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公开(公告)号：US06313234B1
公开(公告)日：2001-11-06
申请号：US08469171
申请日：1995-06-06
申请人： Andreas Kaplan , Manfred Hoppe , Eberhard Kinkelin
发明人： Andreas Kaplan , Manfred Hoppe , Eberhard Kinkelin
IPC分类号： C08F2000
CPC分类号： C09D167/02 , Y10S525/934 , C08L2666/36 , C08L63/00
摘要： A heat settable, coating system of carboxyl-functional polyester resins, polyfunctional epoxy compounds and/or &bgr;-hydroxy alkyl amides, as well as further customary additives, if required. The coating system contains at least one linear carboxyl-functional polyester resin of up to 10 mol-part of isophthalic acid and at least 90 mol-parts of at least a further dicarboxylic acid from the group of aromatic dicarboxylic acids with 8 to 16 C-atoms, aliphatic dicarboxylic acids with 6 to 22 C-atoms and cycloaliphatic dicarboxylic acids with 8 to 16 C-atoms, and at least 90 mol-parts of at least one branched aliphatic diol with 4 to 12 C-atoms, and up to 50 mol-parts of at least one linear aliphatic diol with 2 to 22 C-atoms and/or at least one cycloaliphatic diol with 6 to 16 C-atoms as the binder resin. Also a process for producing thermosetting coating systems of carboxyl-functional polyester resins, wherein binder resin, at least one cross-linking agent from the group of polyfunctional epoxy compounds and &bgr;-hydroxy alkyl amides and, if required, further customary additives are mixed into the melt at 90 to 130° C., extruded, removed, granulated, comminuted and screened to a size of less than 100 &mgr;m. Finally, uses of the thermosetting coating system and of a protective layer produced from this coating system.
摘要翻译： 羧基官能聚酯树脂的热固化涂料体系，多官能环氧化合物和/或β-羟基烷基酰胺，以及如果需要的其它常规添加剂。 该涂料体系含有至多一种至多10摩尔间苯二甲酸的直链羧基官能聚酯树脂和至少90摩尔份的至少一种另外的二羧酸，该芳族二羧酸与8至16 C- 具有6至22个碳原子的脂族二羧酸和具有8至16个C原子的脂环族二羧酸，以及至少90摩尔份至少一种具有4至12个碳原子的支链脂肪族二醇和至多50个 至少一个具有2至22个碳原子的直链脂族二醇的摩尔份数和/或至少一种具有6至16个碳原子的脂环族二醇作为粘合剂树脂。 还有一种制备羧基官能聚酯树脂的热固性涂料体系的方法，其中粘合剂树脂，至少一种多官能环氧化合物和β-羟基烷基酰胺的交联剂，以及如果需要，将其它常规添加剂混合 将熔体在90〜130℃下挤出，除去，造粒，粉碎并筛分至小于100μm的尺寸。 最后，使用热固性涂层系统和由该涂层系统制成的保护层。
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公开(公告)号：US06590063B2
公开(公告)日：2003-07-08
申请号：US09852218
申请日：2001-05-09
IPC分类号： C08G6902
CPC分类号： C09J177/06 , C08G69/02 , C08G69/36 , C09J177/00 , D01F6/80 , Y10S526/935 , Y10T428/29 , Y10T428/2964 , Y10T428/2967 , Y10T428/2969 , Y10T428/31725
摘要： Copolyamides, consisting of polycondensation products of the following components: caprolactam 10 to 45 mol-%, laurolactam 30 to 55 mol-%, at least 2 dicarboxylic acids 20 to 50 mol-% of the following compounds, aliphatic &agr;,&ohgr;-dicarboxylic acids with 6 up to 14 C atoms inclusively, terephthalic acid, isophthalic acid and 2,6-naphthalene dicarboxylic acid, wherein the content of aromatic dicarboxylic acids is lower than 10 mol-%, with reference to the allover amount of the above-mentioned components, which add up to 100 mol-%, a diamine mixture in an amount that is equimolar to that of the dicarboxylic acids, chosen from the group of the following substances, hexamethylene diamine, piperazine and/or 2-methyl-1,5-diaminopentane, wherein the molar content of hexa-methylene diamine is between 75 and 95 mol-% with reference to the diamine mixture. The copolyamides according to the invention are used for the production of mono- and multifilaments, fibers, films and nets.
