层压片材时的固化速度优异，并且在高温下长期耐水解性也优异。
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公开(公告)号：WO2013077457A3
公开(公告)日：2013-08-15
申请号：PCT/JP2012080799
申请日：2012-11-21
Applicant: HENKEL JAPAN LTD
Inventor： ITO SHOKO
IPC: C08G18/62 , C09J175/04 , H01L31/048
CPC classification number: C09J175/14 , C08G18/6229 , C08G18/6254 , C08G18/6262 , C09J175/04 , H01L31/0481 , H01L31/049 , Y02E10/50
Abstract: An object of the present invention is to provide a urethane adhesive for solar battery back sheets, which has satisfactory initial adhesion to a film in the production of a solar battery back sheet, satisfactory initial adhesive property after curing and high adhesive property at high temperature, and also has a sufficient hydrolysis resistance over the long term and is excellent in overall balance; a solar battery back sheet which is obtainable by using the adhesive; and a solar battery module. Disclosed is an adhesive for solar battery back sheets, including a urethane resin obtainable by the reaction of an acrylic polyol with an isocyanate compound, wherein the acrylic polyol is obtainable by polymerizing polymerizable monomers, the polymerizable monomers include a monomer having a hydroxyl group and other monomers, the monomer having a hydroxyl group includes a hydroxyalkyl (meth)acrylate, and the other monomers include acrylonitrile and (meth)acrylic ester(s).
Abstract translation: 本发明的目的是提供一种用于太阳能电池背板的太阳能电池背板的聚氨酯粘合剂，其具有令人满意的初始粘合性，在太阳能电池背板的制造中具有令人满意的初始粘合性和高温下的高粘合性， 并且长期具有足够的耐水解性，总体平衡优异; 可通过使用粘合剂获得的太阳能电池背板; 和太阳能电池模块。 公开了一种用于太阳能电池背板的粘合剂，其包括通过丙烯酸多元醇与异氰酸酯化合物反应获得的聚氨酯树脂，其中丙烯酸多元醇可通过聚合可聚合单体获得，可聚合单体包括具有羟基的单体和其它 单体，具有羟基的单体包括（甲基）丙烯酸羟烷基酯，其它单体包括丙烯腈和（甲基）丙烯酸酯。
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公开(公告)号：WO2010038643A1
公开(公告)日：2010-04-08
申请号：PCT/JP2009/066481
申请日：2009-09-24
IPC: C09D175/04 , B32B27/30 , C09D5/00 , C09D7/12 , C09D125/04 , C09D133/02 , C09D133/08 , C09D133/10 , C09D133/12 , C09D133/14 , C09D133/20 , C09D201/04 , C09D201/06 , C09D201/08
CPC classification number: C09D5/002 , C08G18/0823 , C08G18/6254 , C08G18/6262 , C08G18/755 , C08G18/7642 , C08G18/8025 , C08K5/205 , C08L33/12 , C08L33/20 , C09D133/066 , C09D133/14 , C09D175/04 , C09J133/066 , Y10T428/31591 , Y10T428/31605 , C08K5/0025
Abstract: 包装材の基材層と、印刷インキ層、コーティング剤層乃至接着剤層との密着性の向上を図り、以って、印刷インキの転移性やドット再現性に優れる印刷適性と易接着性、高湿度下での長期保存性、耐酸性を兼ね備える包装用積層体を得るためのプライマー及び、該プライマー層を有する積層体を提供する。該プライマーは、（ａ）水酸基を有する不飽和化合物と、（ｂ）不飽和カルボン酸エステル、スチレン、不飽和カルボン酸、不飽和炭化水素、ビニルエステル及びハロゲン化ビニルからなる群のうち１つ以上の不飽和化合物とを単量体とする共重合体からなる主剤（Ａ）と、イソシアネート基を有する化合物からなる硬化剤（Ｂ）と、１分子中にカルボン酸基を２個以上または無水カルボン酸基を１個以上有する化合物（Ｃ）を含有することを特徴とする。
Abstract translation: 提供底漆和包含由底漆形成的层的层压体。 该底漆改善了包装材料的基层与印刷油墨层，涂层或粘合剂层之间的紧密粘合性，因此用于制造包装的层压材料，其结合了包括优异的印刷油墨转印和优异再现性的可印刷性 点状，易粘合，高湿度下的长期保存性和耐酸性。 底漆的特征在于含有（A）由单体（a）和（b）制备的共聚物组成的主要组分，所述单体（a）是具有羟基的不饱和化合物，所述单体（b）为至少一种 选自不饱和羧酸酯，苯乙烯，不饱和羧酸，不饱和烃，乙烯基酯和卤乙烯的不饱和化合物，（B）由具有异氰酸酯基的化合物组成的固化剂，和（C）化合物 在一个分子中具有两个或多个羧基或一个或多个羧酸酐基团。
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