9-Anthrylalkyl compounds, their preparation and their use
    17.
    发明公开
    9-Anthrylalkyl compounds, their preparation and their use 失效
    9-Anthrylalkyl-Verbindungen,ihre Herstellung und ihre Verwendung。

    公开(公告)号:EP0365495A2

    公开(公告)日:1990-04-25

    申请号:EP89850246.3

    申请日:1989-08-04

    IPC分类号: C07C69/96 C07C33/18

    摘要: New 9-anthrylalkyl compounds having the general formula
    wherein R is hydrogen or an alkyl group, whereby, however, not more than one of the groups R is an alkyl group; R₁ is hydrogen, lower alkyl, halogen or nitro; n is an integer of from 1 to 7, whereby ,however, the total number of carbon atoms in the group -CHR-(CHR) n - does not exceed 8; and X is halogen, an azide group or a succinimidyl group.
    The new compounds are prepared from 9-anthrylalcohols which are reacted with a compound X-CO-X wherein X is a halogen, and then optionally with compounds giving azide or succinimidyl group. The compounds are used as derivatiza­tion reagents for separation and detection purposes.
    Intermediates for preparation of the above defined 9-anthrylalkyl compounds wherein one R is an alkyl group are 9-anthrylalcohols with the group -CHR-(CHR) n -OH, wherein one R is an alkyl group.

    摘要翻译: 具有通式的新的9-蒽基烷基化合物,其中R是氢或烷基,其中不超过一个基团R是烷基; R1是氢,低级烷基,卤素或硝基; n为1〜7的整数,但-CHR-(CHR)n-基团中的碳原子总数不超过8; X为卤素,叠氮基或琥珀酰亚胺基。 新化合物由与蒽化合物X-CO-X反应的9-蒽醇制备,其中X为卤素,然后任选与化合物给予叠氮化物或琥珀酰亚胺基。 该化合物用作分离和检测目的的衍生试剂。 用于制备上述定义的9-蒽基烷基化合物的中间体,其中一个R是烷基是具有基团-CHR-(CHR)n -OH的9-蒽基,其中一个R是烷基。