摘要翻译： 由以下组分的缩聚产物组成的共聚酰胺：己内酰胺10至45mol％，月桂内酰胺30至55mol％，至少2个二羧酸20至50mol％的以下化合物，脂族α，ω-二羧酸 包括6至14个C原子，对苯二甲酸，间苯二甲酸和2,6-萘二甲酸，其中芳族二羧酸的含量低于10摩尔％，相对于上述组分的总量 ，其加入量为100摩尔％，二胺混合物的量等于与二羧酸等摩尔量的二胺混合物，其选自下列物质：六亚甲基二胺，哌嗪和/或2-甲基-1,5- 二氨基戊烷，其中六亚甲基二胺的摩尔含量相对于二胺混合物为75至95摩尔％。根据本发明的共聚酰胺用于生产单丝和复丝，纤维，膜和网。
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3.发明授权Amorphous and/or semicrystalline copolyesters containing .beta.-hydroxyalkylamide groups, method for their manufacture, and utilisation of the esters 失效含有β-羟基烷基酰胺基团的无定形和/或半结晶共聚酯，其制造方法和酯的利用
公开(公告)号：US5889126A
公开(公告)日：1999-03-30
申请号：US891574
申请日：1997-07-11
申请人： Andreas Kaplan , Rene Gisler , Eberhard Kinkelin
发明人： Andreas Kaplan , Rene Gisler , Eberhard Kinkelin
IPC分类号： C08G63/685 , C08G63/91 , C09D5/03 , C09D167/00 , C08F20/00
CPC分类号： C08G63/914 , C08G63/6854 , C09D167/00
摘要： The invention relates to Amorphous and/or semicrystalline copolyesters containing .beta.-hydroxyalkylamide groups according to formula (I) ##STR1## whereinP=polymer chain of the polyesterR1=alkyl residues with 1-5 atoms or hydrogen or ##STR2## R2=alkyl residues with 1-5 C-atoms or hydrogen, R3=alkyl residues and 1-5 C-atoms or hydrogen, andn.gtoreq.2,with a molecular weight (Mn) of 300 to 15,000 and a hydroxyl value of 10 to 400 �mg KOH/g!.
摘要翻译： 本发明涉及含有根据式（I）的β-羟基烷基酰胺基团的无定形和/或半结晶共聚酯，其中P =聚酯的聚合物链R1 =具有1-5个或更多个氢原子或R2的烷基残基 = 1-5个C原子或氢的烷基，R3 =烷基残基和1-5个C原子或氢，n> = = 2，分子量（Mn）为300〜15,000，羟值为 10〜400 [mg KOH / g]。
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公开(公告)号：US20110052927A1
公开(公告)日：2011-03-03
申请号：US12921646
申请日：2009-03-12
申请人： Raffaele Martinoni , Paul Boehler , Paul Stenson , Jurgen Spindler , Eberhard Kinkelin , Gerhard Possnecker
发明人： Raffaele Martinoni , Paul Boehler , Paul Stenson , Jurgen Spindler , Eberhard Kinkelin , Gerhard Possnecker
CPC分类号： C08G69/16 , B29C64/153 , B29K2077/00 , B33Y10/00 , B33Y70/00 , C08G69/08 , C08G69/14 , C08J3/12 , C08J2377/02 , C08K3/36 , C08L77/02 , Y10T428/31728
摘要： Powder compositions and articles and methods of forming articles from powder compositions are provided. The powder compositions include at least one powder that preferably includes an amount of one or more branched polymers such as, for example, one or more branched polyamide polymers. The powder composition is preferably capable of being formed, via a layer-by-layer sintering process such as, for example, selective laser sintering, into a three-dimensional article.
