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1.发明公开SEPARATING AND CONCENTRATING CERTAIN IONS USING ION-BINDING LIGANDS BONDED TO MEMBRANES 失效分离和使用AN结合膜某些离子浓度离子结合配体
公开(公告)号：EP0757589A4
公开(公告)日：1997-11-19
申请号：EP95916458
申请日：1995-04-25
IPC分类号： B01D61/00 , B01D67/00 , B01D69/02 , B01D71/82 , B01J20/32 , B01J39/04 , B01J39/18 , B01J45/00 , C02F1/42 , C08J5/22 , G21F9/04 , B01J49/00 , B32B23/04 , B32B27/00 , B32B27/08 , B32B27/34 , B32B29/00
CPC分类号： B01D67/0093 , B01D2323/30 , B01J20/24 , B01J20/261 , B01J20/262 , B01J20/264 , B01J20/267 , B01J20/28033 , B01J20/28078 , B01J20/28097 , B01J20/321 , B01J20/3212 , B01J20/3217 , B01J20/3219 , B01J20/3251 , B01J20/3282 , B01J45/00 , B01J2220/4825 , G21F9/04 , Y10T428/3154 , Y10T428/31544 , Y10T428/31739 , Y10T428/31913 , Y10T428/31935 , Y10T428/31938 , Y10T428/31971
摘要： A method for removing, separating and concentrating certain selected ions from a source solution that may contain larger concentrations of other ions comprises bringing the source solution in contact with a composition comprising an ion-binding ligand covalently bonded to a membrane having hydrophilic surface properties. The ligand portion of the composition has affinity for and forms a complex with the selected ions, thereby removing them from the source solution. The selected ions are then removed from the composition through contact with a much smaller volume of a receiving solution in which the selected ions are either soluble or which has greater affinity for the selected ions than does the ligand portion of the composition, thereby quantitatively stripping the complexed ions from the ligand and recovering them in concentrated form in the receiving solution. The concentrated ions thus removed may be further separated and recovered by known methods. The process is useful in the removal of selected ions, including noble metals and other transition metals from a variety of source solutions such as are encountered in semicondutor, nuclear waste cleanup, metals refining, environmental cleanup, providing ultra high purity fluids, electric power, and other industrial enterprises. The invention is also drawn to the ligand-membrane compositions.
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2.发明公开POLYAMIDE-CONTAINING LIGANDS COVALENTLY BONDED TO SUPPORTS, POLYAMIDE-CONTAINING RESINS, AND METHODS FOR REMOVING METALS FROM SOLUTIONS 有权聚酰胺遏制和共价键的车辆相关配体容纳有聚酰胺树脂和方法。金属方面从溶液中去除
公开(公告)号：EP1229977A4
公开(公告)日：2003-09-17
申请号：EP00966902
申请日：2000-09-27
IPC分类号： C07D273/08 , B01J45/00 , C02F1/42 , C07C237/08 , C07C237/10 , C07F7/08 , C22B3/42 , C22B11/00 , C22B13/00 , C22B15/00 , C22B17/00 , C22B23/00 , C22B26/20 , B01D15/00
CPC分类号： B01J45/00
摘要： Compositions and methods for selectively binding metal ions from source solutions are disclosed. The compositions include 1) polyamide-containing ligands covalently bonded to a particulate solid support, and 2) polyamide-containing polymeric resins. In the case of the ligand bonded to the solid support, the ligand is bounded or tethered to the solid support through a hydrophilic spacer such that the overall formula is SS-A-X-L. In this formula, SS is a particulate solid support such as silica or a polymeric bead, A is a covalent linkage mechanism, X is a hydrophilic spacer grouping, and L is a polyamide-containing ligand having three or more amide groups and two or more amine nitrogens separated by at least two carbons with the proviso that when SS is a particulate organic polymer, A-X may be combined as a single covalent linkage. With respect to the polyamide ligand-containing polymeric resin, this composition is a reaction product of a hydroxymethylated polyamide ligand and a polymerization and/or crosslinking agent.
