公开(公告)号：EP2200960A2

公开(公告)日：2010-06-30

申请号：EP08803385.7

申请日：2008-08-29

申请人： BASF SE

发明人： HENKELMANN, Jochem ,  PROCHAZKA, Roman ,  BEY, Oliver ,  MAURER, Stephan ,  STEINER, Jochen ,  URTEL, Heiko ,  THEIS, Gerhard ,  WAHL, Peter ,  BECKER, Michael

IPC分类号： C07C29/60 ,  C07C31/20 ,  B01J23/72

CPC分类号： C07C67/03 ,  C07C29/60 ,  Y02E50/13 ,  C07C31/205 ,  C07C69/52 ,  C07C69/24

摘要： The invention relates to a method for producing 1,2-propandiol, wherein a flow containing glycerine, in particular a flow produced on an industrial scale during the production of biodiesel, is subjected to low-pressure hydrogenation.

公开(公告)号：EP1613576B1

公开(公告)日：2010-05-26

申请号：EP04722176.7

申请日：2004-03-20

申请人： BASF SE

发明人： HUBER-DIRR, Sylvia ,  HESSE, Michael ,  HAUNERT, Andrea ,  JUNICKE, Henrik

IPC分类号： C07C29/149 ,  B01J23/72 ,  B01J21/04

CPC分类号： C07C29/149 ,  B01J23/83 ,  C07C31/20

公开(公告)号：EP2165760A2

公开(公告)日：2010-03-24

申请号：EP08155700.1

申请日：1997-03-21

申请人： BASF Catalysts LLC

发明人： Chen, Jianping

IPC分类号： B01J23/72 ,  B01D53/86 ,  B01J23/00 ,  C07C37/16 ,  C01B3/58 ,  C07C231/06 ,  C07C67/40 ,  C07C45/29 ,  C07C45/00 ,  C07C209/16

CPC分类号： C07C29/154 ,  B01D53/86 ,  B01J21/04 ,  B01J23/002 ,  B01J23/005 ,  B01J23/72 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8892 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/031 ,  B01J37/038 ,  B01J2523/00 ,  C01B17/78 ,  C07C1/22 ,  C07C29/149 ,  C07C37/16 ,  C07C209/36 ,  C07C209/48 ,  C07C231/065 ,  C07C2521/04 ,  C07C2523/72 ,  C07D301/32 ,  Y02P20/52 ,  C07C31/125 ,  B01J2523/17 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/67 ,  C07C31/04 ,  C07C39/06 ,  C07C39/07

摘要： Use of a solid Cu-Al-O catalyst comprising a tablet being formed with 0 to 8% graphite powder substantially free of chromium, the catalyst comprising a tablet having a pore volume from 0.2 ml/g to 0.6 ml/g and a bulk density of 0.7 g/ml to 1.5 g/ml, the solid catalyst having a bimodal pore size distribution centering around 100 Å and between 500 Å and 2000 Å and having a surface area of 20m2/g to 200m2/g, the catalyst having a calculated alumina content 30% to 60% by weight, the calculated CuO content is 70% to 40% by weight, the catalyst having a promoter being present in an amount no greater than 25% by weight of the catalyst and being chosen from the group consisting of salts and oxides of Ce, Mn, Ba and Ni in a catalytic reaction chosen from the group consisting of hydration of acrylonitrile to acrylamide, alkylation of a phenol with alcohol, amination of an alcohol, dehydrogenation of an alcohol, hydration of a nitrile, oxidation of carbon monoxide, oxidation of a vapor organic compound, oxidation of sulfur dioxide, oxidation of an alcohol, decomposition of nitric oxide, selective catalytic reduction of nitric oxide, and purification of a gas stream by the removal of oxygen.

