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公开(公告)号:US11846645B2
公开(公告)日:2023-12-19
申请号:US17616705
申请日:2020-06-24
Applicant: BASF SE
Inventor: Thomas Daniel , Markus Toennessen , Christophe Bauduin
CPC classification number: G01N5/02 , G01N15/08 , G01N2015/0866
Abstract: In a method of measuring parameters of superabsorbents, the absorption capacity of superabsorbents is determined under pressure, by reducing the pressure applied to a sample of the superabsorbent stepwise and determining the absorption capacity at each pressure. In addition, the rise in absorption capacity after a reduction in pressure is measured as a function of time and this is used to calculate the swelling constant k or the characteristic swelling time τ. Swelling constant or characteristic swelling time or the magnitude of the difference in absorption capacity at two different pressures are used to determine further parameters of the superabsorbent.
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公开(公告)号:US11591424B2
公开(公告)日:2023-02-28
申请号:US16913170
申请日:2020-06-26
Applicant: BASF SE
Inventor: Stephan Bauer , Tina Mark , Lydia König , Yvonne Hagen , Thomas Daniel
IPC: A61L15/60 , C08F220/06 , A61L15/42 , A61F13/53 , A61F13/534 , A61L15/24 , C08F2/06 , C08F222/10
Abstract: A process for producing water-absorbing polymer particles by suspension polymerization and thermal surface postcrosslinking, wherein the base polymer obtained by suspension polymerization has a centrifuge retention capacity of at least 37 g/g and the thermal surface postcrosslinking is conducted at 100 to 190° C.
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公开(公告)号:US11491463B2
公开(公告)日:2022-11-08
申请号:US16958793
申请日:2019-01-02
Applicant: BASF SE
Inventor: Stephan Bauer , Katrin Baumann , Markus Toennessen , Christophe Bauduin , Markus Christian Biel , Thomas Daniel
Abstract: Superabsorbent mixtures M comprising at least 70% by weight of superabsorbent A having a liquid absorption of 20 g/g (T20) of less than 300 s and/or a volumetric liquid absorption under pressure 0.3 psi (2.07 kPa) (VAUL) with a τ value of less than 400 s, and at least 5% by weight of superabsorbent B having a centrifuge retention capacity (CRC) of at least 30 g/g.
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公开(公告)号:US11325990B2
公开(公告)日:2022-05-10
申请号:US16321638
申请日:2017-08-01
Applicant: BASF SE
Inventor: Kristine Hartnagel , Thomas Gieger , Thomas Daniel , Marcus Schroeder , Michelle Morano , Nathaniel Troy Greene
IPC: C08F2/22 , C08K3/011 , A61L15/60 , B01J20/26 , B01J20/28 , C08F2/01 , C08F2/44 , C08F6/14 , C08F220/06 , C08J3/12 , C08J3/24 , C08K3/30 , C08K5/5317
Abstract: A process for producing superabsorbents, comprising polymerization of a monomer solution and thermal surface postcrosslinking, wherein the monomer solution comprises at least 0.75% by weight of a hydroxyphosphonic acid or salts thereof, calculated on the basis of the total amount of monomer used, and at least 0.09% by weight of aluminum cations, calculated on the basis of the total amount of polymer particles used, is added to the polymer particles before, during or after the thermal surface postcrosslinking.
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公开(公告)号:US20210187479A1
公开(公告)日:2021-06-24
申请号:US16757523
申请日:2018-10-31
Applicant: BASF SE
Inventor: Kristine Hartnagel , Wanthip Poomsuwan , Patrick Neal Hamilton , Norbert Herfert , Thomas Daniel , Olaf Hoeller
IPC: B01J20/32 , A61L15/60 , A61L15/24 , A61L15/18 , B01J20/26 , B01J20/30 , B01J20/02 , C08J3/12 , C08J3/24 , C08J3/07
Abstract: In an improved superabsorbent complexed with aluminum ions, the aluminum ions are applied in the form of an aqueous solution comprising aluminum ions, which has the feature that it comprises aluminum ions in a proportion within the range of 0.5%-15% by weight (converted if appropriate to Al3+), based on the total mass of the solution, and further comprises anions of lactic acid (lactate ions) and phosphoric acid (phosphate ions), where the molar proportion of the lactate ions is within the range of 0.01-2.99 times the molar amount of Al3+ and the molar proportion of the phosphate ions is within the range of 0.01-2.99 times the molar amount of Al3+.
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公开(公告)号:US20200060897A1
公开(公告)日:2020-02-27
申请号:US16482045
申请日:2018-02-12
Applicant: BASF SE
Inventor: Thomas Daniel , Christophe Bauduin , Katrin Baumann , Katarzyna Dobrosielska-Oura
IPC: A61F13/537 , A61L15/60
Abstract: A fluid-absorbent article includes an upper liquid-pervious layer (A), a lower liquid-impervious layer (B), a fluid-absorbent core (C) between (A) and (B) including at least 60% by weight of non-surface postcrosslinked fluid-absorbent polymer particles and not more than 40% by weight of fibrous material, based on the sum of non-surface postcrosslinked fluid-absorbent polymer particles and fibrous material. An acquisition-distribution layer (D) between (A) and (C) includes at least 90% by weight of synthetic fibers and not more than 10% by weight of cellulose based fibers, based on the sum of synthetic fibers and cellulose based fibers. The basis weight of the acquisition-distribution layer (D) is at least 70 gsm. The fluid-absorbent polymer particles have a saline flow conductivity (SFC) of less than 5×10−7 cm3s/g and an AUHL of less than 15 g/g. Preferably the acquisition-distribution layer (D) is a non-woven web including a three dimensional network of fibers.
