摘要:
According to the present invention, a process is provided for forming a lubricating oil concentrate containing aromatic carbonate which comprises admixing lubricating oil, aromatic carbonate and at least one aromatic carbonate solubilizing co-additive of the formula: ##STR1## wherein R.sup.1 is C.sub.1 to C.sub.20 substituted or unsubstituted hydrocarbyl, Ar is C.sub.6 to C.sub.20 aromatic group, and Z.sup.1 is a member selected from the group consisting of --(O)COR.sup.2, --N(R.sup.3)--T.sup.2, --X--T.sup.1, and --D.sup.1 --T.sup.3 wherein R.sup.2 is H or C.sub.1 to C.sub.20 hydrocarbyl, R.sup.3 is H or C.sub.1 to C.sub.6 hydrocarbyl, T.sup.2 is substituted or unsubstituted aryl, X is O or S, T.sup.1 is group of the formula: ##STR2## wherein Ar' is C.sub.6 to C.sub.20 aromatic group, Z.sup.2 is divalent C.sub.1 to C.sub.10 alkylene or C.sub.3 to C.sub.10 cycloalkylene, R.sup.4 is C.sub.1 to C.sub.20 substituted or unsubstituted hydrocarbyl, c' is 0 or 1, d is an integer of at least 1, and f' and b' are each integers of from 0 to 3, with the proviso that the sum of f' and b' does not exceed the unsatisfied valences of Ar', D.sup.1 is a C.sub.1 to C.sub.10 hydrocarbon linking group and T.sub.3 is an alkylene polyamine group, optionally substituted by one or more hydroxy-(optionally hydrocarby-substituted) aromatic groups, wherein f, b and c are each integers of from 0 to 3, with the proviso that the sum of f, b and c does not exceed the unsatisfied valences of Ar.
摘要:
A process for producing polymers from olefins selectively produced by a two stage process for selectively producing C2 to C4 olefins from a gas oil or resid is disclosed herein. The gas oil or resid is reacted in a first stage comprising a fluid catalytic cracking unit wherein it is converted in the presence of conventional large pore zeolitic catalyst to reaction products, including a naphtha boiling range stream. The naphtha boiling range stream is introduced into a second stage comprising a process unit containing a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feed is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500 to 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone.
摘要:
A process for obtaining a substantial amount of olefinic products from a residua feedstock by use of a short vapor contact time thermal process unit comprised of a horizontal moving bed of fluidized hot particles.
摘要:
A filter system containing, in series, a first filter media having a chemically active filter media, a physically active filter media, or mixtures thereof and a second filter media having an inactive filter media can effectively rejuvenate used lubricating oils. In a preferred embodiment, the chemically or physically active filter media will be within a cannister that is separate from a container having both active and inactive filter media.
摘要:
A process for producing polypropylene from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha stream is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures from about 500° C. to 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia. The catalyst may be pre-coked with a carbonaceous feed. Alternatively, the carbonaceous feed used to coke the catalyst may be co-fed with the naphtha feed.
摘要:
The invention is related to a two step process wherein the first step comprises cracking an olefinic naphtha resulting in a cracked product having a diminished total concentration of olefinic species. The second step comprises hydroprocessing at least a portion of the cracked product, especially a naphtha fraction, to provide a hydroprocessed cracked product having a reduced concentration of contaminant species but without a substantial octane reduction.
摘要:
Disclosed is a process for controlling combustion in a fluid catalytic cracking regenerator. More specifically, afterburning which occurs during the combustion process is controlled by adjusting oxygen concentration in at least one of two combustion streams which is injected into a fluid catalytic cracking regenerator. Preferably, the combustion streams used in the invention are asymmetrically injected into a dense phase catalyst bed within the regenerator.
摘要:
Piston deposits resulting from neutralizing combustion acids present in the lubricating oil circulating within the lubrication system of an internal combustion engine are reduced or eliminated by first cntacting the acids with a soluble weak base in the piston ring zone of the engine to form soluble neutral salts containing the weak base and the combustion acids. Thereafter, the neutral salts are contacted with a heterogenous strong base immobilized within the lubrication system but outside of the piston ring zone. The strong base displaces the weak base from the neutral salts, returning the weak base to the oil for recirculation to the piston ring zone for further use. The remaining strong base/combustion adic salts are immobilized as deposits with the strong base rather than on the piston. In a preferred embodiment, trioctadecyl amine is the weak base and magnesium oxide is the strong base.
摘要:
A filter system for use in a three-phase slurry reactor is provided. The filter system comprises one or more bundles of a plurality of filter elements for separating liquid from a mixture of liquid and solids contained in the reactor. Each filter bundle is connected to a product transfer conduit transporting separated liquid to a location outside of and downstream from the reactor. The transfer conduit is provided with means for backflushing the filter bundle and guard filter means.
摘要:
The invention relates to a process for maintaining heat balance in a fluidized bed catalytic cracking unit. More specifically, the invention relates to a combustion control method capable of maintaining or restoring heat balance by conducting, under appropriate conditions, fuel and an oxygen-containing gas to a transfer line. The transfer line conducts effluent including spent catalyst and combustion products to the unit's catalyst regeneration zone.