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    Process for creating high internal phase polymeric emulsions
    5.
    发明授权
    Process for creating high internal phase polymeric emulsions 有权
    制备高内相聚合物乳液的方法

    公开(公告)号：US07432311B2

    公开(公告)日：2008-10-07

    申请号：US11084727

    申请日：2005-03-18

    申请人： Raffaele Mezzenga ,  Glenn H. Fredrickson ,  Edward J. Kramer

    发明人： Raffaele Mezzenga ,  Glenn H. Fredrickson ,  Edward J. Kramer

    IPC分类号： C08J9/28

    CPC分类号： C08L51/003 ,  C08L21/00 ,  C08L23/02 ,  C08L25/06 ,  C08L39/06 ,  C08L39/08 ,  C08L53/00 ,  C08L2205/08 ,  C08L2666/06 ,  C08L2666/02

    摘要： A “high internal phase polymeric emulsion” (“HIPPE”) composition is described which comprises an emulsion of a discrete phase (component A) and a continuous phase (component B), wherein the volume fraction of the discrete phase is the majority fraction (on a volume basis) of the total volume of the emulsion. A compatibilizer, component C, is used to lower the interfacial tension between the phases containing components A and B. A process is described for creating such HIPPE composition in which the A component is a colloidal polymer particle.

    摘要翻译： 描述了一种“高内相聚合乳液”（“HIPPE”）组合物，其包含离散相（组分A）和连续相（组分B）的乳液，其中离散相的体积分数是多数部分 以体积计）乳液的总体积。 使用增容剂C组分来降低含有组分A和B的相之间的界面张力。描述了制备其中A成分为胶体聚合物颗粒的HIPPE组合物的方法。

    GEL-PROCESSED POLYOLEFIN COMPOSITIONS
    7.
    发明申请
    GEL-PROCESSED POLYOLEFIN COMPOSITIONS 审中-公开
    凝胶加工的聚烯烃组合物

    公开(公告)号：US20100063213A1

    公开(公告)日：2010-03-11

    申请号：US12554250

    申请日：2009-09-04

    申请人： Glenn H. Fredrickson ,  Edward Kramer ,  Geoffrey W. Coates

    发明人： Glenn H. Fredrickson ,  Edward Kramer ,  Geoffrey W. Coates

    IPC分类号： C08F10/00 ,  C08F110/06 ,  C08L23/00 ,  B29C47/00

    CPC分类号： C08L23/04 ,  C08J5/18 ,  C08J2323/02 ,  C08L23/10 ,  C08L51/06 ,  C08L53/00 ,  C08L2203/12 ,  C08L2205/02 ,  C08L2207/12 ,  D01F6/04 ,  D01F6/06 ,  D01F6/30 ,  D01F6/46 ,  C08L2666/02

    摘要： Semicrystalline polyolefins with narrow molecular weight distributions characterized by a low polydispersity index (PDI) and selected from the families of homopolymers, statistical copolymers, block copolymers, and graft copolymers, can be blended with a low molecular weight fluid diluent to create gel fiber and film compositions. These gel compositions, when subjected to mechanical or thermomechanical processing, either before or after removal of the diluent, result in fiber or film compositions that combine high tensile strength with other desirable physical properties, such as high rigidity, large extension at break, and/or high recoverable elasticity. These desirable combinations of properties are superior to those obtained from gel-processed semicrystalline polyolefins that are substantially similar in composition and molecular weight, but that have large PDIs.

    摘要翻译： 具有低分子量指数（PDI）和选自均聚物，统计共聚物，嵌段共聚物和接枝共聚物家族的窄分子量分布的半结晶聚烯烃可以与低分子量流体稀释剂混合以产生凝胶纤维和膜 组合物。 这些凝胶组合物在去除稀释剂之前或之后经受机械或热机械加工时，导致将高拉伸强度与其它所需物理性质（例如高刚性，断裂伸长大和/ 或高可恢复弹性。 这些理想的性能组合优于从组成和分子量基本相似但具有大的PDI的凝胶加工的半结晶聚烯烃获得的组合。

    Soft and strong elastomeric compositions from semicrystalline-amorphous polyolefin block copolymers
    10.
    发明申请
    Soft and strong elastomeric compositions from semicrystalline-amorphous polyolefin block copolymers 有权
    来自半结晶非晶形聚烯烃嵌段共聚物的柔软和强力的弹性体组合物

    公开(公告)号：US20080319116A1

    公开(公告)日：2008-12-25

    申请号：US12080971

    申请日：2008-04-08

    申请人： Glenn H. Fredrickson ,  Edward J. Kramer ,  Zhigang Wang

    发明人： Glenn H. Fredrickson ,  Edward J. Kramer ,  Zhigang Wang

    IPC分类号： C08K3/20 ,  C08L51/00 ,  B29C55/30 ,  B29C55/12 ,  B29C47/78

    CPC分类号： C08J3/075 ,  B29C47/0014 ,  B29C47/0016 ,  B29C47/0021 ,  B29C47/786 ,  B29C47/90 ,  B29C47/906 ,  C08J2351/06 ,  C08J2353/00 ,  C08L51/06 ,  C08L53/00 ,  C08L2205/03 ,  C08L2666/24

    摘要： Polyolefin block and graft copolymers comprised of two or more semicrystalline polyolefin blocks or grafts and one or more amorphous polyolefin blocks can be blended with a low molecular weight fluid diluent that preferentially locates within and swells the amorphous domains of the block or graft copolymer, while preserving the crystallinity of the semicrystalline block domains. After mechanical or thermomechanical processing, such compositions combine softness with high strength and high recoverable elasticity. Compositions are also disclosed whereby the diluent species is removed from the composition, either before or after the mechanical or thermomechanical processing, in order to create a strong elastic material with an ultra-low entanglement density within the amorphous domains.

    摘要翻译： 由两个或更多个半结晶聚烯烃嵌段或接枝物和一个或多个非晶形聚烯烃嵌段组成的聚烯烃嵌段和接枝共聚物可以与低分子量流体稀释剂共混，该低分子量流体稀释剂优选位于嵌段或接枝共聚物的无定形区域内并溶胀，同时保留 半结晶区域的结晶度。 在机械或热机械加工之后，这种组合物将柔软度与高强度和高可恢复弹性相结合。 还公开了组合物，其中在机械或热机械加工之前或之后从组合物中除去稀释剂物质，以便在无定形区域内产生具有超低缠结密度的强弹性材料。