PROCESS FOR PREPARING ACRYLIC ACID FROM ETHANOL AND FORMALDEHYDE
    2.
    发明申请
    PROCESS FOR PREPARING ACRYLIC ACID FROM ETHANOL AND FORMALDEHYDE 审中-公开
    从乙醇和甲醛制备丙烯酸的方法

    公开(公告)号:US20130289305A1

    公开(公告)日:2013-10-31

    申请号:US13933732

    申请日:2013-07-02

    Applicant: BASF SE

    Abstract: A process for preparing acrylic acid from ethanol and formaldehyde, in which, in a reaction zone A, the ethanol is partially oxidized to acetic acid in a heterogeneously catalyzed gas phase reaction, the product gas mixture A obtained and a formaldehyde source are used to obtain a reaction gas input mixture B which comprises acetic acid and formaldehyde and has the acetic acid in excess over the formaldehyde, and the formaldehyde present in reaction gas input mixture B is aldol-condensed with acetic acid present in reaction gas input mixture B to acrylic acid under heterogeneous catalysis in a reaction zone B, and unconverted acetic acid still present along-side the acrylic acid target product in the product gas mixture B obtained is removed therefrom, and the acetic acid removed is recycled into the production of reaction gas input mixture B.

    Abstract translation: 一种从乙醇和甲醛制备丙烯酸的方法,其中在反应区A中乙醇在非均相催化气相反应中部分氧化成乙酸,得到的产物气体混合物A和甲醛源用于获得 反应气体输入混合物B,其包含乙酸和甲醛,并且乙酸超过甲醛,反应气体输入混合物B中存在的甲醛与反应气体输入混合物B中存在的乙酸醛醛缩合成丙烯酸 在反应区B中的非均相催化下,从得到的产物气体混合物B中沿着丙烯酸目标产物仍然存在未转化的乙酸,除去乙酸,再循环到反应气体输入混合物B 。

    CATALYST AND METHOD FOR PRODUCING MALEIC ANHYDRIDE
    7.
    发明申请
    CATALYST AND METHOD FOR PRODUCING MALEIC ANHYDRIDE 有权
    催化剂及其生产方法

    公开(公告)号:US20150343433A1

    公开(公告)日:2015-12-03

    申请号:US14823292

    申请日:2015-08-11

    Applicant: BASF SE

    Abstract: The invention relates to a catalyst molded body for preparing maleic anhydride by gas-phase oxidation of a hydrocarbon having at least four carbon atoms using a catalytically active composition containing vanadium, phosphorus and oxygen. The shaped catalyst body has an essentially cylindrical body having a longitudinal axis. The cylindrical body has at least two parallel internal holes which are essentially parallel to the cylinder axis of the body and go right through the body. The catalyst molded body has a large outer surface area, a lower pressure loss and sufficient mechanical stability.

    Abstract translation: 本发明涉及一种用于通过使用含有钒,磷和氧的催化活性组合物通过气相氧化具有至少四个碳原子的烃来制备马来酸酐的催化剂模制体。 成型的催化剂体具有基本上具有纵向轴线的圆柱体。 圆柱体具有至少两个平行的内孔,其基本上平行于主体的气缸轴线并且直接通过本体。 催化剂成型体具有大的外表面积,较低的压力损失和足够的机械稳定性。

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