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公开(公告)号:US09790304B2
公开(公告)日:2017-10-17
申请号:US14442501
申请日:2013-11-11
Applicant: BASF SE
Inventor: Thomas Daniel , Norbert Herfert , Stephan Bauer , Katrin Baumann , Birgit Reinhard , Jürgen Freiberg , Rudolf Schliwa
IPC: B01J20/32 , C08F220/06 , C08F6/00 , A61L15/42 , A61L15/60 , A61L15/22 , C08L33/02 , A61L15/24 , B01J20/26 , B01J20/28
CPC classification number: C08F220/06 , A61L15/22 , A61L15/24 , A61L15/42 , A61L15/60 , B01J20/267 , B01J20/28023 , B01J20/2805 , C08F6/005 , C08L33/02 , C08L33/08 , C08F2222/1013
Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution comprising less than 0.3% by weight of persulfate and at least 0.05% by weight of azo initiator and thermal aftertreatment of the formed polymer particles at less than 100° C. in a fluidized bed for 60 to 300 minutes.
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公开(公告)号:US12196660B2
公开(公告)日:2025-01-14
申请号:US16968225
申请日:2019-02-18
Applicant: BASF SE
Inventor: Markus Toennessen , Marc Haefner , Karsten Kraemer , Christophe Bauduin , Thomas Daniel
IPC: G01N15/08
Abstract: A method of measuring indices in superabsorbents, by initially charging excess aqueous solution or dispersion, swelling the superabsorbent in the initially charged aqueous solution or dispersion while stirring, dissolving or dispersing a component A in the aqueous solution or dispersion, measuring the enrichment of component A in the aqueous solution or dispersion during the swelling of the superabsorbent, using the enrichment of component A in the aqueous solution or dispersion to measure the time-dependent swelling characteristics and using these to determine the swelling constant k or the characteristic swell time τ, the index being dependent on the permeability of the superabsorbent, and ascertaining the index by means of a correlation measured beforehand between swelling constant k and index or characteristic swell time τ and index.
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公开(公告)号:US11813589B2
公开(公告)日:2023-11-14
申请号:US16757523
申请日:2018-10-31
Applicant: BASF SE
Inventor: Kristine Hartnagel , Wanthip Poomsuwan , Patrick Neal Hamilton , Norbert Herfert , Thomas Daniel , Olaf Hoeller
IPC: B01J20/32 , A61L15/18 , A61L15/24 , A61L15/60 , B01J20/02 , B01J20/26 , B01J20/30 , C08J3/07 , C08J3/12 , C08J3/24
CPC classification number: B01J20/3236 , A61L15/18 , A61L15/24 , A61L15/60 , B01J20/0292 , B01J20/267 , B01J20/3021 , C08J3/07 , C08J3/12 , C08J3/245 , B01J2220/68 , C08J2333/02
Abstract: In an improved superabsorbent complexed with aluminum ions, the aluminum ions are applied in the form of an aqueous solution comprising aluminum ions, which has the feature that it comprises aluminum ions in a proportion within the range of 0.5%-15% by weight (converted if appropriate to Al3+), based on the total mass of the solution, and further comprises anions of lactic acid (lactate ions) and phosphoric acid (phosphate ions), where the molar proportion of the lactate ions is within the range of 0.01-2.99 times the molar amount of Al3+ and the molar proportion of the phosphate ions is within the range of 0.01-2.99 times the molar amount of Al3+.
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公开(公告)号:US20220235152A1
公开(公告)日:2022-07-28
申请号:US17717598
申请日:2022-04-11
Applicant: BASF SE
Inventor: Kristine Hartnagel , Thomas Gieger , Thomas Daniel , Marcus Schroeder , Michelle Morano , Nathaniel Troy Greene
IPC: C08F2/22 , C08K3/011 , A61L15/60 , B01J20/26 , B01J20/28 , C08F2/01 , C08F2/44 , C08F6/14 , C08F220/06 , C08J3/12 , C08J3/24 , C08K3/30 , C08K5/5317
Abstract: A process for producing superabsorbents, comprising polymerization of a monomer solution and thermal surface postcrosslinking, wherein the monomer solution comprises at least 0.75% by weight of a hydroxyphosphonic acid or salts thereof, calculated on the basis of the total amount of monomer used, and at least 0.09% by weight of aluminum cations, calculated on the basis of the total amount of polymer particles used, is added to the polymer particles before, during or after the thermal surface postcrosslinking.
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