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公开(公告)号：US4828806A
公开(公告)日：1989-05-09
申请号：US127609
申请日：1987-11-30
Applicant: Claus Flockenhaus , Karl H. Laue , Theo Sander , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
Inventor： Claus Flockenhaus , Karl H. Laue , Theo Sander , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
CPC classification number: F23J15/006 , B01D53/86 , B01D53/8646 , B01D53/865 , F23J2215/40 , F23J2219/10
Abstract: In a process for cleaning a waste gas containing various pollutants, the exhaust gas with the pollutants is introduced directly into a reduction reactor. In the reactor, the pollutants are reduced by ammonia. The catalyst used is iron oxide material or a mixed oxide material of iron oxide and chromium oxide, or a mixture of the mixture material of the mixed oxide material and the iron oxide material.
Abstract translation: 在清洗含有各种污染物的废气的过程中，将具有污染物的废气直接引入还原反应器中。 在反应堆中，污染物被氨还原。 使用的催化剂是氧化铁材料或氧化铁和氧化铬的混合氧化物材料，或混合氧化物材料和氧化铁材料的混合物的混合物。
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公开(公告)号：US4742036A
公开(公告)日：1988-05-03
申请号：US904175
申请日：1986-09-05
Applicant: Claus Flockenhaus , Daniel Grimm , Hartmut Kainer , Karl H. Laue
Inventor： Claus Flockenhaus , Daniel Grimm , Hartmut Kainer , Karl H. Laue
IPC: B01D53/86 , B01J23/745 , B01J27/185 , B01J23/74 , B01J35/02
CPC classification number: B01J27/1853 , B01D53/8628 , B01J23/745
Abstract: The invention relates to catalyst plates for reducing nitrogen oxide in exhaust gases. These plates are molded of granular Fe.sub.2 O.sub.3 catalyst material and a binder. To achieve high activity and strength in the plates, these are molded of a combination of a first mixture comprised of Fe.sub.2 O.sub.3 catalyst material and phosphoric acid as binder, and a second, separately-produced mixture comprised of Fe.sub.2 O.sub.3 catalyst material and sulphuric acid as binder. The plates can also be a molding having layers, which layers have alternate layers of the first and second mixtures.
Abstract translation: 本发明涉及用于还原废气中的氮氧化物的催化剂板。 这些板由粒状Fe 2 O 3催化剂材料和粘合剂成型。 为了在板中实现高活性和强度，它们由由Fe 2 O 3催化剂材料和磷酸组成的第一混合物作为粘合剂的组合以及由Fe 2 O 3催化剂材料和硫酸作为粘合剂组成的第二个单独制备的混合物组合。 板也可以是具有层的模制品，这些层具有第一和第二混合物的交替层。
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3.发明授权Process for the removal of nitrogen oxides and soot from exhaust gases of machines and combustion installations burning heavy fuel oil 失效从燃烧重型燃油的机器和燃烧设备的废气中除去氮氧化物和烟灰的过程
公开(公告)号：US4720376A
公开(公告)日：1988-01-19
申请号：US860306
申请日：1986-05-06
Applicant: Karl H. Laue , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein , Hans-Eugen Buhler
Inventor： Karl H. Laue , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein , Hans-Eugen Buhler
CPC classification number: F01N3/36 , B01D53/8625 , B01D53/8646 , B01D53/9409 , F01N3/02 , F01N3/0205 , F01N3/0231 , F01N3/2066 , F01N3/2882 , F01N2610/02 , F01N2610/14 , Y02T10/24
Abstract: A process for the removal of nitrogen oxides and soot from exhaust gases from machines and combustion installations burning heavy fuel oil by means of free-passage catalysts at increased temperatures with the addition of ammonia into the exhaust gas stream ahead of the catalysts. To make the process mre effective, the soot adhering to the catalyst surfaces is removed by burning it off and/or by friction resulting from the admixture of sand, ash or similar abrasive mixtures into the exhaust gas stream ahead of the catalysts.
Abstract translation: 一种用于从机器和燃烧装置的废气中除去氮氧化物和烟灰的方法，通过在升高的温度下通过自由通道催化剂燃烧重质燃料燃料，在催化剂之前的排气流中加入氨。 为了使该方法有效，粘附到催化剂表面上的烟灰通过将其从脱硫和/或由砂，灰或类似的研磨混合物混合物引起的摩擦物排出到催化剂前面的排气流中来除去。
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Patent Agency Ranking4.发明授权
公开(公告)号：US4721699A
公开(公告)日：1988-01-26
申请号：US900824
申请日：1986-08-27
Applicant: Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
Inventor： Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
CPC classification number: B01D53/8631 , B01J35/04 , F01N2330/06
Abstract: A structure made from catalyst for use in the separation of nitrogen oxides from combustion exhaust gases which contain dust. The catalytic structure has plates with spaces therebetween to carry a flow of the exhaust gas therethrough. The catalyst is constructed of individual ceramic plates. The abrasion or wear resistance of the plates is chosen such that the dust in the exhaust gases flowing through the spaces abrades the plate surface at a rate which is at least equivalent to the deactivation of the catalyst surface by action of the nitrogen oxides, which constantly provides a fresh catalyst surface for reaction with the nitrogen oxides. The movement of the exhaust gas through the catalytic structure carries the dust and abraded material along with it and out of the structure.
