公开(公告)号：US20210104442A1

公开(公告)日：2021-04-08

申请号：US17124207

申请日：2020-12-16

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Colin Smith

IPC: H01L21/8238 ,  B01J37/08 ,  B01J21/06 ,  B01J21/04 ,  B01J23/06 ,  B01J27/02 ,  C07C1/20 ,  H01L21/265 ,  H01L27/092 ,  H01L29/66

Abstract: ZnxZryOz mixed oxide catalysts having improved stability for the conversion of ethanol to isobutene are described, together with methods for making such catalysts.

公开(公告)号：US20190214310A9

公开(公告)日：2019-07-11

申请号：US15860815

申请日：2018-01-03

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Colin Smith

IPC: H01L21/8238 ,  H01L21/265 ,  H01L27/092 ,  H01L29/66

CPC classification number: H01L21/823842 ,  B01J21/04 ,  B01J21/06 ,  B01J23/06 ,  B01J27/02 ,  B01J37/08 ,  C07C1/20 ,  C07C2523/06 ,  H01L21/26513 ,  H01L21/823821 ,  H01L21/82385 ,  H01L27/0922 ,  H01L27/0924 ,  H01L29/66537 ,  H01L29/66545

Abstract: ZnxZryOz mixed oxide catalysts having improved stability for the conversion of ethanol to isobutene are described, together with methods for making such catalysts.

公开(公告)号：US20180138094A1

公开(公告)日：2018-05-17

申请号：US15860815

申请日：2018-01-03

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Colin Smith

IPC: H01L21/8238 ,  H01L21/265 ,  H01L27/092 ,  H01L29/66

CPC classification number: H01L21/823842 ,  B01J21/04 ,  B01J21/06 ,  B01J23/06 ,  B01J27/02 ,  B01J37/08 ,  C07C1/20 ,  C07C2523/06 ,  H01L21/26513 ,  H01L21/823821 ,  H01L21/82385 ,  H01L27/0922 ,  H01L27/0924 ,  H01L29/66537 ,  H01L29/66545

Abstract: ZnxZryOz mixed oxide catalysts having improved stability for the conversion of ethanol to isobutene are described, together with methods for making such catalysts.

公开(公告)号：US09505671B2

公开(公告)日：2016-11-29

申请号：US14060217

申请日：2013-10-22

Applicant: WASHINGTON STATE UNIVERSITY ,  ARCHER DANIELS MIDLAND COMPANY

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Colin Smith ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C1/20 ,  C07C1/207 ,  C07C2/12 ,  C07C5/327 ,  C07C5/393 ,  C07C5/48

CPC classification number: C07C1/2078 ,  C07C2/12 ,  C07C5/327 ,  C07C5/393 ,  C07C5/48 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2529/40 ,  Y02P20/52 ,  C07C11/09 ,  C07C11/02 ,  C07C15/08

Abstract: A process is described for making renewable para-xylene, comprising converting acetic acid to isobutene in the presence of a catalyst then converting the acetic acid-derived isobutene to a product composition including para-xylene. The catalyst can be a ZnxZryOz mixed oxide catalyst.

Abstract translation: 描述了制备可再生对二甲苯的方法，包括在催化剂存在下将乙酸转化为异丁烯，然后将乙酸衍生的异丁烯转化成包括对二甲苯的产物组合物。 该催化剂可以是Zn x Zn x O z混合氧化物催化剂。

公开(公告)号：US20150217273A1

公开(公告)日：2015-08-06

申请号：US14683787

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Colin Smith

IPC: B01J23/06 ,  B01J37/08 ,  B01J27/02 ,  C07C1/20

CPC classification number: H01L21/823842 ,  B01J21/04 ,  B01J21/06 ,  B01J23/06 ,  B01J27/02 ,  B01J37/08 ,  C07C1/20 ,  C07C2523/06 ,  H01L21/26513 ,  H01L21/823821 ,  H01L21/82385 ,  H01L27/0922 ,  H01L27/0924 ,  H01L29/66537 ,  H01L29/66545

Abstract: ZnxZryOz mixed oxide catalysts having improved stability for the conversion of ethanol to isobutene are described, together with methods for making such catalysts.

Abstract translation: 描述了具有改进的将乙醇转化为异丁烯的稳定性的Zn x Zn y O z混合氧化物催化剂，以及制备这种催化剂的方法。

公开(公告)号：US20140121430A1

公开(公告)日：2014-05-01

申请号：US14060217

申请日：2013-10-22

Applicant: ARCHER DANIELS MIDLAND COMPANY ,  WASHINGTON STATE UNIVERSITY

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Colin Smith ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C1/207

CPC classification number: C07C1/2078 ,  C07C2/12 ,  C07C5/327 ,  C07C5/393 ,  C07C5/48 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2529/40 ,  Y02P20/52 ,  C07C11/09 ,  C07C11/02 ,  C07C15/08

Abstract: A process is described for making renewable para-xylene, comprising converting acetic acid to isobutene in the presence of a catalyst then converting the acetic acid-derived isobutene to a product composition including para-xylene. The catalyst can be a ZnxZryOz mixed oxide catalyst.