摘要翻译： 提供了粉末组合物和由粉末组合物制备制品的制品和方法。 粉末组合物包括至少一种粉末，其优选包括一定量的一种或多种支化聚合物，例如一种或多种支化聚酰胺聚合物。 粉末组合物优选能够通过逐层烧结工艺（例如选择性激光烧结）形成三维制品。
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公开(公告)号：US06255443B1
公开(公告)日：2001-07-03
申请号：US09352998
申请日：1999-07-13
IPC分类号： C08G6302
CPC分类号： C09J167/02 , C08G63/16
摘要： Novel, quick-crystallizing hot-melt adhesive masses having a melting point between 60° and 100° C. comprise a statistically-proportioned copolyester or copolyetherester based on terephthalic acid, adipic acid and a mixture of aliphatic diols; the molar proportion of terephthalic acid is between 55 and 85 mole %, relative to the total acid quantity; and the molar proportion of adipic acid is between 15 and 40 mole %. A combination of butane diol and hexane diol is used as the diol component; the molar component of butane diol is between 40 and 55 mole %; and the molar proportion of hexane diol is between 40 and 60 mole %. Up to 15 mole % of a dimer acid having a molar mass between 400 and 800 g/mole, or up to 10 mole % of a higher-molecular polyethylene glycol having a molecular mass of 600 to 4000 g/mole, can be used to increase the flexibility. The copolyester or copolyetherester hot-melt adhesive masses of the invention can be used in the hot-melt method, and in powder-form coating methods.
摘要翻译： 具有熔点在60-100℃之间的新型快速结晶热熔粘合剂组合物包含基于对苯二甲酸，己二酸和脂族二醇的混合物的统计学比例的共聚酯或共聚醚酯; 相对于总酸量，对苯二甲酸的摩尔比例为55-85摩尔％ 己二酸的摩尔比例为15〜40摩尔％。 丁二醇和己二醇的组合用作二醇组分; 丁二醇的摩尔成分为40〜55摩尔％。 己二醇的摩尔比例为40〜60摩尔％。 高达15摩尔％的摩尔质量为400至800克/摩尔或高达10摩尔％的分子量为600至4000克/摩尔的高分子量聚乙二醇的二聚酸可用于 增加灵活性。 本发明的共聚聚酯或共聚醚酯热熔粘合剂可用于热熔融方法，粉末形式的涂布方法
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公开(公告)号：US5869594A
公开(公告)日：1999-02-09
申请号：US909977
申请日：1997-08-12
IPC分类号： C08G63/672 , C09D5/46 , C09J5/06 , C09J167/02 , C08G63/66
CPC分类号： C08G63/672 , C09J167/025
摘要： The invention relates to novel hot-melt masses consisting of a statistically built-up copolyether ester based on terephthalic acid and a mixture of aliphatic diols. Terephthalic acid is used as the single acid component and its molar amount, relative to the total amount of acid, is 100 molar %. A combination of butane diol, diethylene glycol, polyethylene and optionally triethylene glycol is present as diol component. The molar amount of butane diol is less than 75 molar %, the amount of diethylene glycol is between 5 and 60 molar %, the amount of triethylene glycol between 0 and 40 molar % and at least 2 and at the most 10 molar % of a higher-molecular polyethylene glycol component with a molar mass of 600-4000 g/mole is used, relative to the total acid amount and total diol amount of 100 molar % in each instance. The melting point of the copolyether ester adhesive masses is between 90.degree. and 190.degree. C.The copolyetherester hot-melt masses can be used in the hot-melt method and for the known other powder coating methods.
