公开(公告)号：WO2014014472A1

公开(公告)日：2014-01-23

申请号：PCT/US2012/047511

申请日：2012-07-20

Applicant: BRIZIUS, Glen Leon ,  EMPIRE TECHNOLOGY DEVELOPMENT LLC

Inventor： BRIZIUS, Glen Leon

IPC: C09J103/10

CPC classification number: C09J197/005 ,  C09J103/04

Abstract: Disclosed are compositions and methods directed to environmentally friendly, starch-based adhesives with improved properties and adhesive additives which improve the properties of existing starch-based adhesives. Some embodiments are directed to compositions comprising: a starchbased cross-linked phenolic heteropolymer; a plurality of antimicrobial agents covalently bound to the starch-based cross-linked phenolic heteropolymer; and a plurality of sugar units covalently bound to the starch-based cross-linked phenolic heteropolymer. Some embodiments are directed to modified starch-based adhesives comprising: a starch-based adhesive and an additive, the additive consisting of a starch-based composition comprising a starch-based cross-linked phenolic heteropolymer; a plurality of antimicrobial agents covalently bound to the starch-based cross-linked phenolic heteropolymer; and a plurality of sugar units covalently bound to the starch-based crosslinked phenolic heteropolymer.

Abstract translation: 公开的是针对环境友好的具有改进性能的淀粉基粘合剂和粘合剂添加剂的组合物和方法，其改进了现有淀粉基粘合剂的性能。 一些实施方案涉及包含以下的组合物：淀粉基交联的酚类杂聚物; 与淀粉基交联的酚类杂聚物共价结合的多种抗微生物剂; 和与淀粉类交联的酚类杂聚物共价结合的多个糖单元。 一些实施方案涉及改性淀粉基粘合剂，其包含：基于淀粉的粘合剂和添加剂，所述添加剂由包含淀粉基交联的酚类杂聚物的基于淀粉的组合物组成; 与淀粉基交联的酚类杂聚物共价结合的多种抗微生物剂; 以及与淀粉类交联酚醛共聚物共价结合的多个糖单元。

公开(公告)号：WO2012138723A1

公开(公告)日：2012-10-11

申请号：PCT/US2012/032118

申请日：2012-04-04

Applicant: CARGILL, INCORPORATED ,  OWENS CORNING INTELLECTUAL CAPITAL, LLC ,  ANDERSON, Kevin R. ,  HERNANDEZ-TORRES, Jesus

Inventor： ANDERSON, Kevin R. ,  HERNANDEZ-TORRES, Jesus

IPC: D04H13/00 ,  C09D103/02

CPC classification number: C08K5/11 ,  C08K5/0025 ,  C08K5/092 ,  C08K9/04 ,  C08L67/02 ,  C09J103/02 ,  C09J103/04 ,  C09J105/06 ,  D04H1/587 ,  D06M15/11 ,  D06M15/327 ,  E04B1/78 ,  Y10T442/2992

Abstract: An environmentally friendly, formaldehyde-free, aqueous binder composition that includes a carbohydrate, a crosslinking agent, and a pre-reacted product of an alcohol or polyol and monomeric or polymeric polycarboxylic acid or polyglycerol is provided. The pre-reacted product may include glycerol and esters of citric acid such a monoglyceryl citrate, diglyceryl citrate, and triglyceryl citrate as well as other higher molecular weight citric acid-based esters. The inclusion of the pre-reacted product in the binder composition helps to speed the crosslinking reaction, induces faster water evaporation, decreases the viscosity of the binder, helps to reduce the amount of water needed for application of the binder, decreases tackiness, and helps to achieve a maximum vertical expansion of the insulation pack in the transfer zone. The binder composition may be used in the formation of insulation materials and non-woven chopped strand mats.

Abstract translation: 提供了一种环境友好的无甲醛水性粘合剂组合物，其包含碳水化合物，交联剂和醇或多元醇与单体或聚合多羧酸或聚甘油的预反应产物。 预反应的产物可以包括甘油和柠檬酸的酯，例如柠檬酸单甘油酯，柠檬酸二甘油酯和柠檬酸三甘油酯以及其它较高分子量的柠檬酸基酯。 在粘合剂组合物中包含预反应产物有助于加速交联反应，引起更快的水蒸发，降低粘合剂的粘度，有助于减少施加粘合剂所需的水量，降低粘性，并有助于 以实现转移区域中的绝缘包的最大垂直膨胀。 粘合剂组合物可用于形成绝缘材料和无纺短切纤维垫。

