Abstract:
The invention relates to a method for producing a catalyst comprising 0.05 - 0.25 wt % of noble metal, preferably for the oxidative dehydration of olefinically unsaturated alcohols, comprising the following steps: a) generating a direct current plasma, b) introducing metal and carrier material into the plasma, c) vaporizing metal and carrier material in the plasma or "blasting" the solid body of metal and carrier material in the plasma, and reacting the particles, d) cooling, wherein very small particles of composite material are obtained, and e) applying the composite material to the actual catalyst carrier. The invention further relates to a correspondingly produced catalyst, and to the use thereof.
Abstract:
Catalyst for the production of ethylene oxide, at least comprising silver applied to a carrier, said carrier having a BET constant ranging from 0 to 800 as per DIN ISO 9277.
Abstract:
Method for producing a catalyst that is used for the production of ethylene oxide and comprises silver and zinc applied to a carrier, said method at least including the steps of (i) providing a carrier, (ii) applying 10 ppm to 1500 ppm of zinc to the carrier from step (i) by bringing the carrier in contact with at least one mixture G1 comprising at least one zinc compound, the amount of applied zinc being calculated as an element and relative to the total weight of the carrier from step (i), (iii) drying and/or calcining the carrier obtained in step (ii), (iv) applying silver to the dry and/or calcined carrier by bringing the carrier in contact with at least one mixture G2 comprising at least one silver compound.
Abstract:
Proposed is a process for preparing isocyanates by dissociating the corresponding carbamates, which is characterized in that the carbamates are dissociated in the presence of a heterogeneous Lewis-acidic catalyst.
Abstract:
Method for production of ethylene oxide in a microchannel reactor, wherein an ethylene-containing material stream and an oxygen- or oxygen-source-containing material stream are fed to the microchannel reactor and the reaction to give ethylene oxide takes place in the catalyst-containing microchannel reactor. Alkyl halides are continuously fed to the microchannel reactor at a concentration of 0.3 to 50 ppm by volume with respect to the total volume stream of all material streams fed to the reactor.
Abstract:
The invention relates to a method for producing a catalyst used for oxidizing ethylene to obtain ethylene oxide, comprising the steps of a) providing a carrier that has a temperature T 0 , contains aluminum oxide, and is impregnated with silver or a compound containing silver; and b) heating the impregnated carrier from temperature T 0 to a temperature T 1 at a minimum heating rate of 30 K/min. The invention also relates to the catalyst obtained using said method.