摘要翻译： 本发明涉及由统计学上构建的基于对苯二甲酸的共聚醚酯和脂族二醇的混合物组成的热熔体。 使用对苯二甲酸作为单一酸成分，相对于酸的总量，其摩尔量为100摩尔％。 丁二醇，二甘醇，聚乙烯和任选的三甘醇的组合作为二醇组分存在。 丁二醇的摩尔量小于75摩尔％，二甘醇的量为5至60摩尔％，三甘醇的量为0至40摩尔％，至少2和至多10摩尔％ 使用摩尔质量为600-4000g / mol的高分子量聚乙二醇组分，相对于总酸量和总二醇量为100摩尔％。 共聚醚酯粘合剂的熔点在90°和190℃之间。共聚醚酯热熔体可用于热熔法和已知的其它粉末涂覆方法。
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公开(公告)号：US09611355B2
公开(公告)日：2017-04-04
申请号：US12921646
申请日：2009-03-12
申请人： Raffaele Martinoni , Paul Boehler , Paul Stenson , Jürgen Spindler , Eberhard Kinkelin , Gerhard Pössnecker
发明人： Raffaele Martinoni , Paul Boehler , Paul Stenson , Jürgen Spindler , Eberhard Kinkelin , Gerhard Pössnecker
CPC分类号： C08G69/16 , B29C64/153 , B29K2077/00 , B33Y10/00 , B33Y70/00 , C08G69/08 , C08G69/14 , C08J3/12 , C08J2377/02 , C08K3/36 , C08L77/02 , Y10T428/31728
摘要： Powder compositions and articles and methods of forming articles from powder compositions are provided. The powder compositions include at least one powder that preferably includes an amount of one or more branched polymers such as, for example, one or more branched polyamide polymers. The powder composition is preferably capable of being formed, via a layer-by-layer sintering process such as, for example, selective laser sintering, into a three-dimensional article.
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8.发明授权公开(公告)号：US08956986B2
公开(公告)日：2015-02-17
申请号：US12928732
申请日：2010-12-17
申请人： Klaus Bender , Gunther Schäch , Eberhard Kinkelin
发明人： Klaus Bender , Gunther Schäch , Eberhard Kinkelin
CPC分类号： C08G69/36 , C08L77/02 , C09J177/02 , D01F6/80 , D04H1/52 , Y10T428/2915 , Y10T428/2929 , Y10T428/2931 , Y10T428/2969 , Y10T428/298 , Y10T442/608 , Y10T442/609 , Y10T442/61 , Y10T442/611 , Y10T442/627 , C08L2666/02
摘要： A binding fiber having, as at least one first thermoplastic component, a copolyamide which has a relative viscosity of at least 1.50 (measured at 0.5% in m-cresol at 25° C.), a MVR of maximum 20 cm3/10 min at 190° C. and 2.16 kg load, a hydrophobicity of less than 7.2, a melting temperature lower than 105° C. in the water saturated condition and a higher melting temperature in the dry condition. The binding fiber can, on the one hand, be activated with hot steam at approximately ambient pressure during the manufacture of flat materials containing natural fibers, such as paper, cardboard, wood fiber boards, or fiber mats. The finished flat material can, on the other hand, be subjected to higher temperatures, and the copolyamide develops good bonding with respect to the cellulose fibers normally used in the indicated flat materials.
