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    Binuclear metal complex and use thereof
    3.
    发明专利
    Binuclear metal complex and use thereof 审中-公开
    金属复合物及其用途

    公开(公告)号：JP2008169203A

    公开(公告)日：2008-07-24

    申请号：JP2007319331

    申请日：2007-12-11

    申请人： Sumitomo Chemical Co Ltd ,  住友化学株式会社

    发明人： KOSHINO NOBUYOSHI ,  MATSUNAGA TADASHI ,  HIGASHIMURA HIDEYUKI

    IPC分类号： C07D257/10 ,  B01J31/22 ,  C07F15/06

    摘要： PROBLEM TO BE SOLVED: To provide a binuclear metal complex which hardly loses its catalytic activity even in the presence of a strong acid or at an elevated temperature and is useful as a redox reaction catalyst etc.
    SOLUTION: The binuclear metal complex is synthesized by the reaction formulas shown in the figure or the like. The binuclear metal complex is excellent in heat resistance and acid resistance. Since the deterioration of the catalytic activity of the binuclear metal complex is suppressed, even in the presence of a strong acid or at an elevated temperature, it is capable of serving as a catalyst with a wide application and is thus commercially useful.
    COPYRIGHT: (C)2008,JPO&INPIT

    摘要翻译： 要解决的问题：提供即使在强酸存在下或在高温下也几乎不会失去催化活性的双核金属络​​合物，并且可用作氧化还原反应催化剂等。解决方案：双核 金属络合物通过图中所示的反应式等合成。 双核金属络​​合物的耐热性和耐酸性优异。 由于双核金属络​​合物的催化活性的劣化被抑制，即使在强酸或高温的存在下，也能够作为具有广泛应用的催化剂，因此在商业上是有用的。 版权所有（C）2008，JPO＆INPIT

    Ionophore comprising azaannulene derivative, sensitive membrane and ion sensor using the same
    5.
    发明专利
    Ionophore comprising azaannulene derivative, sensitive membrane and ion sensor using the same 有权
    包含AZAANNULENE衍生，敏感膜和离子传感器的IONOPHORE

    公开(公告)号：JP2003327579A

    公开(公告)日：2003-11-19

    申请号：JP2002134654

    申请日：2002-05-09

    申请人： Japan Science & Technology Corp ,  科学技術振興事業団

    发明人： MORIUCHI TAKAYO ,  SHIBUYA YASUHIKO ,  TSUJINAKA TOSHIKI

    IPC分类号： G01N27/333 ,  C07D257/10 ,  G01N27/414

    摘要： PROBLEM TO BE SOLVED: To obtain an ionophore having high sensitivity to a transition metal ion and an ion sensor and an ion-exchange membrane containing the same. SOLUTION: The ionophore for the transition metal ion comprises a [14] azaannulene derivative represented by formula (I) (R 1 to R 4 are the same or different and are each a hydrogen atom or an alkyl group; R 5 and R 6 are the same or different and are each a hydrogen atom, a halogen atom, a carbonyl group, an azo group or an alkyl group containing an electronegative substituent group; R 2 and R 5 , R 4 and R 6 or R 5 and R 6 may be connected by an alkylene chain which may contain a substituent group; R a to R d are the same or different and are each a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or a carbonyl group; R a and R b and R c and R d may be connected by an alkylene group which may contain a substituent group). COPYRIGHT: (C)2004,JPO

    摘要翻译： 要解决的问题：获得对过渡金属离子和离子传感器以及含有过渡金属离子的离子交换膜具有高灵敏度的离子载体。 解决方案：用于过渡金属离子的离子载体包含由式（I）表示的[14]氮杂芸香烯衍生物（R 1 至R 4 相同或不同 并且各自为氢原子或烷基; R 5和R 6相同或不同，各自为氢原子，卤素原子，羰基， 偶氮基团或含有电负性取代基的烷基; R 2和R 5共和R 4，R 6， SP>或R 5 和R 6可以通过可以含有取代基的亚烷基链连接; R a 至R d 相同或不同，各自为氢原子，卤素原子，烷基，烷氧基或羰基; R“SP”和“R” SP＆gt;和R＆lt; SP＆gt; c＆lt; SP＆gt;和R＆lt; SP＆gt; d＆lt; / SP＆gt;可以通过可以含有取代基的亚烷基连接）。 版权所有（C）2004，JPO

