PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION, AND TERPYRIDINE COMPOUND OR ESTERIFICATION PRODUCT THEREOF
    141.
    发明公开
    PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION, AND TERPYRIDINE COMPOUND OR ESTERIFICATION PRODUCT THEREOF 有权
    光电转换元件,染料敏化太阳能电池中,金属络合物染料,染料溶液和三联吡啶连接或酯化THEREOF

    公开(公告)号:EP3168847A1

    公开(公告)日:2017-05-17

    申请号:EP15818813.6

    申请日:2015-07-01

    摘要: Provided are a photoelectric conversion element including a photoelectric conversion element including an electrically conductive support, a photoconductor layer including an electrolyte, a charge transfer layer including an electrolyte, and a counter electrode, in which the photoconductor layer has semiconductor fine particles carrying a metal complex dye represented by the following Formula (I), and a dye-sensitized solar cell; and a metal complex dye, a dye solution, and a terpyridine compound or an esterified product thereof which used in the photoelectric conversion element and the dye-sensitized solar cell,

            Formula (I)     M(LA)(LD)(LX) mX ·(CI) mY

    in the formula, M represents a metal ion, LA represents a tridentate ligand represented by the following Formula (AL-1), LD represents a bidentate ligand, or a tridentate ligand, at least one of coordinating atoms in LD bonded to the metal ion M is a nitrogen atom, at least one of the coordinating atoms is an anion, LX represents a monodentate ligand, mX represents 0 or 1, CI represents a counterion, and mY represents an integer of 0 to 3; and


    in the formula, Za and Zb each represent a non-metal atomic group necessary for forming a 5- or 6-membered ring, and at least one of the Za ring and the Zb ring has one or more acidic groups, L W represents a nitrogen atom or CR W , R W represents a hydrogen atom or a substituent, G represents a ring group represented by any one of Formulae (X-1) to (X-3), n represents an integer of 2 to 7, T represents a hydrogen atom or a substituent, a -(G)n-T group does not have an acidic group and an amino group, Zt2 and Zt3 each represent a non-metal atomic group necessary for forming a fused ring, R T1 to R T3 each represent a substituent, PT1 represents an integer of 0 to 2, PT2 and PT3 are each an integer of 0 or more, and * represents a binding position.

    摘要翻译: 本发明提供了包括光电转换元件,其包括在导电支撑的光电转换元件,光电导体层包括电解质,电荷转移层在电解质包括,和对电极,其中,所述光导层具有载有金属络合物半导体微粒 染料由下式(I),和染料敏化太阳能电池为代表; 和金属配合物染料,染料溶液中,在酯化产品的其在所述光电转换元件和染料敏化太阳能电池中使用的三联吡啶化合物或,€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒFormula (I)€ƒ€ƒ€ƒ€ƒ€ƒM(LA)(LD)(LX)式中米·(CI)M Y,M darstellt金属离子,LA darstellt由下式表示的三齿配体(AL -1),LD darstellt二齿配体,或三齿配体,配位在LD键合到金属离子M原子被氮原子中的至少一个,所述配位原子中的至少一个是阴离子,LX darstellt单齿配体 ,MX darstellt 0或1,CI darstellt抗衡离子,和我的darstellt为0至3的整数; 并且,式中,Za和Zb各自代表非金属原子基团的必要用于形成5-或6-元环,以及Za和所述ZB环环具有一个或多个酸性基团,LW darstellt一个中的至少一个 氮原子或CR W,RW darstellt氢原子或取代基,G darstellt由式中的任何一个(X-1)〜(X-3)所示的环基团,n darstellt 2至7的整数,T表示 氢原子或取代基, - (G)NT组不具有酸性基团和在氨基,ZT2和ZT3各自表示必要用于形成稠合环的非金属原子团,R T1至R T3的每一个代表 取代基,PT1 darstellt为0至2的整数,PT2和PT3分别在0以上的整数,并且* darstellt的结合位置。

    INCREASED-TRANSPARENCY PHOTOVOLTAIC DEVICE
    143.
    发明公开
    INCREASED-TRANSPARENCY PHOTOVOLTAIC DEVICE 审中-公开
    PHOTOVOLTAIKVORRICHTUNG MITERHÖHTERTRANSPARENZ

    公开(公告)号:EP3146573A1

    公开(公告)日:2017-03-29

    申请号:EP15723750.4

    申请日:2015-05-18

    摘要: A photovoltaic device comprises plural layers separated into plural cells, each comprising a region of a photoactive layer and electrodes on opposite sides thereof. Each of the regions of the photoactive layer are formed comprising a first part that comprises photoactive material and a second part that is not photoactive and that has a greater transmittance of visible light than the light absorbing photoactive material, in pre-selected locations, or in a pre-selected distribution of locations, across the region of the photoactive layer. One of the first and second parts are located in plural separate areas within the other of the first and second parts. The transparency of the photovoltaic device is increased by the transmission of light through the second part that is not photoactive.

    摘要翻译: 光电器件包括被分成多个单元的多个层,每个单元包括光电层的区域和相对的两侧的电极。 光活性层的每个区域形成为包括光敏材料的第一部分和不是光敏的第二部分,并且在预先选择的位置中具有比光吸收光活性材料更大的可见光透射率,或者在 在光活性层的区域上预先选择的位置分布。 第一和第二部分中的一个位于第一和第二部分的另一部分内的多个分开的区域中。 通过不透光的第二部分的光的透过来增加光伏器件的透明度。