公开(公告)号：WO2011073531A1

公开(公告)日：2011-06-23

申请号：PCT/FI2010/051049

申请日：2010-12-16

Applicant: TEKNOLOGLAN TUTKIMUSKESKUS VTT ,  MIKKONEN, Hannu ,  PELTONEN, Soili ,  KIVISTÖ, Antti ,  SUOMI-LINDBERG, Leena ,  MALI, Jyrki ,  PAAJANEN, Leena ,  SIIKA-AHO, Matti ,  KALLIOINEN, Anne ,  SUURNÄKKI, Anna ,  VIIKARI, Liisa

Inventor： MIKKONEN, Hannu ,  PELTONEN, Soili ,  KIVISTÖ, Antti ,  SUOMI-LINDBERG, Leena ,  MALI, Jyrki ,  PAAJANEN, Leena ,  SIIKA-AHO, Matti ,  KALLIOINEN, Anne ,  SUURNÄKKI, Anna ,  VIIKARI, Liisa

IPC: C09J103/04 ,  C09J197/00 ,  B27N3/00

CPC classification number: C09J103/10 ,  C08B31/10 ,  C08L3/08 ,  C08L3/10 ,  C08L89/00 ,  C08L99/00 ,  C09J103/04

Abstract: An adhesive composition and a method of producing the same. According to the present invention, a first adhesive component which comprises polyphenol and another adhesive component which comprises a starch derivative, are dissolved or dispersed in water. The polyphenol and the starch derivative are added into the water at a weight ratio which is approximately 1:50...50:1, in which case the quantities of polyphenol and starch derivative added are such that the dry matter percentage of the adhesive composition is at least 40 % by weight. The composition according to the present invention is particularly suitable for gluing of fibrous, such as laminated or veneer-based products.

Abstract translation: 粘合剂组合物及其制备方法。 根据本发明，包含多酚的第一粘合剂组分和包含淀粉衍生物的另一粘合剂组分溶解或分散在水中。 将多酚和淀粉衍生物以约1:50〜50:1的重量比加入到水中，在这种情况下，加入的多酚和淀粉衍生物的量使得粘合剂组合物的干物质百分数 至少为40重量％。 根据本发明的组合物特别适用于粘合纤维，例如层合或单板制品。

公开(公告)号：WO2011009047A2

公开(公告)日：2011-01-20

申请号：PCT/US2010/042268

申请日：2010-07-16

Applicant: YUAN, Ta Tung ,  CHUANG, Shih-Hsien ,  LIU, Tzu-Yin

Inventor： YUAN, Ta Tung ,  CHUANG, Shih-Hsien ,  LIU, Tzu-Yin

IPC: C07D207/40 ,  C07D207/36 ,  A61K31/4015 ,  A61P37/00

CPC classification number: C07D207/40 ,  A61K47/60 ,  C07K14/54 ,  C08H1/00 ,  C08L1/286 ,  C08L3/04 ,  C08L89/00 ,  C08L89/005 ,  C08L97/02 ,  C09J101/286 ,  C09J103/04 ,  C09J189/00 ,  C09J189/005 ,  C08K5/0025

Abstract: This invention relates to protein-polymer conjugates described in the specification. Also disclosed are a method for preparing a protein-polymer conjugate and using such a conjugate in treating various immune disorders.

Abstract translation: 本发明涉及说明书中描述的蛋白质 - 聚合物缀合物。 还公开了制备蛋白质 - 聚合物缀合物并使用这种缀合物治疗各种免疫病症的方法。

公开(公告)号：WO2002088271A1

公开(公告)日：2002-11-07

申请号：PCT/US2002/013724

申请日：2002-05-02

Applicant: ECOSYNTHETIX INC. ,  BLOEMBERGEN, Steven ,  KAPPEN, Frans ,  BEELEN, Brigit

Inventor： BLOEMBERGEN, Steven ,  KAPPEN, Frans ,  BEELEN, Brigit

IPC: C09J103/02

CPC classification number: C09J103/04 ,  C08L2666/28 ,  C09J103/02

Abstract: Environmentally friendly biopolymer adhesives are described, wherein the adhesives comprise biopolymer particles, more preferably starch microparticles, and most preferably starch nanoparticles, and their aqueous dispersions. Applications for the biopolymer particle adhesives are described, that are environmentally friendly alternatives to petroleum based synthetic adhesives. The biopolymer particle adhesives provide are biodegradable as well as repulpable, and thus provide bio-based recycling-friendly alternatives to synthetic adhesives derived from petroleum resources.