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3.发明公开COMPOSITIONS AND METHODS FOR SEPARATING HETEROCYCLIC AROMATIC AMINE BASES, NUCLEOSIDES, NUCLEOTIDES, AND NUCLEOTIDE SEQUENCES 审中-公开用于分离芳香杂环组合物和方法基地阿明，核苷，核苷酸和核苷酸
公开(公告)号：EP1453602A4
公开(公告)日：2005-01-12
申请号：EP02736754
申请日：2002-05-11
发明人： BRUENING RONALD L , KRAKOWIAK KRZYSZTOF E , BRUENING MILTON , HAYMORE BARRY L , DEARDEN DAVID VERNELL
IPC分类号： C12N15/09 , B01J20/22 , C07H1/06 , C07H19/10 , C07H19/20 , C07H21/00 , C07H21/04 , C12N15/10
CPC分类号： C07H21/00 , C12N15/1006
摘要： The compositions of the present invention comprise one or more palladium bound ligands that are covalently bonded to inorganic or organic solid supports. These palladium bound ligands bonded to solid supports can be used for single heterocyclic amine base separation, or can be used to separate nucleotide chain containing specific sequences from other nucleotides or nucleotide chains. In one aspect of the invention, each ligand present is individually complexed to a single Pd(II)ion. If there are from 2 to 4 ligands present in the composition, then each ligand present must be separated from the other ligands by at least 3 atoms, preferably from 3 to 20 carbon atoms or equivalent spacing.
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4.发明公开POLYMERIC MEMBRANES FUNCTIONALIZED WITH POLYHYDROXYPYRIDINONE LIGANDS 审中-公开与POLYHYDROXYPYRIDINONE - 配体官能化的聚合物膜
公开(公告)号：EP1202857A4
公开(公告)日：2003-05-07
申请号：EP00941367
申请日：2000-06-09
IPC分类号： B01D71/82 , B01D67/00 , B01D69/10 , B01D69/12 , B01D71/10 , B01D71/12 , B01D71/16 , B01D71/26 , B01D71/28 , B01D71/30 , B01D71/34 , B01D71/36 , B01D71/40 , B01D71/42 , B01D71/48 , B01D71/50 , B01D71/52 , B01D71/56 , B01D71/60 , B01D71/66 , B01D71/68 , B01J45/00 , C08J7/00 , B32B3/26 , B01D11/00 , B01D63/00
CPC分类号： B01D67/0093 , B01D2323/30 , B01J45/00 , Y10T428/249954 , Y10T428/31544 , Y10T428/31551 , Y10T428/31855 , Y10T428/31938 , Y10T428/8305
摘要： Compositions and methods for selectively binding metal ions from a source solution comprise using a polyhydroxypyridinone-containing ligand covalently bonded to a membrane support having the formula M-A-L(HOPO)n. M is a membrane having a hydrophilic surface, A is a covalent linkage mechanism, L is a ligand carrier, HOPO is a hydroxypyridinone appropriately spaced on the ligand carrier to provide a minimum of six functional coordination metal binding sites, and n is an integer of 3 to 6. The separation is accomplished by passing a source solution containing the ions to be separated through a cartridge containing the membrane-ligand composition, causing the selected ions to be complexed to the HOPO ligands and subsequently removing the selected ions from the cartridge by passing an aqueous receiving solution through the cartridge and quantitatively stripping the selected ions from the HOPO ligand.