    Novel tetraazaannulene-cobalt complex
    9.
    发明专利
    Novel tetraazaannulene-cobalt complex 失效
    新型四氯化碳 - 钴复合物

    公开(公告)号：JPS58222075A

    公开(公告)日：1983-12-23

    申请号：JP10567982

    申请日：1982-06-19

    申请人： Asahi Chem Ind Co Ltd

    发明人： AKASHI HIROYASU ,  SUGA NOBUHIKO

    IPC分类号： C07D257/10 ,  B01J31/00 ,  B01J31/22 ,  H01M4/90

    CPC分类号： Y02E60/50

    摘要： NEW MATERIAL:The tetraazaannulene.cobalt complex of formula (c) (R
    1 WR
    3 are H or 1W8C alkoxy, provided that at least one of R
    1 WR
    3 is 5W8C alkoxy).
    USE: An oxygen reducing catalyst having long catalytic life and improved activity, and useful as a catalyst substituting for the platinum catalyst having problems of cost and resources.
    PROCESS: The compound of formula (c) can be prepared by reacting the compound of formula (a) with cobalt acetate and the compound of formula (b) in dimethylformamide in argon gas stream under heat refluxing.
    COPYRIGHT: (C)1983,JPO&Japio

    摘要翻译： 新材料：式（c）的四氮杂萘（c）配合物（R1-R3为H或1-8C烷氧基，条件是R1-R3中的至少一个为5-8个烷氧基）。 用途：具有长的催化寿命和活性提高的氧还原催化剂，可用作代替具有成本和资源问题的铂催化剂的催化剂。 方法：式（c）化合物可以通过在热回流下在氩气流中使式（a）化合物与乙酸钴和式（b）化合物在二甲基甲酰胺中反应来制备。

    Novel cobalt complex of tetraazaannulene
    10.
    发明专利
    Novel cobalt complex of tetraazaannulene 失效
    四氯化碳的新型钴复合物

    公开(公告)号：JPS58219168A

    公开(公告)日：1983-12-20

    申请号：JP10254382

    申请日：1982-06-15

    申请人： Asahi Chem Ind Co Ltd

    发明人： AKASHI HIROYASU ,  SUGA NOBUHIKO

    IPC分类号： C07D257/10 ,  B01J31/00 ,  B01J31/22 ,  C07F15/06

    摘要： NEW MATERIAL:A cobalt complex of tetraazaannulene shown by the formula I (R
    1 is 1W8C alkyl; R
    2 and R
    3 are H, or 1W8C alkoxy; excluding such case that R
    1 is CH
    3 , R
    2 and R
    3 are H).
    EXAMPLE: A compound shown by the formula II.
    USE: A catalyst for reducing oxygen. Having long catalytic life and improved catalytic activity.
    PROCESS: A compound shown by the formula III is reacted with cobalt acetate shown by the formula IV and a compound shown by the formula V in dimethylformamide solvent in argon flow for 5hr by heating under reflux, to give a compound shown by the formula I .
    COPYRIGHT: (C)1983,JPO&Japio

    摘要翻译： 新材料：由式I表示的四氮杂萘的钴络合物（R1为1-8C烷基; R2和R3为H或1-8C烷氧基，不包括R1为CH3，R2和R3为H的情况）。 实施例：由式II表示的化合物。 用途：减少氧气的催化剂。 催化寿命长，催化活性好。 方法：将通式Ⅳ所示的化合物与式Ⅳ所示的乙酸钴和式Ⅴ所示的化合物在二甲基甲酰胺溶剂中在氩气流下加热回流5小时，得到式Ⅰ所示的化合物。