Abstract translation: 描述了环保生物聚合物粘合剂，其中粘合剂包括生物聚合物颗粒，更优选淀粉微粒，最优选淀粉纳米颗粒及其水分散体。 描述了用于生物聚合物颗粒粘合剂的应用，其是对石油基合成粘合剂是环境友好的替代物。 生物聚合物颗粒粘合剂提供是可生物降解的并且可再生的，因此为从石油资源衍生的合成粘合剂提供生物基回收友好的替代品。

公开(公告)号：WO1996035840A1

公开(公告)日：1996-11-14

申请号：PCT/FR1996000696

申请日：1996-05-09

Applicant: ROQUETTE FRERES

Inventor： ROQUETTE FRERES ,  FUERTES, Patrick ,  LAMBIN, Anne ,  DREUX, Jean-Louis

IPC: D21H17/29

CPC classification number: D21H17/29 ,  B41M5/52 ,  B41M5/5236 ,  C08B31/16 ,  C09J103/04

Abstract: A novel adhesive composition for paper and cardboard is described, which contains a cationic polysaccharide esterified by a dicarboxylic acid anhydride, characterised in that said dicarboxylic acid anhydride is substituted by a saturated or unsaturated, branched carbon chain. The anhydride may for example be tetrapropenylsuccinic anhydride or any isomer thereof. The adhesive composition of the invention may contain an oxidising agent such as a persulphate. It can advantageously be used for coating printing and/or writing paper, particularly envelope paper and paper for non-impact printing, such as ink jet printing.

Abstract translation: 描述了一种用于纸和纸板的新型粘合剂组合物，其包含由二羧酸酐酯化的阳离子多糖，其特征在于所述二羧酸酐被饱和或不饱和支链碳链取代。 酸酐可以是例如四丙烯基琥珀酸酐或其任何异构体。 本发明的粘合剂组合物可以含有氧化剂如过硫酸盐。 它可以有利地用于涂布印刷和/或书写纸，特别是用于无冲击印刷的信封纸和纸，例如喷墨印刷。

公开(公告)号：WO9321279A3

公开(公告)日：1994-01-06

申请号：PCT/EP9300872

申请日：1993-04-08

Applicant: FULLER H B GMBH

Inventor： PLUEMER JUERGEN ,  JANNUSCH LEONARD CHARLES

IPC: C08L29/04 ,  C08L31/04 ,  C08L33/02 ,  C09J103/04 ,  C09J129/04 ,  C09J133/02 ,  C09J201/00

CPC classification number: C09J129/04 ,  C08L29/04 ,  C08L31/04 ,  C08L33/02 ,  C08L2666/02 ,  C08L2666/04 ,  C09J103/04 ,  C09J133/02

Abstract: The invention relates to a process for producing an adhesive for bonding layers of paper in which an adhesive concentrate is first diluted to 1:10 and then reacted with an activating reagent, especially a base. In addition, the invention relates to an adhesive concentrate which can be used in the production of such an adhesive. The adhesive concentrate contains a polyhydroxy component or polyvinyl ester compound and a thickening agent, especially an acrylic acid polymer. By addition to the diluted adhesive concentrate of a base, the thickening agent is neutralised and becomes active, whereby the viscosity of the adhesive is set and can be adapted to each use. The process of the invention is economical and provides an adhesive with variable viscosity, solid body content and adhesive power. It is used especially in the production of tissue paper layers, particularly domestic and toilet paper.

Abstract translation: 本发明涉及一种粘合剂粘合层的制造方法，其中首先将粘合剂浓缩物稀释至1:10，然后与活化剂，特别是碱反应。 此外，本发明涉及可用于生产这种粘合剂的粘合剂浓缩物。 粘合剂浓缩物包含多羟基组分或聚乙烯基酯化合物和增稠剂，特别是丙烯酸聚合物。 通过加入碱的稀释的粘合剂浓缩物，增稠剂被中和并变得活性，由此粘合剂的粘度被设定并且可适用于每种使用。 本发明的方法是经济的并且提供具有可变粘度，固体含量和粘合力的粘合剂。 它特别用于生产薄纸层，特别是家用和卫生纸。

公开(公告)号：WO2015040242A1

公开(公告)日：2015-03-26

申请号：PCT/EP2014/070265

申请日：2014-09-23

Applicant: BASF SE

Inventor： SPROULE, Barry ,  BELOUADI, Chafiq

IPC: C09J7/04 ,  C09J109/06 ,  C09J133/08 ,  C08L9/06 ,  C08L29/04 ,  D21H19/22 ,  D21H19/58 ,  C08F236/10 ,  C08F236/12 ,  C08F273/00 ,  C09J103/00

CPC classification number: D21H19/58 ,  C08B31/00 ,  C08F251/00 ,  C08L3/02 ,  C08L29/04 ,  C08L33/24 ,  C08L39/00 ,  C08L51/02 ,  C09J103/04 ,  C09J133/08 ,  C09J151/02 ,  D21H19/22 ,  D21H27/40 ,  C08F212/08 ,  C08F236/10 ,  C08F220/06 ,  C08F236/06

Abstract: An adhesive formulation for paper is disclosed, comprising a first polymer obtained by polymerization of monomers including (a) a vinyl aromatic monomer, (b) a diene monomer, a (meth)acrylate monomer, or combinations thereof, and (c) a carbohydrate derived compound having a dextrose equivalent (DE) of about 10 to about 35; and a second polymer obtained by polymerization of monomers including at least 50% by weight of a vinyl formamide monomer. Methods of making the formulation, using it with paper, and paper bonded with the formulation are also disclosed.

