摘要:
Thermoplastic molding compositions containingA) ABS-type resin,B) aromatic polycarbonate resins,C) a compound bearing several carboxyl groups or mixtures thereof and optionallyD) further polymer resins,characterized in that an ABS resin with at least one basically acting additive is used as component A, component C is selected from compounds having a molecular weight of from 150 to 260 having at least two carboxyl groups (--COOH) in the molecule, and the weight ratio of basically acting additive in A: carboxyl groups in C is from 5:1 to 1:1.
摘要:
Thermoplastic moulding compounds containing(A) from 5 to 90 parts by weight of one or more thermoplastic polymers,(B) from 5 to 90 parts by weight of one or more graft polymers and(C) from 0.25 to 40 parts by weight of a copolymer having a sequential structure corresponding to the idealized formula (I)(A-X-B).sub.n (I)whereinA=a polymer of a cyclic carbonate,B=a polymer of another cyclic ester andX=a middle member containing both partial structures of A and B.
摘要:
Thermoplastic moulding compounds containing(A) from 5-90 parts by weight of one or more thermoplastic polymers,(B) from 5-90 parts by weight of one or more graft polymers and(C) from 0.25-40 parts by weight of a blocked copolymer corresponding to the idealized formula (I)A - B - A; B - A - B or (A - B).sub.x (I) whereinA denotes the residue of a homopolymer, e.g. of styrene, andB denotes the residue of a homopolymer of a cyclic carbonate or lactone.
摘要:
Thermoplastic molding compositions of a vinyl chloride polymer and one or more emulsion polymers made with special emulsifiers have improved properties for technical application, such as reduced fogging. They are used for the production of molded articles, sheet products and films.
摘要:
Dispersions of stabilizers for plastics in water which contain special reaction products of diols and carboxylic acid anhydrides as auxiliary emulsifiers, and which are characterized by simple preparation, stability and good effectiveness in chemical materials.
摘要:
Polymer mixtures ofa. 10 to 60 parts by weight of a graft polymer,b. 10 to 50 parts by weight of a partially cross-linked, rubber like copolymer of from 5 to 40% by weight of acrylonitrile, styrene, alkyl methacrylate or mixtures thereof and from 95 to 60% by weight of alkyl acrylate having a gel content of from 20 to 99% by weight,c. 5 to 40 parts by weight of an uncross-linked polymer of styrenes, .alpha.-methyl styrenes, acrylonitrile, methacrylonitrile, esters of acrylic acid or methacrylic acid, vinyl C.sub.1 to C.sub.4 carboxylic acids or mixtures of these monomers having Staudinger Indices (.eta.) (determined in dimethyl formamide at 23.degree. C.) of from 0.3 to 1.5 dl/g andd. 1 to 45 parts by weight of a polymer of a cyclic aliphatic ester or of an aliphatic cyclic ester and an aliphatic cyclic carbonate.
摘要:
Elastic-thermoplastic or thermoplastic powder-form moulding compositions having uniform particles size and improved thermal stability and processes for their manufacture.
摘要:
Process for the preparation of a thermoplastic moulding composition of 10 to 65% by weight of at least one graft polymer which is obtainable by emulsion polymerization of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50, it being possible for all or some of the styrene to be replaced by .alpha.-methylstyrene or methyl methacrylate, in the presence of at least one rubber base, and the weight ratio of monomers employed to rubber polymer employed being 20:80 to 70:30, and 90 to 35% by weight of a copolymer of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50, it being possible for all or some of the styrene to be replaced by .alpha.-methylstyrene or methyl methacrylate, wherein, to prepare the graft polymer, the grafting monomers and 0.05 to 1.00 part by weight (per 100 parts by weight of grafting monomer) of a mercaptan are added stepwise to the latex of the rubber base over a period of time, the part amount of the monomer added in each time interval .DELTA.t.sub.n+1 being 0.30 to 0.95 times the amount of monomer added in the preceding time interval .DELTA.t.sub.n at least in the first half of the period of time, and the total period of time comprising n time intervals where n=3 to 30, and each time interval .DELTA.t being 5 to 100 minutes long.
摘要:
Sulphur-containing elastic-thermoplastic graft products of styrene, .alpha.-methyl styrene, p-methyl styrene, vinyl toluene, acrylonitrile or methyl methacrylate or mixtures thereof on a particle-like rubber with an average particle diameter (d.sub.50) of from 0.05 to 20.0 .mu.m and a glass temperature .ltoreq.10.degree. C. with a total rubber content of from 1 to 80% by weight, whereby the graft products have a sulphur content of from 1.15 to 3.95% by weight and the thermoplast proportion of the polymerized monomers on the particle-like rubber has a limiting viscosity of from 2 to 15 ml/g (measured in dimethyl formamide at 25.degree. C.) and in which at least 90% by weight of the incorporated sulphur is present as a constituent of terminal C1-18-thioalkyl groups.
摘要:
Elastic-thermoplastic and thermoplastic powder-form moulding compositions of uniform particle size and improved thermal stability at made by incorporating a sulphur containing polymer.