Abstract translation: 由用于从含有灰尘的燃烧废气中分离氮氧化物的催化剂制成的结构。 催化结构具有在其间具有间隔的板，以使废气流过其中。 催化剂由单独的陶瓷板构成。 选择板的磨损或耐磨性，使得流过空间的废气中的灰尘以至少等于通过氮氧化物的作用使催化剂表面的失活至少相当的速率磨损板表面，氮气氧化物的作用不断 提供了与氮氧化物反应的新鲜催化剂表面。 废气通过催化结构的运动将灰尘和磨损材料与其一起携带并离开结构。
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公开(公告)号：US4672052A
公开(公告)日：1987-06-09
申请号：US768508
申请日：1985-08-22
Applicant: Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
Inventor： Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
CPC classification number: B01D53/8631 , B01J35/04 , F01N2330/06
Abstract: A catalyst for use in a process for the removal of nitrogen oxides from exhaust gases contaminated with dust in which the process uses ammonia. The catalyst is made of a material which is easily disposable. Furthermore, the catalyst should be completely used up in the catalysis. The catalyst comprises individual ceramic bricks with a porous surface, and passages therethrough for the flow of the exhaust gases. The bricks exhibit a resistance to abrasion which is designed so that the dust of the exhaust gas which flows through the passages erodes the catalyst surface, thereby reactivating the catalyst. The exhaust gas carries the dust and the eroded material along with it.
Abstract translation: 一种催化剂，用于从其中使用氨的灰尘污染的废气中除去氮氧化物的方法。 催化剂由易于一次性的材料制成。 此外，催化剂应在催化中完全消耗。 该催化剂包括具有多孔表面的单个陶瓷砖，以及用于排气流动的通道。 砖表现出耐磨性，其设计为使得流过通道的排气的灰尘侵蚀催化剂表面，从而使催化剂再次活化。 废气携带灰尘和侵蚀的材料。
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6.发明授权Process for the manufacture of a catalyst for the reduction of nitrogen oxides in exhaust gases 失效用于制造用于还原废气中的氮氧化物的催化剂的方法
公开(公告)号：US4751212A
公开(公告)日：1988-06-14
申请号：US938525
申请日：1986-12-05
Applicant: Claus Flockenhaus , Erich Hackler , Karl H. Laue , Klaus Merkel , Arnold Max , Werner Stender , Johann Jansen , Hartmut Kainer , Daniel Grimm , Blagoje Levkov
Inventor： Claus Flockenhaus , Erich Hackler , Karl H. Laue , Klaus Merkel , Arnold Max , Werner Stender , Johann Jansen , Hartmut Kainer , Daniel Grimm , Blagoje Levkov
IPC: B01D53/86 , B01J23/745 , B01J23/74 , B01J27/053 , C01B21/00
CPC classification number: B01J23/745 , B01D53/8628
Abstract: The invention relates to a process for the manufacture of a catalyst for the reduction of nitrogen oxides in exhaust gases. The catalyst contains a metal oxide. The catalyst is preferably used for catalytic reduction with ammonia. The process comprises screening a natural goethite iron ore to the required grain size and then treating the ore with sulfuric acid. Subsequently, the goethite iron ore is heated to a temperature which approximately equals the temperature at which it will be used in the catalytic reaction.
Abstract translation: 本发明涉及制备用于还原废气中的氮氧化物的催化剂的方法。 催化剂含有金属氧化物。 该催化剂优选用于用氨催化还原。 该方法包括将天然针铁矿铁矿筛选成所需的粒度，然后用硫酸处理矿石。 随后，将针铁矿铁矿石加热到与催化反应中使用的温度大致相等的温度。
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7.发明授权Catalyst for the selective reduction of nitrogen oxides in waste gases and process for the manufacture of such a catalyst 失效用于选择性还原废气中的氮氧化物的催化剂和用于制造这种催化剂的方法
公开(公告)号：US4695559A
公开(公告)日：1987-09-22
申请号：US831142
申请日：1986-02-19
Applicant: Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Biagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein , Hans-Eugen Buhler , Horst Kalfa , Johann Jansen , Werner Stender , Arnold Max
Inventor： Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Biagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein , Hans-Eugen Buhler , Horst Kalfa , Johann Jansen , Werner Stender , Arnold Max
CPC classification number: B01J37/04 , B01D53/8628 , B01J23/862
Abstract: A catalyst for use with ammonia for the selective reduction of nitrogen oxides in waste gases. The catalyst comprises a mixture of substances which has high activity and selectivity with regard to nitrogen oxide conversion and high sorption capabilities with regard to ammonia, but low oxidation capabilities with regard to sulfur dioxide, ammonia, or similar substances. The invention also provides a process for the manufacture and use of such catalysts.
Abstract translation: 用于氨的催化剂用于选择性还原废气中的氮氧化物。 催化剂包括对于氮氧化物转化和对氨具有高吸附能力而具有高活性和选择性的物质的混合物，但对于二氧化硫，氨或类似物质的氧化能力低。 本发明还提供了制备和使用这种催化剂的方法。
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公开(公告)号：US4447333A
公开(公告)日：1984-05-08
申请号：US457444
申请日：1983-01-12
Applicant: Dietrich Wagener , Theo Sander , Karl H. Laue
Inventor： Dietrich Wagener , Theo Sander , Karl H. Laue
CPC classification number: B01D53/56 , C02F1/586 , Y10S210/903 , Y10S210/919
Abstract: A process for the elimination of ammonia in waste waters from a coke oven battery wherein ammonia-containing waste water or ammonia-containing vapor obtained by means of ammonia separation from the waste water are mixed with flue gas from the coke oven battery and sprayed into a NO.sub.x reactor at an elevated temperature with the resulting mixture being subjected to a catalytic redox reaction.
Abstract translation: 一种从焦炉电池中除去废水中的氨的方法，其中将含废水或通过氨分离得到的含氨蒸气与来自焦炉电池的废气混合并喷射到 NOx反应器在升高的温度下，使所得混合物进行催化氧化还原反应。
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