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5.发明公开COMPOSITIONS AND METHODS FOR SEPARATING AMINES AND AMINO ACIDS FROM THEIR COUNTER-ENANTIOMERS 审中-公开组合物和方法用于胺的分离和AMINOSûUREN您对对映体
公开(公告)号：EP1539139A4
公开(公告)日：2010-07-28
申请号：EP03756836
申请日：2003-09-17
IPC分类号： G01N30/00 , A61K31/045 , A61K31/40 , B01J20/26 , B01J20/281 , B01J20/283 , B01J20/284 , B01J20/285 , B01J20/291 , B01J20/34 , B01J45/00 , B01J47/02 , C07B57/00 , C07C227/34 , C07C229/08 , C07D323/00 , G01N30/26 , G01N30/88 , C07D498/08
CPC分类号： C07B57/00 , A61K31/045 , A61K31/40 , C07D323/00 , C07D498/08
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公开(公告)号：EP1387763A4
公开(公告)日：2004-06-23
申请号：EP02725732
申请日：2002-04-18
IPC分类号： C02F1/42 , B01D61/00 , B01D67/00 , B01D71/26 , B01J20/28 , B01J20/32 , B01J45/00 , B01J47/12 , B01J49/00 , C01B31/16 , C08J5/22 , B01D69/12
CPC分类号： B01D67/0088 , B01D61/00 , B01D67/0093 , B01D71/26 , B01D2323/30 , B01J20/24 , B01J20/261 , B01J20/262 , B01J20/264 , B01J20/267 , B01J20/28033 , B01J20/28078 , B01J20/28097 , B01J20/321 , B01J20/3212 , B01J20/3217 , B01J20/3219 , B01J20/3251 , B01J20/3282 , B01J20/3293 , B01J45/00 , B01J2220/4825 , Y10T428/31544 , Y10T428/31739 , Y10T428/31913 , Y10T428/31935
摘要： Compositions and methods for selectively binding specific metal ions, such as Ca and C , contained in a source solution are disclosed and described. This is accomplished by the use of a composition comprised of an EGTA ligand covalently bonded to a membrane support. The composition formula of the present invention is M-B-L where M is a membrane having a hydrophilic, partially hydrophilic or a composite membrane with a hydrophilic surface, B is a covalent linkage, and L is an EGTA ligand. The separation is accomplished by passing a source solution containing the ions to be separated through a device containing the membrane-ligand composition, causing the selected ions to be complexed to the EGTA ligands and subsequently removing the selected ions from the device by passing an aqueous receiving solution through the device and quantitatively stripping the selected ions from the EGTA ligand.
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7.发明公开COMPOSITIONS AND METHODS FOR SELECTIVELY BINDING AMINES OR AMINO ACID ENANTIOMERS OVER THEIR COUNTER-ENANTIOMERS 有权组合物和方法用于选择性搭售胺或氨基对映至您的对映体
公开(公告)号：EP1268584A4
公开(公告)日：2003-06-18
申请号：EP01922314
申请日：2001-03-09
IPC分类号： G01N30/00 , B01J20/26 , B01J20/281 , B01J20/283 , B01J20/284 , B01J20/285 , B01J20/291 , B01J20/34 , B01J45/00 , B01J47/02 , C07B57/00 , C07C227/34 , C07C229/08 , C07D323/00 , G01N30/26 , G01N30/88 , C08F112/08 , C08F112/14
CPC分类号： C07D323/00
摘要： Naphthyl crown ether ligand molecules containing at least two naphthyl groups that are covalently bonded to suitable solid supports and coated by hydrophobic organic solvents are disclosed. These compositions and associated methods are characterized by selectivity of desired amine or amino acid enantiomers over their counter-enantiomers and derivatives. The composition preferably has an α-value greater than or equal to 4. This allows for the separation of such enantiomers with nonchromatographic resin bed separations of three separation stages or less.
