摘要:
A photoresist polymer having a spiro cyclic ketal group, and a photoresist composition including the same are disclosed. The photoresist polymer and the photoresist composition can improve the resolution and the process margin due to its low activation energy of the deprotection reaction of the spiro cyclic ketal group, and can produce fine photoresist patterns due to its low PEB(Post Exposure Baking) temperature sensitivity.
摘要:
Disclosed are a photo-sensitive compound and a photoresist composition containing the same, for forming ultra-fine photoresist patterns. The photo-sensitive compound is resented by following Formula 1,
wherein x is an integer of 1 to 5, y is an integer of 2 to 6, R is a C 2 ~C 20 hydrocarbon group. The photoresist composition comprises 1~85 weight% of a photo-sensitive compound represented by following Formula 1; 1~55 weight% of a compound which reacts with a hydroxyl group (-OH) of the compound represented by Formula 1 to combine with the photo-sensitive compound represented by Formula 1; 1~15 weight% of a photo-acid generator; and 12~97 weight% of an organic solvent.
摘要:
An acid-amplifier having an acetal group and a photoresist composition including the same, are disclosed. The acid-amplifier produces an acid (second acid) during a post-exposure-bake (PEB), which is induced by an acid (first acid) generated from a photo-acid generator (PAG) at the exposure process so that a line edge roughness (LER) of the photoresist pattern and photoresist energy sensitivity are improved. The acid-amplifier has a structure of following Formula 1.
in Formula 1, R is C 4 ~C 20 mono-cyclic or multi-cyclic saturated hydrocarbon, R 1 is C 1 ∼C 10 linear hydrocarbon, C 1 ~C 10 perfluoro compound or C 5~ C 20 aromatic compound, R a and R b are independently hydrogen atom or C 1 ~C 4 saturated hydrocarbon and A is independently oxygen atom (O) or sulfur atom (S).
摘要:
Is disclosed a method for manufacturing fine patterns of semiconductor devices using a double exposure patterning process for manufacturing the second photoresist patterns by simply exposing without an exposure mask. The method comprises the steps of: forming a first photoresist pattern on a semiconductor substrate on which a layer to be etched is formed; coating a composition for a mirror interlayer on the first photoresist pattern to form a mirror interlayer; forming a photoresist layer on the resultant; and forming a second photoresist pattern which is made by a scattered reflection of the mirror-interlayer and positioned between the first photoresist patterns, by exposing the photoresist layer to a light having energy which is lower than a threshold energy (E th ) of the photoresist layer without an exposure mask, and then developing the same.
摘要:
A polymer including a monomer represented by the following Formula and a photoresist composition including the same are disclosed. The polymer and photoresist composition can improve the resolution and the process margin due to the low activation energy of the deprotection reaction of the alcohol ester group including saturated cyclic hydrocarbyl group, and also can produce fine photoresist patterns because they have a stable PEB(Post Exposure Baking) temperature sensitivity, and further, can improve the focus depth margin and the line edge roughness of the resist layer.
In the above Formula, R* is a hydrogen or methyl group, R 1 is saturated hydrocarbyl group of 1 to 5 carbon atoms, R is mono-cyclic or multi-cyclic homo or hetero saturated hydrocarbyl group of 3 to 50 carbon atoms, and n is an integer of at least 2.
摘要:
A photoresist polymer having a spiro cyclic ketal group, and a photoresist composition including the same are disclosed. The photoresist polymer and the photoresist composition can improve the resolution and the process margin due to its low activation energy of the deprotection reaction of the spiro cyclic ketal group, and can produce fine photoresist patterns due to its low PEB(Post Exposure Baking) temperature sensitivity.
摘要:
Is disclosed a method for manufacturing fine patterns of semiconductor devices using a double exposure patterning process for manufacturing the second photoresist patterns by simply exposing without an exposure mask. The method comprises the steps of: forming a first photoresist pattern on a semiconductor substrate on which a layer to be etched is formed; coating a composition for a mirror interlayer on the first photoresist pattern to form a mirror interlayer; forming a photoresist layer on the resultant; and forming a second photoresist pattern which is made by a scattered reflection of the mirror-interlayer and positioned between the first photoresist patterns, by exposing the photoresist layer to a light having energy which is lower than a threshold energy (E th ) of the photoresist layer without an exposure mask, and then developing the same.