Abstract translation: 描述了制备可再生对二甲苯的方法，包括在催化剂存在下将乙酸转化为异丁烯，然后将乙酸衍生的异丁烯转化成包括对二甲苯的产物组合物。 该催化剂可以是Zn x Zn x O z混合氧化物催化剂。

公开(公告)号：US20140128650A1

公开(公告)日：2014-05-08

申请号：US14105249

申请日：2013-12-13

Applicant: ARCHER DANIELS MILDAND COMPANY ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Colin Smith ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Joshua Terrian

IPC: C07C1/207 ,  C07C5/327 ,  C07C5/48

CPC classification number: C07C1/2078 ,  B01J21/066 ,  B01J23/06 ,  C07C1/207 ,  C07C1/2074 ,  C07C2/12 ,  C07C5/327 ,  C07C5/48 ,  C07C29/00 ,  C07C29/60 ,  C07C51/12 ,  C07C51/235 ,  C07C2521/06 ,  C07C2523/06 ,  C10G3/00 ,  C10G3/44 ,  C10G3/50 ,  C10G9/00 ,  C10G2400/20 ,  C10G2400/22 ,  C12P7/52 ,  C12P7/54 ,  Y02P20/52 ,  C07C11/10 ,  C07C11/09 ,  C07C11/18 ,  C07C31/202 ,  C07C31/205 ,  C07C53/08 ,  C07C53/122 ,  C07C11/167 ,  C07C11/06 ,  C07C11/08

Abstract: A process is described for making a product mixture including isobutene, propylene, 1-butene, 2-butene 2-methyl-1-butene and 2-methyl-2-butene from a mixture of acetic acid and propionic and through reaction in the presence of a source of hydrogen and of a mixed oxide catalyst, for example, a ZnxZryOz mixed oxide catalyst. A variety of commercially valuable products may be made in turn from the various C3, C4 and C3 constituents of the product mixture

Abstract translation: 描述了从乙酸和丙酸的混合物中制备包括异丁烯，丙烯，1-丁烯，2-丁烯-2-甲基-1-丁烯和2-甲基-2-丁烯的产物混合物的方法，并通过在存在下的反应 的氢源和混合氧化物催化剂，例如Zn x Zr y O z混合氧化物催化剂。 可以从产品混合物的各种C3，C4和C3组分依次制备各种商业上有价值的产品

公开(公告)号：US09212106B2

公开(公告)日：2015-12-15

申请号：US14105249

申请日：2013-12-13

Applicant: Washington State University ,  ARCHER DANIELS MILDAND COMPANY

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Colin Smith ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Joshua Terrian

IPC: B01J23/06 ,  C07C1/207 ,  C07C5/327 ,  C07C5/48 ,  C10G3/00 ,  B01J21/06 ,  C07C29/60 ,  C07C51/235 ,  C07C29/00 ,  C12P7/52 ,  C12P7/54

CPC classification number: C07C1/2078 ,  B01J21/066 ,  B01J23/06 ,  C07C1/207 ,  C07C1/2074 ,  C07C2/12 ,  C07C5/327 ,  C07C5/48 ,  C07C29/00 ,  C07C29/60 ,  C07C51/12 ,  C07C51/235 ,  C07C2521/06 ,  C07C2523/06 ,  C10G3/00 ,  C10G3/44 ,  C10G3/50 ,  C10G9/00 ,  C10G2400/20 ,  C10G2400/22 ,  C12P7/52 ,  C12P7/54 ,  Y02P20/52 ,  C07C11/10 ,  C07C11/09 ,  C07C11/18 ,  C07C31/202 ,  C07C31/205 ,  C07C53/08 ,  C07C53/122 ,  C07C11/167 ,  C07C11/06 ,  C07C11/08

Abstract: A process is described for making a product mixture including isobutene, propylene, 1-butene, 2-butene, 2-methyl-1-butene and 2-methyl-2-butene from a mixture of acetic acid and propionic and through reaction in the presence of a source of hydrogen and of a mixed oxide catalyst, for example, a ZnxZryOz mixed oxide catalyst. A variety of commercially valuable products may be made in turn from the various C3, C4 and C5 constituents of the product mixture.

Abstract translation: 描述了从乙酸和丙酸的混合物中制备包括异丁烯，丙烯，1-丁烯，2-丁烯，2-甲基-1-丁烯和2-甲基-2-丁烯的产物混合物的方法，并通过在 存在氢源和混合氧化物催化剂，例如Zn x ZrO 2混合氧化物催化剂。 可以从产品混合物的各种C3，C4和C5组分依次制备各种商业上有价值的产品。