摘要:
A method for transferring microstructures, comprising at least the steps of: (i) bonding a plurality of microstructures formed on one surface of a supplier substrate to a silicone-based rubber layer formed on a donor substrate; (ii) separating some or all of the plurality of microstructures from the supplier substrate and transferring the some or all of the plurality of microstructures to the donor substrate through the silicone-based rubber layer to produce the donor substrate having the plurality of microstructures temporality fixed thereon; (iii) washing or neutralizing the donor substrate having the plurality of microstructures temporality fixed thereon; (iv) drying the washed or neutralized donor substrate having the plurality of microstructures temporality fixed thereon; and (v) transferring the dried donor substrate having the plurality of microstructures temporality fixed thereof so that the donor substrate can be subjected to a subsequent step. According to the method, a plurality of steps can be carried out while temporality fixing microstructures on a single donor substrate, and therefore it becomes possible to achieve the transfer of the microstructures with high efficiency without increasing the number of steps.
摘要:
A composition comprising: (A) an organopolysiloxane having, in the molecule, two groups represented by formula (1)
(R 1 represents a C 1-20 monovalent hydrocarbon group, R 2 represents an oxygen atom, etc., R 3 represents an acryloyloxyalkyl group, etc., p is a number of 0-10, and a is a number of 1-3.); (B) a monofunctional (meth)acrylate compound containing no siloxane structure; (C) an organopolysiloxane resin comprising (a) R 4 3 SiO 1/2 units (R 4 is a C 1-10 monovalent hydrocarbon group) and (b) SiO 4/2 units, the molar ratio of the units (a) to the units (b) being (0.4-1.2): 1; (D) an organopolysiloxane resin comprising (c) units represented by formula (2)
(R 1 to R 3 , a, and p are the same as defined above), (d) R 4 3 SiO 1/2 units (R 4 is the same as defined above), and (e) SiO 4/2 units, the molar ratio of the sum of the units (c) and the units (d) to the units (e) being (0.4-1.2):1; and (E) a photopolymerization initiator. The composition gives cured objects which, when used as temporary fixers, are excellent in terms of tackiness and modulus.
摘要:
The present invention is a microstructure-transfer stamp component including a substrate and a silicone-based rubber film formed on the substrate, wherein a surface of the silicone-based rubber film facing away from the substrate has one or more recesses each being closed except for a surface opening. This provides a microstructure-transfer stamp component that can optimize temporary adhesive strength of the surface of the silicone-based rubber film stamp in a short period of time.
摘要:
An addition-curing silicone pressure-sensitive adhesive composition which contains no noncrosslinking organopolysiloxane resin and comprises 100 parts by mass of (A) an organopolysiloxane having, in the molecule, at least two alkenyl groups which combine with silicon atoms and having a 25°C viscosity of 0.01-1,000 Pa·s, 5-500 parts by mass of (B) an organopolysiloxane resin having an alkenyl group, (C) an organohydrogenpolysiloxane having, in the molecule, two or more silicon-atom-bonded hydrogen atoms, the amount of (C) being such that the amount of the silicon-atom-bonded hydrogen atoms contained in the (C) component is 0.1-5.0 times by mole the total amount of all the silicon-atom-bonded alkenyl groups contained in the composition, and (D) a catalyst based on a platinum-group metal. The addition-curing silicone pressure-sensitive adhesive composition has excellent tackiness as a temporary fixer and gives cured objects with very little component migration.
摘要:
Provided is an oxygen-curable silicone composition that cures at room temperature, the reaction being triggered by oxygen in the atmosphere, without requiring heat or UV irradiation at the time of use, and exhibits good mechanical strength after curing. A composition including (A) an organopolysiloxane (1)
(R 1 represents an alkyl group or the like but has at least one acryloyloxy group or the like in the molecule, R 2 represents an oxygen atom or the like, and m and n represent numbers that satisfy 1 ≤ m + n ≤ 1,000.), (B) a silicone resin including (a) a unit of formula (2), (b) an R 1 3 SiO 1/2 unit, and (c) an SiO 4/2 unit, the molar ratio of [(a) + (b)]/(c) being 0.4-1.2, and the silicone resin having 0.005 mol/100 g or more Si-OH groups
(R 1 and R 2 are the same as above. R 3 represents an acryloyloxyalkyl group or the like, p represents 0-10, and 1 represents a number that satisfies 1-3.), and (C) an organoborane complex (3)
摘要:
Provided are an excellently convenient ultraviolet-curable organopolysiloxane causing no surface curing inhibition even when cured in the atmosphere; a composition containing such organopolysiloxane; and a cured product of such composition. The organopolysiloxane is represented by the following formula (1):
wherein each R 1 independently represents a monovalent hydrocarbon group having 1 to 10 carbon atoms or a group represented by the following formula (2), each molecule has at least one group represented by the following formula (2), m is a number satisfying 1≤m≤10,000,
wherein R 2 represents a group having at least one of an acryloyl group, methacryloyl group, acryloyloxyalkyl group or methacryloyloxyalkyl group, R 3 represents a divalent hydrocarbon group having 1 to 20 carbon atoms.