摘要翻译： 使用包含形成有基本上不含铬的0至8％石墨粉末的片剂的固体Cu-Al-O催化剂，所述催化剂包含孔体积为0.2ml / g至0.6ml / g的片剂和堆积密度 为0.7g / ml至1.5g / ml，该固体催化剂的双峰孔径分布为中心在大约的范围内且介于500和2000之间，表面积为20m 2 / g至200m 2 / g，催化剂具有计算值 氧化铝含量为30重量％至60重量％，所计算的CuO含量为70重量％至40重量％，催化剂的催化剂的存在量不大于催化剂的25重量％，并且选自 在催化反应中选择Ce，Mn，Ba和Ni的盐和氧化物，所述催化反应选自丙烯腈与丙烯酰胺的水合，苯酚与醇的烷基化，醇的胺化，醇的脱氢，腈的水合， 氧化一氧化碳，氧化有机蒸汽 化合物，二氧化硫的氧化，醇的氧化，一氧化氮的分解，一氧化氮的选择性催化还原，以及通过除去氧而净化气流。

公开(公告)号：EP2119491A4

公开(公告)日：2010-03-10

申请号：EP08703402

申请日：2008-01-17

申请人： TOYOTA CHUO KENKYUSHO KK

发明人： KAYAMA TOMOYUKI ,  YAMAZAKI KIYOSHI ,  MATSUNAGA SHINICHI ,  SHINJOH HIROFUMI

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J23/63 ,  B01J23/66 ,  B01J23/68 ,  B01J23/72 ,  B01J23/89 ,  B01J23/90 ,  B01J37/08 ,  B01J38/02 ,  B22F1/02 ,  B22F9/24 ,  F01N3/02

CPC分类号： B01D53/945 ,  B01D53/944 ,  B01D53/9495 ,  B01D53/96 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/1026 ,  B01D2255/1028 ,  B01D2255/104 ,  B01D2255/106 ,  B01D2255/2047 ,  B01D2255/206 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/2092 ,  B01D2255/9022 ,  B01D2255/9202 ,  B01J23/50 ,  B01J23/63 ,  B01J23/66 ,  B01J23/68 ,  B01J23/83 ,  B01J23/89 ,  B01J35/006 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0225 ,  B01J37/0242 ,  B01J37/0244 ,  B01J37/031 ,  B22F1/02 ,  B22F9/24 ,  F01N3/035 ,  F01N9/002 ,  Y02T10/22 ,  Y02T10/47

公开(公告)号：EP2117697A1

公开(公告)日：2009-11-18

申请号：EP08704513.4

申请日：2008-01-31

申请人： Kao Corporation

发明人： SHIRASAWA, Takeshi ,  KUMITA, Yasukazu ,  SAITO, Eiji

IPC分类号： B01J10/00 ,  B01J12/00 ,  B01J23/72 ,  B01J35/06 ,  C07C45/00 ,  C07C47/02

CPC分类号： B01J10/007 ,  B01J12/007 ,  B01J23/72 ,  C07C45/002 ,  C07C47/02

摘要： A reaction device according to the present invention is used in production of aldehyde from alcohol. The reaction device includes a reactor having a reaction field where a catalyst is provided inside and a reaction fluid flows. The catalyst has a surface extending in the direction of flow of the reaction fluid and contains Cu.

公开(公告)号：EP1153657B1

公开(公告)日：2009-09-09

申请号：EP99935050.7

申请日：1999-08-04

申请人： Japan Science and Technology Agency

发明人： KOBAYASHI, Shu

IPC分类号： B01J27/10 ,  C07C45/60 ,  B01J31/12 ,  B01J23/06 ,  B01J23/14 ,  B01J23/72 ,  B01J23/74

CPC分类号： C07C45/72 ,  B01J27/10 ,  B01J27/125 ,  B01J35/002 ,  B01J2531/96 ,  C07C45/511 ,  C07C49/83

摘要： An organic synthesis method in which a metal compound stable in water and functioning as a Lewis acid is used as a novel Lewis acid catalyst in a reaction system employing water as part or all of the solvent, wherein the compound gives a metal ion having a hydrolysis constant (pKh) of 4.3 to 10.1 and a water exchange rate constant (WERC) of 3.2x10?6 M-1sec-1¿ or larger.

