SOLID ACIDS AS CATALYSTS FOR THE PREPARATION OF HYDROCARBON RESINS
    2.
    发明申请
    SOLID ACIDS AS CATALYSTS FOR THE PREPARATION OF HYDROCARBON RESINS 审中-公开
    固体酸作为制备碳氢化合物树脂的催化剂

    公开(公告)号:WO98030519A1

    公开(公告)日:1998-07-16

    申请号:PCT/US1998/000009

    申请日:1998-01-07

    CPC classification number: C08F240/00 C08F10/00 C08F12/04 C08F4/005 C08F4/06

    Abstract: Solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer, C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5 DEG C to 170 DEG C can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerisation catalysts since the acid sites are an integral part of the solid. The solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.

    Abstract translation: 使用固体酸作为用于聚合包含纯单体,C5单体和C9单体中的至少一种的进料流的催化剂以产生烃树脂。 在使用之前,可以从固体酸催化剂中除去自由相关的水。 可以制备在约5℃至170℃范围内具有软化点(环和球)的树脂。 这些催化剂比传统的Friedel-Crafts聚合催化剂具有优势,因为酸性位点是固体的组成部分。 固体酸催化剂是相对非危险的,可重复使用的催化剂,其消除或至少减少所得树脂产物与酸残基或副产物的污染。

    CATALYST COMPOSITION FOR OLIGOMERIZATION OF ETHYLENE OLIGOMERIZATION PROCESS AND METHOD FOR ITS PREPARATION
    3.
    发明申请
    CATALYST COMPOSITION FOR OLIGOMERIZATION OF ETHYLENE OLIGOMERIZATION PROCESS AND METHOD FOR ITS PREPARATION 审中-公开
    用于乙烯低聚化方法低级化的催化组合物及其制备方法

    公开(公告)号:WO2009074203A1

    公开(公告)日:2009-06-18

    申请号:PCT/EP2008/009585

    申请日:2008-11-13

    Abstract: Catalyst composition for the oligomerization of ethylene, comprising (i) an at least partially hydrolyzed transition metal compound, obtainable by controlled addition of water to a transition metal compound having the general formula MX m (OR') 4-m or MX m (OOCR') 4-m , wherein R' is an alkyl, alkenyl, aryl, aralkyl or cycloalkyl group, X is halogen, preferably Cl or Br, and m is from 0 to 4; preferably 0-3; and (ii) an organoaluminum compound as a cocatalyst, wherein the molar ratio of water and transition metal compound is within a range of between about (0.01-3): 1; a process for oligomerization of ethylene and a method for preparing the catalyst composition.

    Abstract translation: 用于乙烯低聚的催化剂组合物,其包含(i)至少部分水解的过渡金属化合物,其可通过将具有通式MX m(OR')4-m或MX m(OOCR')的过渡金属化合物控制加入而获得, 4-m,其中R'是烷基,烯基,芳基,芳烷基或环烷基,X是卤素,优选Cl或Br,m是0-4; 优选0-3; 和(ii)作为助催化剂的有机铝化合物,其中水和过渡金属化合物的摩尔比在约(0.01-3):1之间的范围内; 乙烯低聚方法和制备催化剂组合物的方法。

    OLEFIN OLIGOMERIZATION METHOD USING ONLINE MEASUREMENT OF CHROMIUM CONCENTRATION IN A CATALYTIC SYSTEM

    公开(公告)号:WO2019108081A1

    公开(公告)日:2019-06-06

    申请号:PCT/RU2017/000890

    申请日:2017-12-01

    Abstract: The present invention relates to the method for producing α-olefins by oligomerization of C2 to C4 olefins. The olefin oligomerization method is carried out in a presence of a catalytic system comprising: 1) a chromium source, 2) a nitrogen-containing ligand, 3) alkyl aluminium and optionally in the presence of a zinc compound, thereby, prior to feeding the catalytic system to the oligomerization reactor its dilution is carried out with subsequent online determination of chromium concentration in the diluted catalytic system by measuring optical density of obtained diluted solution after producing the catalytic system, and correction, if necessary, of the amount of solvent fed for diluting the catalytic system in response to performed measurement. The method in accordance with the present invention allows for significantly simplifying control of catalytic system concentration after its dilution and the amount of diluted catalytic system fed to the olefin oligomerization reactor, which, in its turn, allows for providing high selectivity and productivity of the olefin oligomerization process.

    REDUCTION OF ORGANIC HALIDES IN ALKYLATE GASOLINE
    9.
    发明申请
    REDUCTION OF ORGANIC HALIDES IN ALKYLATE GASOLINE 审中-公开
    有效降低碱性汽油中的有机物

    公开(公告)号:WO2008073945A3

    公开(公告)日:2008-09-25

    申请号:PCT/US2007087113

    申请日:2007-12-12

    Abstract: An alkylation process comprising contacting a first hydrocarbon feed comprising at least one olefin having from 2 to 6 carbon atoms and a second hydrocarbon feed comprising at least one isoparaffin having from 3 to 6 carbon atoms with a halide-based acidic ionic liquid catalyst under alkylation conditions to produce an alkylate containing an organic halide and contacting at least a portion of the alkylate with a hydrotreating catalyst in the presence of hydrogen under hydrotreating conditions to reduce the concentration of the organic halide is disclosed.

    Abstract translation: 一种烷基化方法,包括在烷基化条件下使包含至少一种具有2至6个碳原子的烯烃的第一烃进料和包含至少一个具有3至6个碳原子的异链烷烃的第二烃进料与卤化物基酸性离子液体催化剂接触 以产生含有有机卤化物的烷基化物,并且在加氢处理条件下在氢气存在下,使烷基化物的至少一部分与加氢处理催化剂接触以降低有机卤化物的浓度。

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