Abstract translation: 公开了一种用于纸的粘合剂制剂，其包含通过聚合单体获得的第一聚合物，所述单体包括（a）乙烯基芳族单体，（b）二烯单体，（甲基）丙烯酸酯单体或其组合，和（c）碳水化合物 具有约10至约35的葡萄糖当量（DE）的衍生化合物; 和通过聚合包含至少50重量％的乙烯基甲酰胺单体的单体获得的第二聚合物。 还公开了用制剂制备制剂，用纸制造的纸和与制剂粘合的纸的方法。

公开(公告)号：WO2012166414A1

公开(公告)日：2012-12-06

申请号：PCT/US2012/038850

申请日：2012-05-21

Applicant: CARGILL, INCORPORATED ,  OWENS CORNING INTELLECTUAL CAPITAL, LLC ,  TOLFA, John, Carl ,  LOCHEL, Frank, P., Jr.

Inventor： TOLFA, John, Carl ,  LOCHEL, Frank, P., Jr.

IPC: B05D3/02 ,  C09D103/02

CPC classification number: C09J103/02 ,  C03C25/321 ,  C08K5/0025 ,  C08K5/092 ,  C08K5/103 ,  C08K9/04 ,  C08L3/02 ,  C08L91/00 ,  C09J103/04 ,  C09J105/06 ,  C09J191/00 ,  D04H1/64 ,  D04H3/004 ,  D04H3/12 ,  E04B1/7662

Abstract: An environmentally friendly, bio-based binder system that is useful for the formation of fiberglass insulation, the system includes: A) an aqueous curable binder composition, which includes a carbohydrate and a crosslinking agent; and B) a dedust composition, which includes a blown, stripped plant-based oil and optionally at least one emulsifying agent. The bio-based binder system is typically heated to form a cured binder system.

Abstract translation: 一种可用于形成玻璃纤维绝缘体的环保生物基粘合剂体系，该系统包括：A）包含碳水化合物和交联剂的水性可固化粘合剂组合物; 和B）除尘组合物，其包括吹制，剥离的植物油和任选的至少一种乳化剂。 通常将生物基粘合剂体系加热以形成固化的粘合剂体系。

公开(公告)号：WO2011009812A1

公开(公告)日：2011-01-27

申请号：PCT/EP2010/060272

申请日：2010-07-16

Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V. ,  KHABBAZ, Farideh ,  FARE, Joanna

Inventor： KHABBAZ, Farideh ,  FARE, Joanna

IPC: C08L97/02 ,  C09J189/00 ,  C09J179/02 ,  C09J131/04 ,  C09J133/08 ,  C09J135/06

CPC classification number: C08L97/02 ,  C08L1/286 ,  C08L3/04 ,  C08L79/02 ,  C08L89/00 ,  C08L89/005 ,  C08L2666/02 ,  C09J101/286 ,  C09J103/04 ,  C09J131/04 ,  C09J133/08 ,  C09J133/10 ,  C09J179/02 ,  C09J189/00 ,  C09J189/005 ,  C08K5/0025

Abstract: The invention relates to an adhesive system comprising - a protein; - a polymer comprising at least one carboxylic group or at least one carboxylic anhydride group, or a combination thereof, with the proviso that said polymer does not contain 5 to 90 wt-% of vinyl pivalate units in combination with 0.2 to 15 wt-% of primary hydroxyl group-containing vinyl compound units, and - a polyamine-epihalohydrin. The invention further relates to the use of the adhesive system, an adhesive composition, a method of producing a wood based product and a wood based product.

Abstract translation: 本发明涉及包含蛋白质的粘合剂体系; - 包含至少一个羧基或至少一个羧酸酐基团的聚合物或其组合，条件是所述聚合物不含5-90重量％的新戊酸乙烯酯单元和0.2至15重量％ 含伯羟基的乙烯基化合物单元，和 - 多胺 - 表卤代醇。 本发明还涉及粘合剂体系的使用，粘合剂组合物，木制产品的生产方法和木制品。