公开(公告)号：EP2066445A1

公开(公告)日：2009-06-10

申请号：EP07801383.6

申请日：2007-09-25

申请人： Technical University of Denmark

发明人： RASMUSSEN, Søren Birk ,  KUSTOV, Arkady ,  FEHRMANN, Rasmus ,  DUE-HANSEN, Johannes

IPC分类号： B01J37/20 ,  B01J23/22 ,  B01J23/72 ,  B01J23/745 ,  B01D53/86

CPC分类号： B01J37/20 ,  B01D53/8628 ,  B01D2251/2062 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/20769 ,  B01D2255/9205 ,  B01D2255/9207 ,  B01J21/063 ,  B01J21/066 ,  B01J23/22 ,  B01J23/72 ,  B01J23/745 ,  B01J27/053

摘要： The present invention concerns a process for selectively removing nitrogen oxides (NOx) from exhaust or flue gasses, especially from gases arising from the burning of biomass, combined biomass-fossil fuel and from waste incineration units, and a catalyst for this process. The process relates to the selective catalytic reduction (SCR) of NOx with ammonia as reductant which is the most common method to catalytically reduce NOx in flue gasses from stationary sources. SCR systems are designed to clean the nitrogen dioxide (NO 2 and nitrogen oxide (NO) out of flue gasses. The present invention relates to a process for the selective removal of nitrogen oxides in the presence of ammonia from gases containing a significant amount of alkali metal and/or alkali-earth compounds which process comprises using a catalyst combined of a) a formed porous superacidic support b) a metal oxide catalytic component deposited on said support selected from the group consisting of Cu, V, Fe, Cr, Mn, Mo and mixtures thereof. The support can e.g. be obtained by the adsorbing of sulfate ions onto amorphous or crystalline inorganic oxide of Zr, Ti, Fe, Sn, Si, Al, and Hf, followed by calcination in air.

摘要翻译： 本发明涉及从废气或烟道气体，特别是从燃烧生物质，组合的生物质 - 化石燃料和废物焚烧装置产生的气体中选择性地除去氮氧化物（NOx）的方法和用于该方法的催化剂。 该方法涉及NOx与氨作为还原剂的选择性催化还原（SCR），这是从固定源催化还原烟气中的NOx的最常用方法。 SCR系统设计用于清除烟道气中的二氧化氮（NO 2和氮氧化物（NO）），本发明涉及一种在氨气存在下从含有大量碱的气体中选择性除去氮氧化物的方法 金属和/或碱土化合物，其包括使用以下组合的催化剂：a）形成的多孔超酸性载体b）沉积在所述载体上的金属氧化物催化组分，所述金属氧化物催化组分选自Cu，V，Fe，Cr，Mn， Mo及其混合物。 支持体例如 通过将硫酸根离子吸附到Zr，Ti，Fe，Sn，Si，Al和Hf的无定形或结晶无机氧化物上，然后在空气中煅烧而获得。

公开(公告)号：EP1994985A1

公开(公告)日：2008-11-26

申请号：EP07737592.1

申请日：2007-03-01

申请人： Nissan Motor Company Limited ,  The University of Tokyo

发明人： NIWA, Yusuke ,  MATSUSHITA, Kenjiro ,  MASUDA, Kouji ,  DOMEN, Kazunari ,  TERAMURA, Kentaro

IPC分类号： B01J35/02 ,  B01D53/86 ,  B01J23/10 ,  B01J23/18 ,  B01J23/22 ,  B01J23/72 ,  B01J23/745 ,  B01J23/83 ,  B01J23/89

CPC分类号： B01J23/10 ,  B01D2255/206 ,  B01D2255/20738 ,  B01D2255/40 ,  B01D2255/802 ,  B01J21/063 ,  B01J23/18 ,  B01J23/22 ,  B01J23/72 ,  B01J23/745 ,  B01J23/83 ,  B01J23/8906 ,  B01J35/004

摘要： Disclosed is a photocatalyst activation system characterized by including (a) a catalyst which includes a photocatalytic material containing cerium oxide, or a catalyst which includes a photocatalytic material containing at least one oxide selected from the group consisting of transition metal oxides other than cerium oxide; (b) a light source which irradiates the catalyst with light; and (c) a heat transfer device which transfers heat to the catalyst. By this photocatalyst activation system, it is possible to widen a usable wavelength range of light, and to enhance the catalytic activity to a large extent.