摘要翻译： 作为至少一种第一热塑性成分的结合纤维，其具有至少1.50的相对粘度（在间甲酚中在25℃下以0.5％测定）的共聚酰胺，最大20cm 3/10分钟的MVR为 190℃和2.16kg负荷，疏水性小于7.2，熔融温度低于105℃，在饱和水饱和条件下和较高的熔融温度在干燥条件下。 一方面，在制造含有天然纤维的平面材料（例如纸，纸板，木纤维板或纤维垫）的过程中，粘合纤维一方面可以在大气压下用热蒸汽活化。 另一方面，成品扁平材料可以经历更高的温度，并且共聚酰胺相对于通常用于所示扁平材料的纤维素纤维发展良好的粘结。
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9.发明申请公开(公告)号：US20110146907A1
公开(公告)日：2011-06-23
申请号：US12928732
申请日：2010-12-17
申请人： Klaus Bender , Gunther Schäch , Eberhard Kinkelin
发明人： Klaus Bender , Gunther Schäch , Eberhard Kinkelin
IPC分类号： D02G3/22 , D02G3/02 , C09J177/06 , C09J5/02
CPC分类号： C08G69/36 , C08L77/02 , C09J177/02 , D01F6/80 , D04H1/52 , Y10T428/2915 , Y10T428/2929 , Y10T428/2931 , Y10T428/2969 , Y10T428/298 , Y10T442/608 , Y10T442/609 , Y10T442/61 , Y10T442/611 , Y10T442/627 , C08L2666/02
摘要： A binding fiber having, as at least one first thermoplastic component, a copolyamide which has a relative viscosity of at least 1.50 (measured at 0.5% in m-cresol at 25° C.), a MVR of maximum 20 cm3/10 min at 190° C. and 2.16 kg load, a hydrophobicity of less than 7.2, a melting temperature lower than 105° C. in the water saturated condition and a higher melting temperature in the dry condition. The binding fiber can, on the one hand, be activated with hot steam at approximately ambient pressure during the manufacture of flat materials containing natural fibers, such as paper, cardboard, wood fiber boards, or fiber mats. The finished flat material can, on the other hand, be subjected to higher temperatures, and the copolyamide develops good bonding with respect to the cellulose fibers normally used in the indicated flat materials.
摘要翻译： 作为至少一种第一热塑性成分的结合纤维，其具有至少1.50的相对粘度（在间甲酚中在25℃下以0.5％测定）的共聚酰胺，最大20cm 3/10分钟的MVR为 190℃和2.16kg负荷，疏水性小于7.2，熔融温度低于105℃，在饱和水饱和条件下和较高的熔融温度在干燥条件下。 一方面，在制造含有天然纤维的平面材料（例如纸，纸板，木纤维板或纤维垫）的过程中，粘结纤维一方面可以在大气压下用热蒸汽活化。 另一方面，成品扁平材料可以经历更高的温度，并且共聚酰胺相对于通常用于所示扁平材料的纤维素纤维发展良好的粘结。
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公开(公告)号：US5767226A
公开(公告)日：1998-06-16
申请号：US909586
申请日：1997-08-12
IPC分类号： C08G63/672 , C09D5/46 , C09J5/06 , C09J167/02 , C08G63/16
CPC分类号： C08G63/672 , C09J167/025
摘要： The invention relates to novel hot-melt masses consisting of a statistically built-up copolyether ester based on terephthalic acid in a mixture of aliphatic diols. Terephthalic acid is used as the single acid component and its molar amount, relative to the total amount of acid, is 100 molar %. A combination of butane diol, triethylene glycol and polyethylene glycol is present as diol component. The molar amount of butane diol is less than 80 molar %, the amount of triethylene glycol is between 15 and 60 molar % and at least 2 and at the most 10 molar % of a higher-molecular polyethylene glycol component with a molar mass of 600-4000 g/mole is used, relative to the total acid amount and total diol amount of 100 molar % in each instance. The melting point of the copolyether ester adhesive masses is between 90.degree. and 180.degree. C. The copolyetherester hot-melt masses can be used in the hot-melt method and for other known powder coating methods.
摘要翻译： 本发明涉及由在脂肪族二醇的混合物中基于对苯二甲酸的统计建立的共聚醚酯组成的新型热熔体。 使用对苯二甲酸作为单一酸成分，相对于酸的总量，其摩尔量为100摩尔％。 丁二醇，三甘醇和聚乙二醇的组合作为二醇组分存在。 丁二醇的摩尔量小于80摩尔％，三甘醇的量为摩尔质量为600的高分子量聚乙二醇组分的15至60摩尔％至少2摩尔％且至多10摩尔％ 使用-4000g / mol，相对于总酸量和总二醇量为100摩尔％。 共聚醚酯粘合剂的熔点在90℃和180℃之间。共聚醚酯加热熔体可用于热熔法和其它已知的粉末涂覆方法中。
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