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8.发明公开POLY N-CYCLIC AROMATIC LIGANDS BONDED TO SOLID SUPPORTS FOR REMOVING AND CONCENTRATING IONS FROM SOLUTIONS 失效附着于固体支持POLY-N-环状芳族配体从溶液中移走及CONCENTRAT离子的
公开(公告)号：EP0958055A4
公开(公告)日：2001-03-14
申请号：EP97934017
申请日：1997-06-24
IPC分类号： B01D15/04 , B01D15/00 , B01D15/08 , B01J20/22 , B01J20/26 , B01J20/32 , B01J45/00 , B01J49/00 , C02F1/42 , C08F8/30
CPC分类号： B01J20/3219 , B01D15/00 , B01J20/286 , B01J20/289 , B01J20/3092 , B01J20/3204 , B01J20/321 , B01J20/3217 , B01J20/3246 , B01J20/3255 , B01J20/3257 , B01J20/3259 , B01J20/3261 , B01J20/3263 , B01J45/00 , B01J2220/54 , B01J2220/58
摘要： A method and composition for the concentration and removal of desired metal ions from a source solution by contacting the solution with an N-cyclic aromatic hydrocarbon-containing ligand covalently bonded to a solid support through a hydrophilic spacer of the formula SS-A-X-(L)n where SS is a solid support, A is covalent linkage mechanism, X is a hydrophilic spacer grouping, L is an N-cyclic aromatic containing ligand group and n is an integer of 1 to 6. X or L combined will not contain more than two amine nitrogen atoms. There will preferably be at least four N-cyclic groups present of which pyridine, pyrimidine, pyrazine, imidazole, quinoline, isoquinoline, naphthyridine, pyridopyridine, phenanthroline are representative. The desired ions in the source solution are bound to the ligands and are subsequently separated by contacting the ligand containing compound with a smaller volume of a receiving solution that removes the bound ions for recovery in concentrated form in the smaller volume of the receiving solution.
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9.发明公开PROCESSES FOR SEPARATING CESIUM FROM INDUSTRIAL STREAMS CONTAINING OTHER ALKALI METALS USING POLY(HYDROXYARYLENE) POLYMERIC RESINS 失效方法用于分离铯工业，其它碱金属含有用聚（hydroxyarylene）聚合物树脂STREAMS
公开(公告)号：EP0789608A4
公开(公告)日：1998-10-21
申请号：EP95939053
申请日：1995-11-02
IPC分类号： B01D15/00 , B01J20/32 , B01J39/04 , B01J39/18 , B01J45/00 , C01D17/00 , C08G8/04 , C08G8/10 , C08G8/12 , C08G8/20 , C08G14/02 , C08G14/04 , C22B3/26 , C22B26/10 , G21F9/12 , B01J39/00
CPC分类号： G21F9/12 , B01D15/00 , B01J45/00 , C22B3/0097 , C22B26/10 , Y02P10/234
摘要： A method for the removal, separation, and concentration of cesium cations from a source solution which may contain larger concentrations of other alkali metal ions comprises bringing the source solution into contact with a polymeric resin containing poly(hydroxyarylene) ligands. The process is useful in the removal of cesium cations from a variety of source solutions such as from semiconductor, nuclear waste cleanup, metals refining, electric power, and other industrial enterprises. The invention is also drawn to the poly(hydroxyarylene)-ligand-containing polymeric resins.
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公开(公告)号：EP0701630A4
公开(公告)日：1997-03-19
申请号：EP94916047
申请日：1994-05-06
IPC分类号： B01D15/00 , B01J20/26 , C01G55/00 , C07D327/00 , C07F7/08 , C09K3/00 , C22B3/26 , C22B13/00 , C22B26/00 , C22B26/10 , C22B26/20 , C22B61/00 , C07D321/00 , C07D323/00 , C07D325/00 , C07D407/04
CPC分类号： C22B13/04 , C22B3/42 , C22B26/00 , C22B61/00 , Y02P10/234
摘要： A method for the removal, separation, and concentration of alkali metal, alkaline earth metal, Pb and/or Tl cations from a source solution which may contain larger concentrations of other ions which comprises bringing the source solution into contact with a compound comprising an oxygen donor macrocycle-containing ligand covalently bonded through an organic spacer silicon grouping to a solid inorganic support.
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