摘要:
This composition does not contain a non-crosslinkable organopolysiloxane resin but contains:(A) an organopolysiloxane having, per molecule, two groups each represented by formula (1) (R1 represents a C1-20 monovalent hydrocarbon group, R2 represents an oxygen atom or the like, R3 represents an acryloyloxyalkyl group or the like, and p and a respectively represent numbers satisfying 0-10 and 1-3);(B) a monofunctional(meth)acrylate compound not including a siloxane structure;(C) an organopolysiloxane resin which comprises a unit (a) represented by formula (2)(R1, R2, R3, a, and p are identical to those described above), a R43SiO1/2 unit (b) (in the formula, R4 represents a monovalent hydrocarbon group having 1-10 carbon atoms), and a SiO4/2 unit (c), and in which the mole ratio of the total of units (a) and (b) to unit (c) is in a range of 0.4 to 1.2 : 1; and(D) a photoinitiator.Said composition provides a cured product having excellent elastic modulus and adhesiveness when used as a temporary fixing material.
摘要:
A UV curable silicone composition comprises: (A) 100 parts by mass of an organopolysiloxane represented by formula (1) wherein n represents a number satisfying 1 ‰¤ n ‰¤ 100, Ar represents an aromatic group, each of F 1 and F 2 is selected from groups of formulae (2) and (3), and a ratio of the number of terminal groups of the formula (3) to a total number of all the terminal groups is not lower than 20%, wherein each R 1 represents a monovalent hydrocarbon group having 1 to 20 carbon atoms, wherein m represents a number satisfying 0 ‰¤ m ‰¤ 10, each R 1 represents a monovalent hydrocarbon group having 1 to 20 carbon atoms, R 2 represents an oxygen atom or an alkylene group, and R 3 represents an acryloyl group, a methacryloyl group, an acryloyloxyalkyl group or a methacryloyloxyalkyl group; and (B) 0.1 to 10 parts by mass of a photopolymerization initiator.
摘要:
The present invention is directed to an addition curable type silicone resin composition which comprises (a) an organopolysiloxane having an alkenyl group bonded to a silicon atom, (b) an organopolysiloxane represented by the formula, (R 1 R 2 2 SiO 1/2 ) m (R 1 R 2 SiO 2/2 ) n (R 2 2 SiO 2/2 ) p (R 1 SiO 3/2 ) q (R 2 (OR 3 )SiO 2/2 ) r (S iO 4/2 ) s , (c) an organohydrogen polysiloxane represented by R 4 a H b SiO (4-a-b)/2 , (d) a platinum group metal catalyst, and (e) a polyorganometallosiloxane containing an Si-O-Ce bond, and an Si-O-Ti bond, and contents of Ce and Ti of which are each 50 to 5,000 ppm, which cures by heating. According to this constitution, it is provided an addition curable type silicone resin composition which can provide a cured product excellent in transparency, and less change in hardness and weight loss under high temperature conditions.
摘要:
A UV curable silicone composition comprises: (A) 100 parts by mass of an organopolysiloxane represented by formula (1)
wherein n represents a number satisfying 1 ≤ n ≤ 100, Ar represents an aromatic group, each of F 1 and F 2 is selected from groups of formulae (2) and (3), and a ratio of the number of terminal groups of the formula (3) to a total number of all the terminal groups is not lower than 20%,
wherein each R 1 represents a monovalent hydrocarbon group having 1 to 20 carbon atoms,
wherein m represents a number satisfying 0 ≤ m ≤ 10, each R 1 represents a monovalent hydrocarbon group having 1 to 20 carbon atoms, R 2 represents an oxygen atom or an alkylene group, and R 3 represents an acryloyl group, a methacryloyl group, an acryloyloxyalkyl group or a methacryloyloxyalkyl group; and (B) 0.1 to 10 parts by mass of a photopolymerization initiator.