摘要翻译： 公开了一种光催化剂活化体系，其特征在于包括（a）包含含有氧化铈的光催化材料的催化剂或包含选自氧化铈以外的过渡金属氧化物中的至少一种氧化物的光催化材料的催化剂; （b）用光照射催化剂的光源; 和（c）将热传递到催化剂的传热装置。 通过该光催化剂活化体系，可以扩大光的可用波长范围，并且可以在很大程度上提高催化活性。

公开(公告)号：EP1987877A2

公开(公告)日：2008-11-05

申请号：EP08005787.0

申请日：2008-03-27

申请人： Nippon Shokubai Co., Ltd.

发明人： Fukumoto, Naohiro

IPC分类号： B01J23/00 ,  B01J23/18 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J23/72 ,  B01J23/745 ,  C07C47/22 ,  C07C51/25 ,  C07C57/04

CPC分类号： B01J23/002 ,  B01J23/28 ,  B01J23/8876 ,  B01J23/8885 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0063 ,  B01J37/009 ,  B01J37/0221 ,  B01J37/0236 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/47 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/842 ,  B01J2523/847

摘要： The invention provides a process which enables, in preparation of acrolein by catalytic gas-phase oxidation of propylene in the presence of molecular oxygen or a molecular oxygen-containing gas or in preparation of acrylic acid by catalytic gas-phase oxidation of acrolein in the presence of molecular oxygen or a molecular oxygen-containing gas, using single kind of atalyst, to suppress occurrence of localized extraordinarily high temperature spots (hot spots) in the catalyst layer and can stably maintain high acrolein or acrylic acid yield for a long time. The process is characterized by use of an oxide catalyst containing molybdenum as an essential component and having relative standard deviation of its particle size in a range of 0.02 to 0.20.

摘要翻译： 本发明提供一种能够在制剂通过丙烯的催化气相氧化丙烯醛的在分子氧或含分子氧的气体或通过在存在丙烯醛的催化气相氧化制备丙烯酸的存在 的分子氧或含分子氧的气体，使用单一种类的atalyst，为了抑制在催化剂层的局部异常高温点（热点）的发生，并能够稳定地保持高丙烯醛或丙烯酸产率很长时间。 该过程由使用的氧化物催化剂含有钼作为必要成分，并具有到0点20的范围内的12点02分其粒径的相对标准偏差为特征。

公开(公告)号：EP1948358A1

公开(公告)日：2008-07-30

申请号：EP06839813.0

申请日：2006-11-10

申请人： Oxy Vinyls L.P.

发明人： KRAMER, Keith, S. ,  COWFER, Joseph, A.

IPC分类号： B01J21/00 ,  B01J21/06 ,  B01J21/12 ,  B01J21/14 ,  B01J21/16 ,  B01J23/72 ,  B01J23/76 ,  B01J23/02 ,  B01J32/00 ,  C07C17/156 ,  B01J37/04 ,  B01J35/02

CPC分类号： C07C17/152 ,  B01J21/12 ,  B01J23/83 ,  B01J27/122 ,  B01J27/138 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  C07C17/154 ,  C07C17/156 ,  C07C19/045

摘要： Oxychlorination catalyst compositions which include a catalytically effective amount of an oxychlorination catalyst and a diluent having certain chemical composition and/or physical properties are disclosed. Processes using such oxychlorination catalyst compositions are also described. Some oxychlorination catalyst compositions and processes disclosed herein can increase the optimal operating temperature, and thereby increase the production capacity of an existing reactor, such as a fluid-bed reactor, compared to other oxychlorination catalyst compositions.